Phần 1 : 

$m_{Cu} = 0,4(gam)$

Gọi $n_{Fe} = a ; n_{Al} = b \Rightarrow 56a + 27b + 0,4 = 1,5 : 2 = 0,75(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{H_2} = a + 1,5b = \dfrac{896}{1000.22,4} = 0,04(2)$

Từ (1)(2) suy ra a = -0,025 < 0$

$\to$ Sai đề

a) PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2

x___________3x______________1,5x(mol)

Fe +2 HCl -> FeCl2 + H2

y___2y____y______y(mol)

b) Ta có: m(rắn)= mCu=0,4(g)

=> m(Al, Fe)=1,5-mCu=1,5-0,4=1,1(g)

nH2= 0,04(mol)

Ta lập hpt:

\(\left\{{}\begin{matrix}27x+56y=1,1\\1,5x+y=0,04\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)

=> mAl=27.0,02=0,54(g)

mFe=56.0,01=0,56(g)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,Zn+2HCl\to ZnCl_2+H_2\\ b,n_{ZnCl_2}=0,1(mol)\\ \Rightarrow m_{ZnCl_2}=0,1.136=13,6(g)\\ c,n_{Zn}=0,1(mol)\\ \Rightarrow \%_{Zn}=\dfrac{0,1.65}{20}.100\%=32,5\%\\ \Rightarrow \%_{Ag}=100\%-32,5\%=67,5\%\)

áp dụng công thức là ra

PTHH:

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)

0,15                                                     0,15 

\(CaO+2HCl\rightarrow CaCl_2+H_2O\)

Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(\Rightarrow m_{CaCO_3}=0,15\cdot100=15\left(g\right)\)

\(\Rightarrow m_{CaO}=20,6-15=5,6\left(g\right)\)

\(\Rightarrow\%m_{CaCO_3}=\dfrac{15\cdot100}{20,6}\approx73\%\)

\(\Rightarrow\%m_{CaO}=100\%-73\%=27\%\)

\(n_{H_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(0.15.....0.3.......................0.15\)

\(m_{Mg}=0.15\cdot24=3.6\left(g\right)\)

\(m_{Cu}=10-3.6=6.4\left(g\right)\)

\(\%Mg=\dfrac{3.6}{10}\cdot100\%36\%\)

\(\%Cu=64\%\)

\(V_{dd_{HCl}}=\dfrac{0.3}{2}=0.15\left(l\right)\)

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)  (1)

            \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)  (2)

b) Ta có: \(\Sigma n_{H_2}=\dfrac{3,024}{22,4}=0,135\left(mol\right)\)

Gọi số mol của Fe là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\)

Gọi số mol của Al là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=\dfrac{3}{2}b\)

Ta lập được hệ phương trình:

\(\left\{{}\begin{matrix}a+\dfrac{3}{2}b=0,135\\56b+27b=4,14\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,045\\b=0,06\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,045\cdot56=2,52\left(g\right)\\m_{Al}=1,62\left(g\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{2,52}{4,14}\cdot100\%\approx60,87\%\\\%m_{Al}=39,13\%\end{matrix}\right.\)

c) PTHH: \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\downarrow\)

                \(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3\downarrow+3NaCl\)

             \(4Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\) 

             \(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)

Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe\left(OH\right)_2}=n_{FeCl_2}=0,045mol\\n_{Al\left(OH\right)_3}=n_{AlCl_3}=0,06mol\end{matrix}\right.\) 

\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,0225mol\\n_{Al_2O_3}=0,03mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=0,0225\cdot160=3,6\left(g\right)\\m_{Al_2O_3}=0,03\cdot102=3,06\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{chấtrắn}=3,06+3,6=6,66\left(g\right)\)

a)

\(n_{H_2\left(1\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 2Na + 2H₂O --> 2NaOH + H₂ (1)

             0,6<----------------------0,3

=> m_Na = 0,6.23 = 13,8 (g)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

            0,1<-0,2

=> m_Fe = 0,1.56 = 5,6 (g)

m_Cu = 10 (g)

\(\left\{{}\begin{matrix}\%Na=\dfrac{13,8}{13,8+5,6+10}.100\%=46,94\%\\\%Fe=\dfrac{5,6}{13,8+5,6+10}.100\%=19,05\%\\\%Cu=\dfrac{10}{13,8+5,6+10}.100\%=34,01\%\end{matrix}\right.\)

b)

PTHH: Fe_xO_y + yH₂ --t^o--> xFe + yH₂O

             \(\dfrac{0,3}{y}\)<--0,3

=> \(M_{Fe_xO_y}=\dfrac{17,4}{\dfrac{0,3}{y}}=58y\left(g/mol\right)\)

=> 56x = 42y

=> \(\dfrac{x}{y}=\dfrac{3}{4}\) => CTHH: Fe₃O₄