Đặt \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo đề: \(m_{hh}=39\left(g\right)\)

\(\Rightarrow m_{Al}+m_{Fe}=39\\ \Rightarrow27x+56y=39\left(1\right)\)

\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ \left(mol\right)....x\rightarrow..0.75x....0,5x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow..\dfrac{2}{3}y.....\dfrac{1}{3}y\)

Theo đề: \(n_{O_2}=\dfrac{V}{22,4}=\dfrac{12,32}{22,4}=0,55\left(mol\right)\)

\(\Rightarrow0,75x+\dfrac{2}{3}y=0,55\left(2\right)\)

\(\xrightarrow[\left(1\right)]{\left(2\right)}\left\{{}\begin{matrix}27x+56y=39\\0,75x+\dfrac{2}{3}y=0,55\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,6\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,6.56=33,6\left(g\right)\end{matrix}\right.\\ m_r=m_{Al_2O_3}+m_{Fe_3O_4}=0,5.0,2.102+\dfrac{1}{3}.0,6.232=56,6\left(g\right)\)

PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,2mol\\n_{Fe_3O_4}=0,1mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_3O_4}=0,1\cdot232=23,2\left(g\right)\\V_{O_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)

Cu khong tác dụng với O2

=> nO2=6,72:22,4=0,3mol

PTHH: 3Fe+2O2=> Fe3O4

          0,45mol<-0,3mol

=> mFe=0,45.56=25,2

=> m chất rắn là mCu= 29,6-25,2=4,4g

a) Gọi số mol Al, Zn là 2a, a (mol)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

          2a-->1,5a---------->a

             2Zn + O₂ --t^o--> 2ZnO

            a---->0,5a------->a

=> \(102a+81a=18,3\)

=> a = 0,1 (mol)

=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{0,2.27+0,1.65}.100\%=45,378\%\\\%m_{Zn}=\dfrac{0,1.65}{0,2.27+0,1.65}.100\%=54,622\%\end{matrix}\right.\)

b) \(n_{O_2}=1,5a+0,5a=0,2\left(mol\right)\)

=> \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)

\(m_{Al}=27,8.19,2\%=5,4\left(g\right)\\ m_{Fe}=27,8-5,4=22,4\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\end{matrix}\right.\)

PTHH:

4Al + 3O₂ --t^o--> 2Al₂O₃

0,2-->0,15------->0,1

3Fe + 2O₂ --t^o--> Fe₃O₄

0,4-->4/15--------->2/15

\(\rightarrow\left\{{}\begin{matrix}V_{kk}=\left(0,15+\dfrac{4}{15}\right).22,4.5=\dfrac{140}{3}\left(l\right)\\m_{Cran}=0,1.102+\dfrac{2}{15}.232=\dfrac{617}{15}\left(g\right)\end{matrix}\right.\)

mAl=27,8.19,42%=5,4g

⇒nAl=\(\dfrac{5,4}{27}\)=0,2mol

⇒nFe=\(\dfrac{27,8-5,4}{56}\)=0,4mol

4Al+3O2to→2Al2O34

3Fe+2O2to→Fe3O4

⇒nO2=\(\dfrac{3}{4}\)nAl+\(\dfrac{2}{3}\)nFe=\(\dfrac{5}{12}\)mol

⇒Vkk=\(\dfrac{5}{12}\).22,4.5=46,67l

b,

mrắn=27,8+mO2=27,8+​​\(\dfrac{5}{12}\)32=41,1g

→⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩Vkk=(0,15+415

\(n_{Al} = a ; n_{Fe} = b\Rightarrow 27a + 56b = 27,6(1)\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{Al_2O_3} = \dfrac{1}{2}n_{Al} = 0,5a(mol)\\ n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = \dfrac{b}{3}(mol)\\ \Rightarrow 0,5a.102 + \dfrac{b}{3}232 = 43,6(2)\\ (1)(2) \Rightarrow a = 0,4 ; b = 0,3\\ m_{Al} = 0,4.27 = 10,8(gam) ; m_{Fe} = 0,3.56 = 16,8(gam)\)

\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ PTHH:4Al+3O_2-^{t^o}>2Al_2O_3\)

tỉ lệ:         4     :    3         :     2

n(mol)     0,2---->0,15------->0,1

\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\\ m_{Al_2O_3}=n\cdot M=0,1\cdot\left(27\cdot2+16\cdot3\right)=10,2\left(g\right)\)

đây nha bạn
Ta có PTHH:  4Al + 3O₂ -> 2Al₂O₃ (điều kiện: có nhiệt độ)
a/
Có: ⁿAl = 5,4 : 27
             = 0,2 (mol)
Từ PTHH, ta có: V_O2 = (0,2 x 3 : 4) x 22,4
                                   = 3,36 (lít)
b/
Có: ^mAl₂O₃ = (0,2 : 2) x 102
                    = 10,2 (g)

PTHH: \(Cu_2S+2O_2\xrightarrow[]{t^o}2CuO+SO_2\)

a) Ta có: \(n_{Cu_2S}=\dfrac{100}{160}=0,625\left(mol\right)\) \(\Rightarrow n_{O_2\left(lýthuyết\right)}=1,25\left(mol\right)\)

\(\Rightarrow V_{O_2\left(thực\right)}=\dfrac{1,25\cdot22,4}{96\%}\approx29,17\left(l\right)\)

b) Sửa đề: "Tính khối lượng KMnO₄ để hấp thụ hết SO₂"

PTHH: \(5SO_2+2KMnO_4+2H_2O\rightarrow K_2SO_4+2MnSO_4+2H_2SO_4\)

Ta có: \(n_{SO_2\left(thực\right)}=n_{Cu_2S}\cdot96\%=0,6\left(mol\right)\)

\(\Rightarrow n_{KMnO_4}=0,24\left(mol\right)\) \(\Rightarrow m_{KMnO_4}=0,24\cdot158=37,92\left(g\right)\)

c) PTHH: \(SO_2+\dfrac{1}{2}O_2\xrightarrow[V_2O_5]{t^o}SO_3\)

Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{SO_2}=0,3\left(mol\right)\) \(\Rightarrow V_{kk}=\dfrac{0,3\cdot22,4}{21\%}=32\left(l\right)\)

d) Bảo toàn nguyên tố Lưu huỳnh: \(n_{H_2SO_4\left(lýthuyết\right)}=n_{SO_2\left(thực\right)}=0,3\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4\left(thực\right)}=0,3\cdot85\%=0,255\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,255\cdot98}{10\%}=249,9\left(g\right)\)