\(S+O_2\underrightarrow{^{to}}SO_2\\ n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ n_{S\left(LT\right)}=n_{SO_2}=0,6\left(mol\right)\\ n_{S\left(TT\right)}=0,6:75\%=0,8\left(mol\right)\\ m_{S\left(TT\right)}=0,8.32=25,6\left(g\right)\)

S+O2-to>SO2

0,6-----------0,6 mol

n SO2=13,44\22,4=0,6 mol

=>H=75%

=>m S=0,6.32.100\75=25,6g

\(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: S + O₂ ---t^o→ SO₂

Mol:    0,6                      0,6

\(m_{S\left(lt\right)}=0,6.32=19,2\left(g\right)\)

\(\Rightarrow m_{S\left(tt\right)}=\dfrac{19,2}{75}.100=25,6\left(g\right)\)

\(n_{SO2}=\dfrac{6,4}{64}=0,1\left(mol\right)\)

Pt : \(S+O_2\rightarrow\left(t_o\right)SO_2|\)

      1       1                1

     0,1    0,1

\(n_{O2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

\(V_{O2\left(lt\right)}=0,1.22,4=2,24\left(l\right)\)

⇒ \(V_{O2\left(tt\right)}=\dfrac{2,24.100}{80}=2,8\left(l\right)\)

 Chúc bạn học tốt

S+O2-to>SO2

0,2----------0,2 mol

n S=6,4\32=0,2 mol

H=80%

VSO2=0,2.22,4.80\100=3.584l

\(n_S=\dfrac{6,4}{32}=0,2\left(mol\right)\)

PTHH: S + O₂ ---t^o→ SO₂

Mol:    0,2                    0,2

\(V_{SO_2\left(lt\right)}=0,2.22,4=4,48\left(l\right)\)

\(V_{SO_2\left(tt\right)}=4,48.80\%=3,584\left(l\right)\)

2KMnO4-to>K2MnO4+MnO2+O2

1,2-------------------------------------0,6 mol

n O2=13,44\22,4=0,6 mol

H =75%

=>m KMnO4 tt= 1,2.158 .100\75=252,8g

\(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: 2KMnO₄ ---t^o→ K₂MnO₄ + MnO₂ + O₂

Mol:       1,2                                                    0,6

\(m_{KMnO_4\left(lt\right)}=1,2.158=189,6\left(g\right)\Rightarrow m_{KMnO_4\left(tt\right)}=\dfrac{189,6}{75}.100=252,8\left(g\right)\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

\(\Rightarrow n_{KMnO_4}=\dfrac{2n_{O_2}}{75\%}=\dfrac{2.13,44.100}{22,4.75}=1,6\left(mol\right)\)

\(\Rightarrow a=m_{KMnO_4}=1,6.158=252,8\left(g\right)\)

\(PTHH:4P+5O_2-^{t^o}>2P_2O_5\)

áp dụng ĐLBTKL ta có

\(m_P+m_{O_2}=m_{P_2O_5}\\ =>m_{O_2}=m_{P_2O_5}-m_P\\ =>m_{O_2}=7,1-3,1\\ =>m_{O_2}=4\left(g\right)\)

a) $\rm 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
b) Áp dụng ĐLBTKL:
$\rm m_P + m_{O_2} = m_{P_2O_5}$
$\rm \Rightarrow m_{O_2} = m_{P_2O_5} - m_P = 7,1 - 3,1 = 4 (g)$

a) $n_P = \dfrac{12,4}{31} = 0,4(mol) ; n_{O_2} = \dfrac{13,44}{22,4} = 0,6(mol)$

$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$

Ta thấy : 

$n_P : 4 < n_{O_2} : 5$ nên $O_2$ dư

 Điphotpho pentaoxit được tạo thành

$n_{P_2O_5} = \dfrac{1}{2}n_P = 0,2(mol)$
$m_{P_2O_5} = 0,2.142 = 28,4(gam)$

\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ 3Fe+2O_2\underrightarrow{^{to}}Fe_3O_4\\ Vì:\dfrac{0,6}{2}>\dfrac{0,3}{3}\Rightarrow O_2dư\\ n_{Fe_3O_4\left(LT\right)}=\dfrac{0,3}{3}=0,1\left(mol\right)\\ n_{Fe_3O_4\left(TT\right)}=\dfrac{18,56}{232}=0,08\left(mol\right)\\ H=\dfrac{0,08}{0,1}.100=80\%\)

a) $n_P = \dfrac{6,2}{31} = 0,2(mol) ; n_{O_2} = \dfrac{6,4}{32} = 0,2(mol)$

$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
$n_{P\ pư} = \dfrac{4}{5}n_{O_2} = 0,16(mol)$
$\Rightarrow m_{P\ dư} = 6,2 -0,16.31 = 1,24(gam)$

b) Sản phẩm là $P_2O_5$
$n_{P_2O_5} = \dfrac{2}{5}n_{O_2} = 0,08(mol)$
$m_{P_2O_5} = 0,08.142 = 11,36(gam)$

Đặt \(\left\{{}\begin{matrix}n_{CO_2}=a\left(mol\right)\\n_{H_2O}=b\left(mol\right)\end{matrix}\right.\)

Ta thấy các chất đều có công thức C_nH_2n+2O \(\Rightarrow n_{O\left(hỗnhợp\right)}=n_{H_2O}-n_{CO_2}\)

\(\Rightarrow n_{O\left(ancol\right)}=b-a\)

Ta có: \(m_{hh}=m_C+m_H+m_O=9,2\left(g\right)\) \(\Rightarrow a+2b+16\left(b-a\right)=9,2\)  (1)

Mặt khác: \(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Bảo toàn oxi: \(\left(b-a\right)+2\cdot0,6=2a+b\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=n_{CO_2}=0,4\left(mol\right)\\b=n_{H_2O}=\dfrac{38}{45}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,4\cdot22,4=8,96\left(l\right)\\m_{H_2O}=15,2\left(g\right)\end{matrix}\right.\)

4P + 5O₂ -----to---> 2P₂O₅

0,4---0,5-----------> 0,2 (mol)

+ n _P = 12,4 / 31 = 0,4 (mol)

+nO2 = 13,44 / 22,4 = 0,6 (mol)

Vì n_P/4 = 0,1 < n _O2 /5 = 0,12

=> Oxi còn thừa sau phản ứng .

m_{O2 dư} = (0,6 - 0,5 ) . 32 = 3,2 (g)

b. chất tạo thành : P₂O₅

m_P2O5 = 0,2 . ( 2.31 + 16 . 5 ) = 28,4 (g)

\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\ n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,4}{4}< \dfrac{0,6}{5}\) 
=> Oxi dư 
\(n_{O_2\left(p\text{ư}\right)}=\dfrac{5}{4}n_P=0,5\left(mol\right)\\ m_{O_2\left(d\right)}=\left(0,6-0,5\right).32=3,2\left(g\right)\\ n_{P_2O_5}=\dfrac{1}{2}n_P=0,2\left(mol\right)\\ m_{P_2O_5}=0,2.142=28,4\left(g\right)\)