Tóm tắt:

m_P = 6.2 g

V_O2 = 4,48g

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a. PTHH

b. Chất nào dư? dư bao nhiêu mol?

c.m_P2O5 = ?

a.                4  P          +         5   O₂       -----------     2    P₂O₅

                      _{4mol                          5 mol                                       2mol}

                    _{0,2 mol}

b.    Số mol P là:          n =\(\dfrac{m}{M}\)=\(\dfrac{6,2}{31}\)= 0,2 mol

       Số mol O₂ là:        n =\(\dfrac{V}{22,4}\)=\(\dfrac{4,48}{22,4}\) = 0,2 mol 

      Lập tỉ lệ :   \(\dfrac{0,2}{4}\)   <   \(\dfrac{0,2}{5}\)  => O₂ dư 

Số mol dư : n_O2 = n_bd - n_{phân huỷ}

                =  0,2 - \(\dfrac{0,2.4}{5}\)= 0,04 mol

c. Số mol P₂O₅ : \(\dfrac{0,2.2}{4}\)=0,1

   Khối lượng P₂O₅ : m = n.M= 0,1 . 142 = 14,2g

$a) 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$

$n_P = \dfrac{6,2}{31} = 0,2(mol) ; n_{O_2} = \dfrac{7,84}{22,4} = 0,35(mol)$
$n_P : 4 = 0,05 < n_{O_2} :5 = 0,07$ nên $O_2$ dư

$n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)$
$\Rightarrow m_{O_2\ dư} = (0,35 - 0,25).32 = 3,2(gam)$

c) $n_{P_2O_5} = \dfrac{1}{2}n_P = 0,1(mol)$
$m_{P_2O_5} = 0,1.142 = 14,2(gam)$

\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\\a, 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ V\text{ì}:\dfrac{0,35}{5}>\dfrac{0,2}{4}\Rightarrow O_2d\text{ư}\\ n_{O_2\left(d\text{ư}\right)}=0,35-\dfrac{5}{4}.0,2=0,1\left(mol\right)\\b, m_{O_2\left(d\text{ư}\right)}=0,1.32=3,2\left(g\right)\\ c,n_{P_2O_5}=\dfrac{n_P}{2}=\dfrac{0,2}{2}=0,1\left(mol\right)\\ m_{r\text{ắn}}=m_{P_2O_5}=142.0,1=14,2\left(g\right)\)

nP = 3,1/31 = 0,1 (mol)

PTHH: 4P + 5O2 -t°-> 2P2O5

             0,1---> 0,125--->0,05

VO2 = 0,125 . 22,4 = 2,8 (l)

mP2O5 = 0,05 . 142 = 7,1 (g)

\(n_P=\dfrac{3,1}{31}=0,1mol\)

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

0,1     0,125   0,05

\(V_{O_2}=0,125\cdot22,4=2,8l\)  

\(m_{P_2O_5}=0,05\cdot142=7,1g\)

a,PTHH : \(4P+5O_2->2P_2O_5\)

b, 

Số mol O2 tham gia phản ứng :

nO2 = 5/4.n_P = 5/4 . 0,1 = 0,125 ( mol )

=> V O₂ phản ứng : 0,125 . 22,4 = 2,8 ( lít )

c,

Số mol P2O5 : n_p2o5 = 1/2.n_p = 0,05 ( mol )

=> m = 142 . 0,05 = 7,1 (g)

\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)

\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)

\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,1}{4}>\dfrac{0,1}{5}\) 
=> P dư 
\(n_{P\left(p\text{ư}\right)}=\dfrac{4}{5}n_{O_2}=0,08\left(mol\right)\\ m_{P\left(d\right)}=\left(0,1-0,08\right).31=0,62\left(g\right)\)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\)

PTHH: \(4P+5O_2\xrightarrow[]{t^o}2P_2O_5\)

bđ      0,1       0,1

pư     0,08     0,1

spư    0,02     0         

=> P dư

\(m_{P\left(dư\right)}=0,02.31=0,62\left(g\right)\)

a)

\(n_{O_2} = \dfrac{11,2}{22,4} = 0,5(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_P = \dfrac{4}{5}n_{O_2} = 0,4(mol)\\ \Rightarrow m_P = 0,4.31 = 12,4(gam)\)

b)

\(n_{P_2O_5} = \dfrac{2}{5}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{P_2O_5} = 0,2.142 = 28,4(gam)\)

c)

\(2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,5.2 = 1(mol)\\ \Rightarrow m_{KMnO_4} = 1.158 = 158(gam)\)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)

\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)

4P + 5O₂ \(\underrightarrow{t^o}\) 2P₂O₅

\(\dfrac{0,1}{4}< \dfrac{0,2}{5}\) => O₂ dư, Photpho đủ

\(n_{O_2}=0,2-0,04=0,16\left(mol\right)\)

\(m_{P_2O_5}=\) 0,05 . 142 = 7,1 ( g )

nP= 0.1 mol

nO2= 0.15 mol

4P + 5O2 -to-> 2P2O5

4____5

0.1___0.15

Lập tỉ lệ: 0.1/4 < 0.15/5 => O2 dư

nO2 dư= 0.15 - 0.125=0.025 mol

mO2 dư= 0.8g

nP2O5= 0.05 mol

mP2O5= 7.1g

nP=\(\dfrac{62}{31}\)=0,2(mol)

nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)

PTHH:4P+5O2to→2P2O5

tpứ:    0,2     0,35     

pứ:     0,2     0,25     0,1

spứ:     0     0,1         0,1

a)chất còn dư là oxi

mO2dư=0,1.32=3,2(g)

b)mP2O5=n.M=0,1.142=14,2(g)

\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)

a) n\(_P\) = \(\dfrac{6,2}{31}\) = 0,2(mol); n\(_{O_2}\) = \(\dfrac{7,84}{22,4}\) = 0,35(mol).

Theo phương trình hóa học:

\(4P+5O_2\) \(\underrightarrow{t^o}\) \(2P_2O_5\)

4        5          2 (mol)

0,2 \(\rightarrow\)0,25 \(\rightarrow\) 0,1(mol)

Tỉ lệ số mol: \(\dfrac{0,2}{4}< \dfrac{0,35}{5}\) \(\Rightarrow\) \(O_2\) phản ứng dư, P phản ứng hết.

\(n_{O_2}\)dư = 0,35 - \(\dfrac{0,2.5}{4}\) = 0,1(mol) \(\Rightarrow\) \(m_{O_2}\)dư = 0,1.32 = 3,2g

b) \(n_{P_2O_5}\) = 0,1.142 = 14,2g