`a)PTHH:`

`Mg + H_2 SO_4 -> MgSO_4 + H_2`

`0,2`                                   `0,2`      `0,2`        `(mol)`

`n_[Mg]=[4,8]/24=0,2(mol)`

`b)m_[MgSO_4]=0,2.120=24(g)`

`c)C%_[MgSO_4]=24/[4,8+50-0,2.2].100~~44,12%`

100.\(\approx\)

\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a.Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ m_{ddHCl}=\dfrac{0,4.36,5.100}{7,3}=200\left(g\right)\\ c.m_{ddsau}=4,8+200-0,2.2=204,4\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{204,4}.100\approx9,295\%\\ d.V_{ddHCl}=\dfrac{200}{1,05}=\dfrac{4000}{21}\left(ml\right)=\dfrac{4}{21}\left(l\right)\\ C_{MddHCl}=\dfrac{0,4}{\dfrac{4}{21}}=2,1\left(M\right)\)

\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)

PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)

                        0,1<----------------0,05-------------->0,05

\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)

\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)

PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)

bđ          0,1                 0,15

pư          0,1                 0,1

spư         0                     0,05                          0,1

\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)

Câu 2:

\(n_{MgBr_2}=\dfrac{14,72}{184}=0,08\left(mol\right)\\ Mg+Br_2\rightarrow MgBr_2\\ n_{Mg}=n_{Br_2}=n_{MgBr_2}=0,08\left(mol\right)\\ a=m_{Mg}=24.0,08=1,92\left(g\right)\\ m_{Br_2}=160.0,08=12,8\left(g\right)\)

Câu 1:

\(n_{AlBr_3}=\dfrac{106,8}{267}=0,4\left(mol\right)\\ 2Al+3Br_2\rightarrow2AlBr_3\\ n_{Al}=n_{AlBr_3}=0,4\left(mol\right)\\ n_{Br_2}=\dfrac{3}{2}.0,4=0,6\left(mol\right)\\ a=m_{Al}=0,4.27=10,8\left(g\right)\\ m_{Br_2}=160.0,6=96\left(g\right)\)

2Al+3Br₂-to>2AlBr₃

0,4-----0,6-------0,4 mol

n AlBr3=\(\dfrac{106,8}{267}\)=0,4 mol

=>a=mAl=0,4.27=10,8g

=>mBr₂=0,6.160=96g

Câu 2

Mg+Br₂->MgBr₂

0,08--0,08---0,08 mol

n _MgBr2=\(\dfrac{14,72}{184}\)=0,08 mol

=>a=mMg=0,08.24=1,92g

=>m _Br2=0,08.160=12,8g

\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)

PTHH: Fe₂O₃ + 3H₂SO₄ --> Fe₂(SO₄)₃ + 3H₂O

______0,05------>0,15--------->0,05

=> m_H2SO4 = 0,15.98 = 14,7(g)

=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)

\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)

PTHH: Fe₂(SO₄)₃ + 6NaOH --> 2Fe(OH)₃\(\downarrow\) + 3Na₂SO₄

________0,05----------------------->0,1

=> mFe(OH)₃ = 0,1.107=10,7(g)

a) Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

              0,0125<-----0,025------------>0,025------>0,0125

=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)

c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)

\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)

m CH3COOH=1,5g=>n=0,025 mol

2CH3COOH+Na2CO3->2CH3COONa+H2O+CO2

0,025--------------0,0125----------0,025

=>m Na2CO3=0,0125.106=1,325g

=>mdd=25g

c) 

C% =\(\dfrac{0,025.82}{25+25}100=4,1\%\)

nMg = 4,8 : 24 = 0,2 mol

a) Mg  +  H₂SO₄  →  MgSO₄  +   H₂

Theo tỉ lệ phản ứng => nH₂SO₄ phản ứng = nMgSO₄ = nH₂ = 0,2 mol

=> VH₂ = 0,2.22,4 = 4,48 lít.

b)

mH₂SO₄ phản ứng = 0,2.98 = 19,6 gam

=> C% _H2SO4 = \(\dfrac{19,6}{300}.100\text{%}\) = 6,53%

c) mMgSO₄ = 0,2.120 = 24 gam.

Đáp án B

2CH3COOH + Mg => (CH3COO)2Mg + H2

nH2 = V/22.4 = 13.44/22.4 = 0.6 (mol)

Theo phương trình ==> nCH3COOH = 1.2 (mol)

==> mCH3COOH = n.M = 1.2 x 60 = 72 (g)

C% = 72 x 100/200 = 36%

Theo phương trình ==> n(CH3COO)2Mg = 0.6 (mol)

==> m(CH3COO)2Mg = n.M = 142x0.6 = 85.2 (g)