\(CaCO_3\rightarrow\left(t^o\right)CaO+CO_2\\ CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ m_{BaCO_3}=17,73\left(g\right)\Rightarrow n_{BaCO_3}=0,09\left(mol\right)\\ n_{Ba\left(OH\right)_2}=n_{BaCO_3}=0,09\left(mol\right)\\ V=V_{ddBa\left(OH\right)_2}=\dfrac{0,09}{2}=0,045\left(l\right)\)

- Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\Rightarrow27a+24b=10,2\left(1\right)\)

Khí thu được sau p/ứ là khí H₂: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

2                                         3       (mol)

a                                        3/2 a   (mol)

\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

1                                        1   (mol)

b                                         b   (mol)

Từ hai PTHH trên ta có: \(\dfrac{3}{2}a+b=0,5\left(2\right)\)

\(\left(1\right),\left(2\right)\) ta có hệ: \(\left\{{}\begin{matrix}27a+24b=10,2\\\dfrac{3}{2}a+b=0,5\end{matrix}\right.\)

Giải ra ta có \(\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)

a) \(\%Al=\dfrac{m_{Al}}{m_{hh}}.100\%=\dfrac{0,2.27}{10,2}.100\%\approx52,94\%\)

\(\%Mg=100\%-\%Al=100\%-52,94=47,06\%\)

b)

 \(3H_2+Fe_2O_3\rightarrow^{t^0}2Fe+3H_2O\)

3               1              2  (mol)

0,5            1/6         1/3  (mol)

\(m_{Fe}=\dfrac{1}{3}.56=\dfrac{56}{3}\left(g\right)\)

\(m_{Fe_2O_3\left(pứ\right)}=\dfrac{1}{6}.160=\dfrac{80}{3}\left(g\right)\)

\(m_{Fe_2O_3\left(dư\right)}=60-m_{Fe}=60-\dfrac{56}{3}=\dfrac{124}{3}\left(g\right)\)

\(a=\dfrac{124}{3}+\dfrac{80}{3}=68\left(g\right)\)

a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)

⇒ m_FeO = 12,6 - 5,4 = 7,2 (g)

c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?

d, Cho hh vào dd H₂SO₄ đặc nguội thì có khí thoát ra.

PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)

Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)

Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)

\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)

a. \(n_{CO_2}=0,02\left(mol\right);n_{Ca\left(OH\right)_2}=0,008\left(mol\right)\Rightarrow n_{OH^-}=0,016\\ Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,016}{0,02}=0,8\Rightarrow ChỉtạoCa\left(HCO_3\right)_2,CO_2dư\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2+H_2O\\ n_{Ca\left(HCO_3\right)_2}=n_{Ca\left(OH\right)_2}=0,016\left(mol\right)\\ \Rightarrow CM_{Ca\left(HCO_3\right)_2}=\dfrac{0,016}{0,4}=0,04M\)

\(b.n_{SO_2}=0,18\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{OH^-}=0,4\left(mol\right)\\Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,4}{0,18}=2,22\Rightarrow Ba\left(OH\right) _2dư\\ SO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{Ba\left(OH\right)_2dư}=0,2-0,18=0,02\left(mol\right)\\ \Rightarrow CM_{Ba\left(OH\right)_2dư}=\dfrac{0,02}{0,2}=0,1M\)

\(4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O\\ Ta\ có :\\ m_O = m_B - m_{hh} = 5,4 - 4,44 = 0,96(mol)\\ n_O = \dfrac{0,96}{32} = 0,03(mol)\\ \Rightarrow n_{Al_2O_3}= \dfrac{1}{3}n_O = 0,01(mol)\\ \Rightarrow n_{Al} = 2n_{Al_2O_3} = 0,02(mol)\\ m_{Al} = 0,02.54 = 1,08(gam)\\ m_{Fe} = 4,44 - 1,08 = 3,36(gam)\)

