Bài 1:

a) CuSO₄ + 2NaOH → Na₂SO₄ + Cu(OH)₂↓

\(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)

Theo PT: \(n_{CuSO_4}=\dfrac{1}{2}n_{NaOH}\)

Theo bài: \(n_{CuSO_4}=\dfrac{1}{3}n_{NaOH}\)

Vì \(\dfrac{1}{3}< \dfrac{1}{2}\) ⇒ NaOH dư

b) Theo PT: \(n_{Cu\left(OH\right)_2}=m_{CuSO_4}=0,1\left(mol\right)\)

\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1\times98=9,8\left(g\right)\)

c) \(\Sigma V_{dd}saupư=40+60=100\left(ml\right)=0,1\left(l\right)\)

Theo PT: \(n_{NaOH}pư=2n_{CuSO_4}=2\times0,1=0,2\left(mol\right)\)

\(\Rightarrow n_{NaOH}dư=0,3-0,2=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{NaOH}}dư=\dfrac{0,1}{0,1}=1\left(M\right)\)

Theo PT: \(n_{Na_2SO_4}=n_{CuSO_4}=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,1}{0,1}=1\left(M\right)\)

Bài 2:

ZnCl₂ + 2NaOH → 2NaCl + Zn(OH)₂↓ (1)

\(n_{ZnCl_2}=0,3\times1,5=0,45\left(mol\right)\)

\(n_{NaOH}=0,1\times1=0,1\left(mol\right)\)

Theo PT1: \(n_{ZnCl_2}=\dfrac{1}{2}n_{NaOH}\)

Theo bài: \(n_{ZnCl_2}=\dfrac{9}{2}n_{NaOH}\)

Vì \(\dfrac{9}{2}>\dfrac{1}{2}\) ⇒ ZnCl₂ dư

a) \(\Sigma V_{dd}saupư=300+100=400\left(ml\right)=0,4\left(l\right)\)

Theo PT1: \(n_{ZnCl_2}pư=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}\times0,1=0,05\left(mol\right)\)

\(\Rightarrow n_{ZnCl_2}dư=0,45-0,05=0,4\left(mol\right)\)

\(\Rightarrow C_{M_{ZnCl_2}}dư=\dfrac{0,4}{0,4}=1\left(M\right)\)

Theo PT1: \(n_{NaCl}=n_{NaOH}=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,1}{0,4}=0,25\left(M\right)\)

b) Zn(OH)₂ \(\underrightarrow{to}\) ZnO + H₂O (2)

Theo pT1: \(n_{Zn\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}\times0,1=0,05\left(mol\right)\)

Theo pT2: \(n_{ZnO}=n_{Zn\left(OH\right)_2}=0,05\left(mol\right)\)

\(\Rightarrow m_{ZnO}=0,05\times81=4,05\left(g\right)\)

c) NaOH + HCl → NaCl + H₂O (3)

Theo PT: \(n_{HCl}=n_{NaOH}=0,1\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,1\times36,5=3,65\left(g\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{3,65}{25\%}=14,6\left(g\right)\)

\(n_{BaCl_2}=\dfrac{41,6}{208}=0,2\left(mol\right)\)

\(n_{AgNO_3}=\dfrac{17}{170}=0,1\left(mol\right)\)

\(BaCl_2+2AgNO_3\rightarrow Ba\left(NO_3\right)_2+2AgCl\)

\(\dfrac{0,2}{1}>\dfrac{0,1}{2}\) ⇒ BaCl2 dư.

a, \(n_{AgCl}=n_{AgNO_3}=0,1\left(mol\right)\)

\(\Rightarrow m_{AgCl}=0,1.143,5=14,35\left(g\right)\)

b, \(n_{Ba\left(NO_3\right)_2}=\dfrac{1}{2}n_{AgNO_3}=0,05\left(mol\right)\) 

\(C_{M_{Ba\left(NO_3\right)_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(n_{BaCl_2phan/ung}=\dfrac{1}{2}n_{AgNO_3}=0,05\left(mol\right)\)

\(\Rightarrow n_{BaCl_2dư}=0,15\left(mol\right)\rightarrow C_{M\left(BaCl_2\right)}=\dfrac{0,15}{0,2}=0,75\left(M\right)\)

\(n_{Zn}=\dfrac{13}{65}=0,2mol\)

\(n_{H_2SO_4}=0,04.1=0,04mol\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

0,2  >   0,04                              ( mol )

0,04       0,04            0,04     0,04     ( mol )

\(m_{ZnSO_4}=0,04.161=6,44g\)

Câu b ko hiểu lắm bạn ơi!

a) $CuSO_4 + 2NaOH \to Cu(OH)_2 + Na_2SO_4$

b) $n_{Cu(OH)_2} = n_{CuSO_4} = \dfrac{16}{160} = 0,1(mol)$
$m_{Cu(OH)_2} = 0,1.98 = 9,8(gam)$

c) $n_{NaOH} = 2n_{CuSO_4} = 0,2(mol) \Rightarrow C_{M_{NaOH}} = \dfrac{0,2}{0,1} = 2M$

PTHH: \(CuSO_4+2NaOH\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

Ta có: \(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2\left(M\right)\\m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\end{matrix}\right.\)

\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)

nHCl=0,6 mol

FeO+2HCl-->FeCl2+ H2O

x mol               x mol

Fe2O3+6HCl-->2FeCl3+3H2O

x mol                   2x mol

72x+160x=11,6         =>x=0,05 mol

A/ C_FeCl2=0,05/0,3=1/6 M

CFeCl3=0,1/0,3=1/3 M

CHCl du=(0,6-0,4)/0,3=2/3 M

B/ 

NaOH+ HCl-->NaCl+H2O

0,2          0,2

2NaOH+FeCl2-->2NaCl+Fe(OH)2

0,1           0,05

3NaOH+FeCl3-->3NaCl+Fe(OH)3

0,3            0,1

nNaOH=0,6

CNaOH=0,6/1,5=0,4M

Câu 1 bạn biết làm k chỉ mình với

Gọi CT của oxit KL là M2Om 
=> %M = 2M/(2M + 16m) = 85.22% 
<=> M = 46.13m --> ko có KLoại quen thuộc (chỉ có m=2, M = 92.26 ~ Nb = 92.9) 
Tuy nhiên, ta ko cần tìm M mà vẫn tính dc (nhưng bạn vẫn nên xem lại đề nhé)
M2Om + mH2SO4 ---> M2(SO4)m + mH2O 
n(M2Om) = 10/(2M + 16m) = 10/(2*46.13m + 16m) = 10/108.26m 
--> nH2SO4 = m*10/108.26m = 10/108.26 ~ 0.0924 mol 
=> mddH2SO4 = 0.0924*98/0.1 = 90.55g

a) \(NaOH+HCl\rightarrow NaCl+H_2O\)

0,1................0,3

LẬp tỉ lệ : \(\dfrac{0,1}{1}< \dfrac{0,3}{1}\)=> Sau pứ HCl dư

\(m_{NaCl}=0,1.58,5=5,85\left(g\right)\)

b) \(CM_{NaCl}=\dfrac{0,1}{0,2+0,3}=0,2M\)

\(CM_{HCl\left(dư\right)}=\dfrac{\left(0,3-0,1\right)}{0,2+0,3}=0,4M\)