a, Giả sử: \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

⇒ 27x + 56y = 13,8 (1)

BTNT Al và Fe, có: \(\left\{{}\begin{matrix}n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}x\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{3}y\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\dfrac{1}{2}x.102+\dfrac{1}{3}y.232=21,8\left(g\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{13,8}.100\%\approx39,1\%\\\%m_{Fe}\approx60,9\%\end{matrix}\right.\)

b, BTNT O, có: \(n_{O_2}=\dfrac{3n_{Al_2O_3}+4n_{Fe_3O_4}}{2}=0,6\left(mol\right)\)

\(\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)

Bạn tham khảo nhé!

giúp tui với tui cần gấp

Gọi số mol Al, Na trong a gam hỗn hợp là x, y (mol)

=> 27x + 23y = a (1)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

             x---------------->0,5x

            4Na + O₂ --t^o--> 2Na₂O

              y---------------->0,5y

=> 102.0,5x + 62.0,5y = 1,64.a

=> 51x + 31y = 1,64a (2)

(1)(2) => 51x + 31y = 1,64(27x + 23y)

=> 6,72x = 6,72y

=> x = y

\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{27x}{27x+23y}.100\%=54\%\\\%m_{Na}=\dfrac{23y}{27x+23y}.100\%=46\%\end{matrix}\right.\)

PTHH: \(4FeS+7O_2\underrightarrow{t^o}2Fe_2O_3+4SO_2\)  (1)

            \(2ZnS+3O_2\underrightarrow{t^o}2ZnO+2SO_2\)  (2)

a) Gọi số mol của FeS là \(a\) \(\Rightarrow n_{Fe_2O_3}=\dfrac{1}{2}a\left(mol\right)\)

    Gọi số mol của ZnS là \(b\) \(\Rightarrow n_{ZnO}=b\left(mol\right)\)

Ta lập được hệ phương trình

\(\left\{{}\begin{matrix}88a+97b=54,6\\80a+81b=48,2\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,4\\b=0,2\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{FeS}=0,4\cdot88=35,2\left(g\right)\\m_{ZnS}=19,4\left(g\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{FeS}=\dfrac{35,2}{54,6}\cdot100\%\approx64,47\text{%}\\\%m_{ZnS}=35,53\%\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{O_2\left(1\right)}=\dfrac{7}{4}n_{FeS}=0,7\left(mol\right)\\n_{O_2\left(2\right)}=\dfrac{3}{2}n_{O_2\left(2\right)}=0,3\left(mol\right)\\n_{SO_2\left(1\right)}=n_{FeS}=0,4\left(mol\right)\\n_{SO_2\left(2\right)}=n_{ZnS}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\Sigma n_{O_2}=1\left(mol\right)\\\Sigma n_{SO_2}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=1\cdot22,4=22,4\left(l\right)\\V_{SO_2}=0,6\cdot22,4=13,44\left(l\right)\end{matrix}\right.\)

\(n_{Al} = a ; n_{Fe} = b\Rightarrow 27a + 56b = 27,6(1)\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{Al_2O_3} = \dfrac{1}{2}n_{Al} = 0,5a(mol)\\ n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = \dfrac{b}{3}(mol)\\ \Rightarrow 0,5a.102 + \dfrac{b}{3}232 = 43,6(2)\\ (1)(2) \Rightarrow a = 0,4 ; b = 0,3\\ m_{Al} = 0,4.27 = 10,8(gam) ; m_{Fe} = 0,3.56 = 16,8(gam)\)

Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)

\(m_{CuO}+m_{Fe_2O_3}=40\\ \Rightarrow80x+160y=40\left(1\right)\)

\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ \left(mol\right)......x\rightarrow.x\\ PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\\ \left(mol\right).....y\rightarrow....3y\\ V_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow x+3y=0,6\left(2\right)\)

\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}80x+160y=40\\x+3y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,1\end{matrix}\right.\)

a) \(\left\{{}\begin{matrix}m_{CuO}=80.0,3=24\left(g\right)\\m_{Fe_2O_3}=40-24=16\left(g\right)\end{matrix}\right.\)

b) \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=100\%-60\%=40\%\end{matrix}\right.\)

Đặt \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo đề: \(m_{hh}=39\left(g\right)\)

\(\Rightarrow m_{Al}+m_{Fe}=39\\ \Rightarrow27x+56y=39\left(1\right)\)

\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ \left(mol\right)....x\rightarrow..0.75x....0,5x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow..\dfrac{2}{3}y.....\dfrac{1}{3}y\)

Theo đề: \(n_{O_2}=\dfrac{V}{22,4}=\dfrac{12,32}{22,4}=0,55\left(mol\right)\)

\(\Rightarrow0,75x+\dfrac{2}{3}y=0,55\left(2\right)\)

\(\xrightarrow[\left(1\right)]{\left(2\right)}\left\{{}\begin{matrix}27x+56y=39\\0,75x+\dfrac{2}{3}y=0,55\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,6\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,6.56=33,6\left(g\right)\end{matrix}\right.\\ m_r=m_{Al_2O_3}+m_{Fe_3O_4}=0,5.0,2.102+\dfrac{1}{3}.0,6.232=56,6\left(g\right)\)

a, \(2Cu+O_2\underrightarrow{t^o}2CuO\)

\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

b, Theo ĐLBT KL, có: m_X + m_O2 = m _oxit

⇒ m_O2 = 18,2 - 11,8 = 6,4 (g)

c, Ta có: 64n_Cu + 27n_Al = 11,8 (1)

Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Cu}+\dfrac{3}{4}n_{Al}=\dfrac{6,4}{32}=0,2\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu}=0,1\left(mol\right)\\n_{Al}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,1.64}{11,8}.100\%\approx54,24\%\\\%m_{Al}\approx45,76\%\end{matrix}\right.\)