a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)

                 \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)

b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)

\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)

c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\) 

(Coi như thể tích dd thay đổi không đáng kể)

d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\) 

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)

\(n_{CuCl_2}=0,3.0,5=0,15\left(mol\right)\)

PT: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)

Theo PT: \(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,15\left(mol\right)\Rightarrow m_{Cu\left(OH\right)_2}=0,15.98=14,7\left(g\right)\)

\(n_{NaOH}=2n_{CuCl_2}=0,3\left(mol\right)\)

\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)

a) $CuSO_4 + 2NaOH \to Cu(OH)_2 + Na_2SO_4$

b) $n_{Cu(OH)_2} = n_{CuSO_4} = \dfrac{16}{160} = 0,1(mol)$
$m_{Cu(OH)_2} = 0,1.98 = 9,8(gam)$

c) $n_{NaOH} = 2n_{CuSO_4} = 0,2(mol) \Rightarrow C_{M_{NaOH}} = \dfrac{0,2}{0,1} = 2M$

PTHH: \(CuSO_4+2NaOH\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

Ta có: \(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2\left(M\right)\\m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\end{matrix}\right.\)

a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

b. Đổi 100ml = 0,1 lít

Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)

Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)

=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)

c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)

=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)

Rainbow

a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)

c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)

\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)

a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl

     0.15        0.3            0.15            0.3

Cu(OH)2 -> CuO + H2O

  0.15            0.15

nNaOH = 0.3 mol

\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)

b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l

\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)

c.mCuO = \(0.15\times80=12g\)

\(n_{FeCl_3}=0.2\cdot0.4=0.08\left(mol\right)\)

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

\(0.08...........0.24..............0.08\)

\(2Fe\left(OH\right)_3\underrightarrow{^{^{t^0}}}Fe_2O_3+3H_2O\)

\(0.08...........0.04\)

\(m_{Fe_2O_3}=0.04\cdot160=6.4\left(g\right)\)

\(V_{dd_{NaOH}}=\dfrac{0.24}{0.5}=0.48\left(l\right)\)

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\) (1)

\(2Fe\left(OH\right)_3\rightarrow Fe_2O_3+3H_2O\) (2)

\(n_{FeCl_3}=0,2.0,4=0,08\left(mol\right)\)

Bảo toàn nguyên tố Fe : \(n_{FeCl_3}=2n_{Fe_2O_3}=0,08\left(mol\right)\)

=> \(n_{Fe_2O_3}=0,04\left(mol\right)\)

=> \(m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\)

Theo PT (1) : \(n_{NaOH}=3n_{FeCl_3}=0,08.3=0,24\left(mol\right)\)

=> \(V_{NaOH}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)

\(n_{FeCl_3}=C_M.V=0,4.0,2=0,08\left(mol\right)\)

PT: FeCl₃ + 3NaOH \(\rightarrow\) 3NaCl + Fe(OH)₃ \(\downarrow\)

       0,08 -> 0,24                     ->  0,08          (mol)

      2Fe(OH)₃ \(\underrightarrow{t^o}\) Fe₂O₃ + 3H₂O

        0,08       ->    0,04                                  (mol)

m_cr=m_Fe2O3=n.M=0,04.160=6,4(g)

\(V_{NaOH}=\dfrac{n}{C_M}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)

\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)

Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)

Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)

\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)