a, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

b, \(n_{MgCl_2}=0,2.0,25=0,05\left(mol\right)\)

 Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,05\left(mol\right)\)

\(\Rightarrow m_{MgO}=0,05.40=2\left(g\right)\)

c, \(n_{NaOH}=2n_{MgCl_2}=0,1\left(mol\right)\)

\(\Rightarrow m_{ddNaOH}=\dfrac{0,1.40}{15\%}=\dfrac{80}{3}\left(g\right)\)

a)\(n_{CuSO_4}=0,4.0,5=0,2\left(mol\right)\)

\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Mol:               0,2                0,4                   0,2

⇒ \(m_{Cu\left(OH\right)_2}=0,2.98=19,6\left(g\right)\)

b)\(C_{M\left(ddNaOH\right)}=\dfrac{0,4}{0,3}=1,3\left(M\right)\)

c)\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

Mol:                 0,2                   0,2

=> m_CuO = 0,2.80 = 16 (g)

a) mNaOH= 200.20%= 40(g)

=>nNaOH=1(mol)

PTHH: 2 NaOH + CuCl2 -> 2 NaCl + Cu(OH)2

Dung dịch sau khi lọc kết tủa có NaCl.

nNaCl=nNaOH= 1(mol)

nCuCl2=nCu(OH)2=nNaOH/2=1/2=0,5(mol)

mNaCl=1.58,5=58,5(g)

mCuCl2=0,5.135=67,5(g)

=> mddCuCl2=(67,5.100)/10=675(g)

mCu(OH)2=0,5.98=49(g)

=>mddNaCl=mddNaOH+ mddCuCl2 - mCu(OH)2= 200+675 - 98=777(g)

=> \(C\%ddNaCl=\dfrac{58,5}{777}.100\approx7,529\%\)

b) PTHH: Cu(OH)2 -to-> CuO + H2O

0,5__________________0,5(mol)

m(rắn)=mCuO=0,5.80=4(g)

\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,095          0,19              0,095            0,095

\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)

0,095                 0,095

\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)

a, \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

b, \(m_{CuSO_4}=250.16\%=40\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{40}{160}=0,25\left(mol\right)\)

Theo PT: \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,25\left(mol\right)\)

\(\Rightarrow a=m_{CuO}=0,25.80=20\left(g\right)\)

c, Ta có: m _{dd sau pư} = m _{dd NaOH} + m _{dd CuSO4} - m_Cu(OH)2 = 200 + 250 - 0,25.98 = 425,5 (g)

\(a)2NaOH+CuSO_4\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\ Cu\left(OH\right)_2\xrightarrow[]{t^0}CuO+H_2O\\ b)n_{CuSO_4}=\dfrac{250.16}{100.160}=0,25mol\\ n_{CuSO_4}=n_{Cu\left(OH\right)_2}=n_{CuO}=0,25mol\\ a=m_{CuO}=0,25.80=20g\\ c)m_{dd}=200+250-0,25.98=425,5g\)

a,\(n_{FeCl_2}=0,25.0,2=0,05\left(mol\right);n_{NaOH}=0,25.0,5=0,125\left(mol\right)\)

PTHH: FeCl₂ + 2NaOH → Fe(OH)₂ + 2NaCl

Mol:      0,05                         0,05           0,1

Tỉ lệ:\(\dfrac{0,05}{1}< \dfrac{0.125}{2}\) ⇒ FeCl₂ pứ hết;NaOH dư

PTHH: \(Fe\left(OH\right)_2\underrightarrow{t^o}FeO+H_2O\)

Mol:          0,1              0,1

⇒ m=m_FeO = 0,1.72 = 7,2 (g)

b,\(C_{MNaOHdư}=\dfrac{0,125-0,1}{0,5}=0,05M\)

  \(C_{MNaCl}=\dfrac{0,1}{0,5}=0,2M\)