a, \(\left[H^+\right]=0,1=10^{-1}\Rightarrow pH=1\)

b, \(\left[H^+\right]=2.0,05=10^{-1}\Rightarrow pH=1\)

c, \(\left[OH^-\right]=0,2\)

\(\Rightarrow\left[H^+\right]=5.10^{-14}\)

\(\Rightarrow pH\approx13,3\)

d, \(\left[OH^-\right]=2.0,025=0,05\)

\(\Rightarrow\left[H^+\right]=2.10^{-13}\)

\(\Rightarrow pH\approx12,7\)

Ta có: \(n_{Ba\left(OH\right)_2}=0,025.0,02=0,0005\left(mol\right)\)

\(n_{NaOH}=0,025.0,05=0,00125\left(mol\right)\)

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}+n_{NaOH}=0,00225\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(\Rightarrow n_{H^+}=n_{OH^-}=0,00225\left(mol\right)\)

Gọi: V_X = x (l)

Ta có: \(n_{HCl}=0,1x\left(mol\right)\)

\(n_{CH_3COOH}=0,2x\left(mol\right)\)

\(\Rightarrow n_{H^+}=n_{HCl}+n_{CH_3COOH}=0,1x+0,2x=0,00225\)

\(\Rightarrow x=0,0075\left(l\right)=7,5\left(ml\right)\)

1. Ptrình ion H(+) + OH(-) = H2O 
n H(+) 0,3*0,75*2 + 0,3*1,5 = 0,9mol 
=> n OH(-) = 0,9mol => n KOH = 0,9mol => V = 0,6l

2. a) nNaOH= 0,05.20/40=0,025 mol 
NaOH + HCl ------> NaCl +H2O 
....3x.........3x 
2NaOH +H2SO4------> Na2SO4 + 2H2O 
.....2x.........x 
tỉ lệ mol 2 axit HCl : H2SO4 =3:1 
đặt số mol H2SO4 la` x ----> nHCl =3x 
>>>>3x+2x =0,025 >>>x=0,05 mol 
=>nồng độ mol của HCl va` H2SO4 lần lươt la` 1,5M & 0,5M 

b) n(OH-) = nNaOH + 2nBa(OH)2 = 0,2V + 2.0,1.V=0,4V 
trong 0,2l ddA có 0,3 mol HCl & 0,1 mol H2SO4 ( vi` V gấp đôi >> n gấp đôi) 
=> n(H+)= nHCl + 2nH2SO4 = 0,5mol 
ma` n(OH-) =n(H+) 
=> 0,4V=0,5 >>V= 1,25l=1250ml 

c) nNaOH=0,2.1,25=0,25mol = nBa(OH)2 
nH2O = n(axit)= 0,3 +0,1 =0,4 mol 
theo BTKL : m(muối) = m(axit) + m(bazo) -m(H2O) 
..............................= 0,3.36,5 +0,1.98 + 0,25( 40+171) -0,4.18=66,3g 

\(n_{OH^-}=0,12V_1\)

\(n_{H^+}=0,17V_2\)

\(n_{OH^-dư}=\left(V_1+V_2\right).10^{-1}\)

Ta có: 

\(n_{OH^-dư}+n_{H^+}=n_{OH^-}\)

\(\Leftrightarrow\left(V_1+V_2\right).10^{-1}=0,12V_1\)

\(\Leftrightarrow0,1V_1=0,02V_2\)

\(\Rightarrow\dfrac{V_1}{V_2}=\dfrac{1}{5}\)

\(pH=7\Rightarrow n_{H^+}=n_{OH^-}\)

\(\Leftrightarrow\left(0,05+0,06.2\right)\text{​​}V_2=\left(0,08+0,02.2\right)V_1\)

\(\Rightarrow V_1:V_2=17:12\)