PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết

\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)

+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\) 

a) Chất tham gia: Sắt (Fe), Oxi (O₂)

Sản phẩm: Sắt từ (Fe₃O₄)

b) Theo ĐLBTKL

 \(m_{Fe}+m_{O_2}=m_{Fe_3O_4}\) (1)

c) \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\); \(n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2\left(mol\right)\)

PTHH: 3Fe + 2O₂ --t^o--> Fe₃O₄

______0,2----------------->\(\dfrac{0,2}{3}\) ________(mol)

=> vô lí ...

gọi số mol Fe là x 
pthh : 3Fe + 2O2 --t---> Fe3O4 
          x---->\(\dfrac{2}{3}\)x----------> \(\dfrac{x}{3}\) 
=> mFe3O4= \(\dfrac{x}{3}\) . 232 = \(\dfrac{232x}{3}\) (G)
=> VO2 = \(\dfrac{2x}{3}\) . 22,4 = \(\dfrac{224x}{15}\) (L)

Số liệu ??

không có đâu bạn m như là x ấy 

\(n_{Fe_3O_4}=\dfrac{m_{Fe_3O_4}}{M_{Fe_3O_4}}=\dfrac{23,2}{232}=0,1mol\)

\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)

0,3       0,2              0,1          ( mol )

\(m_{Fe}=n_{Fe}.M_{Fe}=0,3.56=16,8g\)

\(V_{O_2}=n_{O_2}.22,4=0,2.22,4=4,48l\)

\(V_{kk}=\dfrac{4,48.100}{20}=22,4l\)

\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)

    0,4                                         0,2               ( mol )

\(n_{KMnO_4}=\dfrac{0,4}{85\%}=\dfrac{8}{17}mol\)

\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=\dfrac{8}{17}.158=74,3529g\)

3Fe+2O₂-to>Fe₃O₄

0,3------0,2-------0,1mol

n Fe3O4=\(\dfrac{23,2}{232}\)=0,1 mol

->m Fe=0,3.56=16,8g

b)

VO2=0,2.22,4=4,48l

=>Vkk=4,48.5=22,4l

c)2KMnO₄-to>K₂MnO₄+MnO₂+O₂

   0,4-------------------------------------0,2

=>m KMnO4=0,4.158.\(\dfrac{100}{85}\)=74,35g

a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)

Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)

\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)

c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H₂ dư.

Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)

\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)

\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)

\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)

2KClO₃ --to--> 2KCl + 3O₂

\(\dfrac{8}{45}\)                                \(\dfrac{4}{15}\)

\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)

a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)

PTHH: 3Fe + 2O₂ ---t^o---> Fe₃O₄

Mol:     0,4      \(\dfrac{0,8}{3}\)               \(\dfrac{0,4}{3}\)

b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)

c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)

d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)

e,

PTHH: 2KClO₃ ---t^o---> 2KCl + 3O₂

Mol:       \(\dfrac{0,16}{9}\)                            \(\dfrac{0,8}{3}\)

\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)

\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
=> pthh :\(3Fe+2O_2-t^o->Fe_3O_{\text{4 }}\)

             0,4       0,26              0,13 
=> \(V_{O_2}=0,26.22,4=5,973\left(L\right)\)
=> \(V_{KK}=5,973:\dfrac{1}{5}=29,86\left(L\right)\)
\(m_{Fe_3O_4}=0,13.232=30,16\left(g\right)\)
\(pthh:2KClO_3-t^o->2KCl+3O_2\)
           0,173                                0,26 
=> \(m_{KClO_3}=0,173.122,5=21,1925\left(G\right)\)

a)\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(m\right)\)

\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

tỉ lệ        :3         2        1

số mol   :0,3      0,2     0,1

\(V_{O_2}=0,2.22,4=4,48\left(l\right)\)

b)\(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)