\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\Rightarrow m_C=0,1\cdot12=1,2g\Rightarrow n_C=0,1mol\)

\(m_{H_2O}=\dfrac{2,7}{18}=0,15mol\Rightarrow m_H=0,3g\Rightarrow n_H=0,3mol\)

\(\Rightarrow m_C+m_H< m_{hh}\Rightarrow\)Trong hợp chất A có chứa nguyên tố O.

\(\Rightarrow m_O=2,3-\left(1,2+0,3\right)=0,8g\Rightarrow n_O=0,05mol\)

Gọi CTHH của A là \(C_xH_yO_z\)

\(x:y:z=n_C:n_H:n_O=0,1:0,3:0,05=2:6:1\)

Vậy CTHH của A là \(C_2H_6O\)

a) 

\(n_{CO_2}=\dfrac{2,64}{44}=0,06\left(mol\right)\)

\(n_{H_2O}=\dfrac{0,45}{18}=0,025\left(mol\right)\)

\(n_{N_2}=\dfrac{0,112}{22,4}=0,005\left(mol\right)\)

Bảo toàn C: n_C = 0,06 (mol)

Bảo toàn H: n_H = 0,05 (mol)

Bảo toàn N: n_N = 0,01 (mol)

=> \(n_O=\dfrac{1,23-0,06.12-0,05.1-0,01.14}{16}=0,02\left(mol\right)\)

\(\%C=\dfrac{0,06.12}{1,23}.100\%=58,537\text{%}\)

\(\%H=\dfrac{0,05.1}{1,23}.100\%=4,065\%\)

\(\%O=\dfrac{0,02.16}{1,23}.100\%=26,016\%\)

\(\%N=\dfrac{0,01.14}{1,23}.100\%=11,382\%\)

b)

Xét n_C : n_H : n_N : n_O  = 0,06 : 0,05 : 0,01 : 0,02 = 6 : 5 : 1 : 2

=> CTDGN: C₆H₅NO₂

CTPT: (C₆H₅NO₂)_n

Mà \(M_X=4,242.29=123\left(g/mol\right)\)

=> n = 1

=> CTPT: C₆H₅NO₂

a) 

Do \(\dfrac{n_{CO_2}}{n_{H_2O}}=\dfrac{1}{2}\)

=> \(\dfrac{n_C}{n_H}=\dfrac{1}{4}\)

Giả sử A có CTHH là C_xH_4xO_y

Gọi số mol của A là a (mol)

=> 12ax + 4ax + 16ay = 3,2

=> ax + ay = 0,2 (1)

Bảo toàn C: n_CO2 = ax (mol)

Bảo toàn H: n_H2O = 2ax (mol)

\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Bảo toàn O: \(ay+0,4.2=2ax+2ax\)

=> 4ax - ay = 0,8 (2)

(1)(2) => ax = 0,2 (mol); ay = 0 (mol)

=> A chỉ chứa C và H

\(\left\{{}\begin{matrix}n_C=ax\left(mol\right)\\n_H=4ax\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}m_C=12.ax=2,4\left(g\right)\\m_H=1.4ax=0,8\left(g\right)\end{matrix}\right.\)

b)

Xét \(\dfrac{n_C}{n_H}=\dfrac{1}{4}\)

=> CTPT: (CH₄)_n

Mà M = 16 g/mol

=> n = 1

=> CTPT: CH₄

Gọi CTĐGN của A là \(C_xH_y\)

\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2mol\Rightarrow m_C=0,2\cdot12=2,4g\)

\(n_{H_2O}=\dfrac{5,4}{18}=0,3mol\Rightarrow n_H=2n_{H_2O}=0,6mol\Rightarrow m_H=0,6g\)

\(\Rightarrow x:y=n_C:n_H=0,2:0,6=1:3\)

\(\Rightarrow\left\{{}\begin{matrix}x=1\\y=3\end{matrix}\right.\)\(\Rightarrow CTĐGN\) là \(CH_3\)

Gọi CTHH cần tìm là \(\left(CH_3\right)_n\)

Theo bài: \(M_A=15\cdot2=30g\)\(\Rightarrow15n=30\Rightarrow n=2\)

Vậy A cần tìm có CTHH là \(C_2H_6\)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\left(1\right)\)

Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,5\left(mol\right)\\n_{C_2H_2}=1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,5.22,4}{33,6}.100\%\approx33,33\%\\\%V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)

b, Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=3,5\left(mol\right)\Rightarrow m_{O_2}=3,5.32=112\left(g\right)\)

