\(n_{HCl}=0,3.1=0,3mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

0,1        0,3                        0,15  ( mol )

\(m_{Al}=0,1.27=2,7g\)

\(\Rightarrow m_{Al}=9,1.2,7=6,4g\)

\(V_{H_2}=0,15.22,4=3,36l\)

nHCl = 0,3 . 1 = 0,3 (mol)

PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2

Mol: 0,1 <--- 0,3 ---> 0,1 ---> 0,15

mAl = 0,1 . 27 = 2,7 (g(

mCu = 9,1 - 2,7 = 6,4 (g)

VH2 = 0,15 . 22,4 = 3,36 (l)

a) Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow27a+56b=11\)  (1)

Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Bảo toàn electron: \(3a+2b=0,4\cdot2=0,8\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{11}\cdot100\%\approx49,09\%\\\%m_{Fe}=50,91\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{muối}=m_{AlCl_3}+m_{FeCl_2}=0,2\cdot133,5+0,1\cdot127=39,4\left(g\right)\)

c) Bảo toàn electron: \(3\cdot0,2+3\cdot0,1=2n_{SO_2}\)

\(\Rightarrow n_{SO_2}=0,45\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,45\cdot22,4=10,08\left(l\right)\)

a) Gọi nAl = x, nFe = y

Có 27x + 56y = 11 (1)

Bảo toàn e

3x + 2y = 2.0,4 (2)

Từ 1 và 2 => x = 0,2, y = 0,1

\(\%mAl=\dfrac{0,2.27}{11}.100\%=49,09\%\)

\(\%mFe=100-49,09=50,91\%\)

b) BTKL: 

m muối = mkim loại + mHCl - mH2

= 11 + 0,4.2.36,5 - 0,4.2 = 39,4g

c) 

Bảo toàn e

Al => Al⁺³ + 3e                                  S⁺⁶ + 2e => S⁺⁴

0,2               0,6                                             2x          x

Fe => Fe⁺³ + 3e

0,1                  0,3

=> 2x = 0,6 + 0,3 => x = 0,45 mol

=> VSO₂ = 0,45.22,4 = 10,08 lít

a) Gọi số mol Mg, Fe là a, b (mol)

=> 24a + 56b = 11,84

\(n_{HCl}=\dfrac{146.14\%}{36,5}=0,56\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

            a--->2a--------->a----->a

           Fe + 2HCl --> FeCl₂ + H₂

            b-->2b-------->b------>b

=> 2a + 2b = 0,56

=> a = 0,12; b = 0,16

=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{0,12.24}{11,84}.100\%=24,324\%\\\%Fe=\dfrac{0,16.56}{11,84}.100\%=75,676\%\end{matrix}\right.\)

b) \(n_{H_2}=a+b=0,28\left(mol\right)\)

=> \(V_{H_2}=0,28.22,4=6,272\left(l\right)\)

c) m_{dd sau pư} = 11,84 + 146 - 0,28.2 = 157,28 (g)

=> \(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,12.95}{157,28}.100\%=7,25\%\\C\%_{FeCl_2}=\dfrac{0,16.127}{157,28}.100\%=12,92\%\end{matrix}\right.\)

a)

Gọi : \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)⇒ 27a + 56b = 1,66(1)

\(2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe +2 HCl \to FeCl_2 + H_2\)

Theo PTHH :

\(n_{H_2} = 1,5a + b = \dfrac{1,12}{22,4} = 0,05(2)\)

Từ (1)(2) suy ra a = 0,02 ; b = 0,02

Vậy :

\(\%m_{Al} = \dfrac{0,02.27}{1,66}.100\% = 32,53\%\\ \%m_{Fe} = 100\% - 32,53\% = 67,47\%\)

a)

\(n_{HCl} = 2n_{H_2} = 0,05.2 = 0,1(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,1.36,5}{100}.100\% = 3,65\%\)

Gọi $n_{Fe} = a(mol) ; n_{Al} = b(mol)$

$\Rightarrow 56a + 27b = 11(1)$

$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{H_2} = a + 1,5b = 8,96 : 22,4 = 0,4(2)$
Từ (1)(2) suy ra a = 0,1 ; b = 0,2

Vậy :

$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,91\%$
$\%m_{Al} = 100\% -50,91\% = 49,09\%$

\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)

\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)

\(a) n_{Mg}= a(mol) ; n_{Al} = b(mol) \Rightarrow 24a + 27b =2,55(1)\\ Mg + 2HCl \to MgCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ n_{H_2} = a + 1,5b = \dfrac{2,8}{22,4}=0,125(2)\\ (1)(2) \Rightarrow a = b = 0,05\\ \%m_{Mg} = \dfrac{0,05.24}{2,55}.100\% = 47,06\%\ ;\ \%m_{Al} =100\% -47,06\% = 52,94\%\\ b) n_{HCl} = 2n_{H_2} = 0,125.2 = 0,25(mol)\\ m_{dd\ HCl} = \dfrac{0,25.36,5}{7,3\%} = 125(gam)\\ V_{dd\ HCl} = \dfrac{125}{1,2} = 104,17(ml)\)

\(a,n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,2mol\\ m_{Fe}=0,2.56=11,2g\\ m_{Cu}=25-11,2=13,8g\\ b,\%m_{Fe}=\dfrac{11,2}{25}\cdot100=44,8\%\\ \%m_{Cu}=100-44,8=55,2\%\)
c, Gọi CTHH của sắt là \(Fe_xO_y\)

\(Fe_xO_y+yH_2\xrightarrow[t^0]{}xFe+yH_2O\\ \Rightarrow n_{Fe_xO_y}=n_{H_2}:y\\ \Leftrightarrow\dfrac{11,6}{56x+16y}=\dfrac{0,2}{y}\\ \Leftrightarrow11,6y=11,2x+3,2y\\ \Leftrightarrow11,6y-3,2y=11,2x\\ \Leftrightarrow8,4y=11,2x\\ \Leftrightarrow\dfrac{x}{y}=\dfrac{8,4}{11,2}=\dfrac{3}{4}\\ \Rightarrow x=3;y=4\\ \Rightarrow CTHH:Fe_3O_4\)