$n_{CH_3COOC_2H_5} = \dfrac{8,8}{88} = 0,1(mol)$
$n_{NaOH} = 0,2.2 = 0,4(mol) > n_{este}$ nên NaOH dư
$CH_3COOC_2H_5 + NaOH \to CH_3COONa + C_2H_5OH$

$n_{C_2H_5OH} = n_{este} = 0,1(mol)$
Bảo toàn khối lượng : 

$m_{chất\ rắn} = 8,8 + 0,4.40 - 0,1.46 = 20,2(gam)$

nCH3COONa = nCH3COOC2H5 = 0,1 (mol) 

=> m rắn = m CH3COONa + mNaOH dư = 20,2 (g)

Ta có: $n_{CH_3COOC_2H_5}=0,1(mol);n_{NaOH}=0,4(mol)$

$\Rightarrow n_{C_2H_5OH}=0,1(mol)$

Bảo toàn khối lượng ta có: $m_{ran}=20,2(g)$

Theo gt ta có: $n_{C_3H_5COOCH_3}=0,086(mol);n_{NaOH}=0,04(mol)$

$\Rightarrow n_{CH_3OH}=0,04(mol)$

Bảo toàn khối lượng ta có: $m_{chatran}=8,92(g)$

$n_{este} = \dfrac{8,6}{86} = 0,1(mol)$
$n_{NaOH} = 0,2.0,2 = 0,04 < n_{este}$ nên Este dư

$C_2H_3COOCH_3 + NaOH \to C_2H_3COONa + CH_3OH$
$n_{C_2H_3COONa} = n_{NaOH} = 0,04(mol)$
$m_{chất\ rắn} = 0,04.94 = 3,76(gam)$

3,28 gam

CO2+2NaOH->Na2CO3+H2O

0,2-------0,4---------0,2--------0,2

n CO2=4,48\22,4=0,2 mol

=>Cm NaOH=0,4\0,1=4M

=>m Na2CO3=0,2.106=21,2g

a, \(n_{CuO}=\dfrac{48}{80}=0,6\left(mol\right)\)

Gọi: n_{CuO (pư)} = x (mol)

⇒ n_{CuO (dư)} = 0,6 - x (mol)

\(CuO+CO\underrightarrow{t^o}Cu+CO_2\)

Theo PT: \(n_{Cu}=n_{CuO\left(pư\right)}=x\left(mol\right)\)

X gồm: Cu và CuO dư.

⇒ m_Cu + m_{CuO (dư)} = 40,8 ⇒ 64x + 80.(0,6-x) = 40,8 ⇒ x = 0,45 (mol)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,45.64}{40,8}.100\%\approx70,59\%\\\%m_{CuO\left(dư\right)}\approx29,41\%\end{matrix}\right.\)

b, \(H\%=\dfrac{0,45}{0,6}.100\%=75\%\)

c, Gọi CTHH cần tìm là Fe_xO_y.

PT: \(Fe_xO_y+yCO\underrightarrow{t^o}xFe+yCO_2\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)

\(n_{CaCO_3}=\dfrac{22,5}{100}=0,225\left(mol\right)\)

Theo PT: \(n_{Fe_xO_y}=\dfrac{1}{y}n_{CO_2}=\dfrac{1}{y}n_{CaCO_3}=\dfrac{0,225}{y}\left(mol\right)\)

\(\Rightarrow M_{Fe_xO_y}=\dfrac{12}{\dfrac{0,225}{y}}=\dfrac{160}{3}y\left(g/mol\right)\)

Mà: \(M_{Fe_xO_y}=56x+16y\left(g/mol\right)\)

\(\Rightarrow56x+16y=\dfrac{160}{3}y\Rightarrow\dfrac{x}{y}=\dfrac{2}{3}\)

Vậy: CTHH cần tìm là Fe₂O₃

Sau phản ứng còn lại gì bạn nhỉ?