\(a,n_{Zn}=\dfrac{0,65}{65}=0,01\left(mol\right)\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

          0,01--->0,02---->0,01---->0,01

\(V_{H_2}=0,01.22,4=0,224\left(l\right)\\ b,m_{ZnCl_2}=0,01.136=1,36\left(g\right)\\ V_{ddHCl}=\dfrac{0,02}{2}=0,01\left(l\right)\)

Câu 4:

a, \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PT: \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

Theo PT: \(n_{CH_3COOH}=2n_{H_2}=0,5\left(mol\right)\Rightarrow V_{CH_3COOH}=\dfrac{0,5}{2,5}=0,2\left(l\right)\)

b, \(n_{\left(CH_3COO\right)_2Zn}=n_{H_2}=0,25\left(mol\right)\)

\(\Rightarrow m_{\left(CH_3COO\right)_2Zn}=0,25.183=45,75\left(g\right)\)

\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=2\cdot0,15=0,3\left(mol\right)\)

Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên sau p/ứ Zn dư

\(\Rightarrow n_{Zn}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\\ \Rightarrow m_{Zn}=0,15\cdot65=9,75\\ \Rightarrow m_{Zn\left(dư\right)}=13-9,75=3,25\left(g\right)\\ c,n_{H_2}=n_{Zn}=0,15\left(mol\right)\\ \Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b, \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)

c, \(n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\Rightarrow m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)

`n_[Zn]=13/65=0,2(mol)`

`Zn + 2HCl -> ZnCl_2 + H_2 \uparrow`

`0,2`  `0,4`                            `0,2`           `(mol)`

`a)V_[H_2]=0,2.22,4=4,48(l)`

`b)C%_[HCl]=[0,4.36,5]/150 .100~~9,73%`

a,\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:    0,15     0,3

Ta có: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) ⇒ H₂ pứ hết,Fe dư

\(V_{H_2}=3,36\left(l\right)\) (đề cho)

b, ko tính đc k/lg dd ,chỉ tính đc thể tích dd

\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)

\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)

a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)

n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)

PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)

            0,2     0,5

Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)

n\(Zn\) hết , n\(HCl\) dư

-->Tính theo số mol hết

               Zn + 2HCl->ZnCl\(2\) + H\(2\)

              0,2 ->  0,4      0,2        0,2

n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)

m​\(HCl\) dư= 0,1.36,5 = 3,65(g)

b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)

c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)

d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)

 3H2 +Fe2O3 → 2Fe + 3H2O

  0,2       0,12

Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)

    nH2 hết .Tính theo số mol hết

\(HCl\)

​ 3H2 +Fe2O3 → 2Fe + 3H2O

0,2->                  0,2

m\(Fe\)=n.M= 0,2.56= 11,2(g)