\(n_{CO_2}=\dfrac{5.28}{44}=0.12\left(mol\right)\Rightarrow n_C=0.12\left(mol\right)\Rightarrow m_C=0.12\cdot12=1.44\left(g\right)\)

\(n_{H_2O}=\dfrac{0.9}{18}=0.05\left(mol\right)\Rightarrow n_H=0.05\cdot2=0.1\left(mol\right)\)

\(n_{N_2}=\dfrac{0.224}{22.4}=0.01\left(mol\right)\Rightarrow n_N=0.02\left(mol\right)\Rightarrow m_N=0.02\cdot14=0.28\left(g\right)\)

\(m_O=m_A-m_C-m_H-m_N=2.46-1.44-0.1-0.28=0.64\left(g\right)\)

\(\%C=\dfrac{1.44}{5.28}\cdot100\%=27.27\%\)

\(\%H=\dfrac{0.1}{5.28}\cdot100\%=1.89\%\)

\(\%N=\dfrac{0.28}{5.28}\cdot100\%=5.3\%\)

\(\%O=65.54\%\)

Em làm tương tự như câu lúc nãy nhé !

\(n_{CO_2}=\dfrac{17,92}{22,4}=0,8mol\Rightarrow n_C=0,8mol\Rightarrow m_C=9,6g\)

\(n_{H_2O}=\dfrac{21,6}{18}=1,2g\Rightarrow n_H=2n_{H_2O}=2\cdot1,2=2,4mol\Rightarrow m_H=2,4g\)

\(\Rightarrow m_C+m_H=12g< m_A=18,4g\Rightarrow\)chứa O.

\(\Rightarrow m_O=18,4-12=6,4g\)

Gọi CTĐGN là \(C_xH_yO_z\)

\(x:y:z=\dfrac{m_C}{12}:\dfrac{m_H}{1}:\dfrac{m_O}{16}=\dfrac{9,6}{12}:\dfrac{2,4}{1}:\dfrac{6,4}{16}=2:6:1\)

\(\Rightarrow CTĐGN:C_2H_6O\)

a)\(C_2H_6O_2+\dfrac{5}{2}O_2\underrightarrow{t^o}2CO_2+3H_2O\)

                        1        0,8         1,2

\(m_{O_2}=1\cdot32=32g\)

b)Gọi CTPT là \(\left(C_2H_6O\right)_n\)

Theo bài: \(M_A=1,4375\cdot32=46\)

\(\Rightarrow46n=46\Rightarrow n=1\)

Vậy CTPT là \(C_2H_6O\)

\(a,m_C=48\left(g\right)\rightarrow n_C=\dfrac{m_C}{M_C}=\dfrac{48}{12}=4\left(mol\right)\)

\(V_{O_2}=44,8\left(l\right)\rightarrow n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{44,8}{22,4}=2\left(mol\right)\)

\(PTHH:C+O_2\underrightarrow{t^o}CO_2\)

\(pt:\)      \(1mol\)  \(1mol\)

\(đb:\)      \(4mol\)  \(2mol\)

Xét tỉ lệ:

\(\dfrac{n_{C\left(đb\right)}}{n_{C\left(pt\right)}}=\dfrac{4}{1}=4>\dfrac{n_{O_2\left(đb\right)}}{n_{O_2\left(pt\right)}}=\dfrac{2}{1}=2\)

\(\Rightarrow\) \(O_2\) hết, \(C\) dư.

\(b,PTHH:C+O_2\underrightarrow{t^o}CO_2\)

\(pt:\)                  \(1mol\)   \(1mol\)

\(đb:\)                  \(2mol\)   \(2mol\)

\(\Rightarrow m_{CO_2}=n_{CO_2}.M_{CO_2}=2.\left(1.C+2.O\right)=2.\left(1.12+2.16\right)=88\left(g\right)\)

\(a.n_C=\dfrac{48}{12}=4\left(mol\right);n_{O_2}=\dfrac{44,8}{22,4}=2\left(mol\right)\\ C+O_2\xrightarrow[t^0]{}CO_2\)

Theo pt:\(\dfrac{4}{1}>\dfrac{2}{1}\Rightarrow C\) dư, O₂ pư hết

\(b.C+O_2\xrightarrow[t^0]{}CO_2\\ \Rightarrow n_{CO_2}=n_{O_2}=2mol\\ m_{CO_2}=2.44=88\left(g\right)\)