1) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

m_A = m_KMnO4(bđ) - m_O2 = 79 - 0,15.32 = 74,2 (g)

PTHH: 2KMnO₄ --t^o--> K₂MnO₄ + MnO₂ + O₂

               0,3<-----------0,15<----0,15<---0,15

=> \(H=\dfrac{0,3.158}{79}.100\%=60\%\)

2) 

\(\left\{{}\begin{matrix}\%m_{K_2MnO_4}=\dfrac{0,15.197}{74,2}.100\%=39,825\%\\\%m_{MnO_2}=\dfrac{0,15.87}{74,2}.100\%=17,588\%\\\%m_{KMnO_4\left(không.pư\right)}=\dfrac{79-0,3.158}{74,2}.100\%=42,587\%\end{matrix}\right.\)

3) \(n_{KMnO_4\left(không.pư\right)}=\dfrac{79}{158}-0,3=0,2\left(mol\right)\)

PTHH: 2KMnO₄ + 16HCl --> 2KCl + 2MnCl₂ + 5Cl₂ + 8H₂O

                 0,2----------------------------------->0,5

             K₂MnO₄ + 8HCl --> 2KCl + MnCl₂ + 2Cl₂ + 4H₂O

                 0,15-------------------------------->0,3

              MnO₂ + 4Hcl --> MnCl₂ + Cl₂ + 2H₂O

                0,15------------------->0,15

=> \(V_{Cl_2}=22,4\left(0,5+0,3+0,15\right)=21,28\left(l\right)\)

\(n_{KMnO_4}=\dfrac{79}{158}=0,5mol\)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

0,5                                                  0,15

a)\(m_{KMnO_4}=0,15\cdot197=29,55g\)

\(m_{MnO_2}=0,15\cdot87=13,05g\)

\(m_{CRắn}=m_{KMnO_4}+m_{MnO_2}=29,55+13,05=42,6g\)

\(n_{KMnO_4pư}=0,15\cdot2=0,3mol\)

\(H=\dfrac{0,3}{0,5}\cdot100\%=60\%\)

b)\(m_{O_2}=0,15\cdot32=4,8g\)

\(\%m_{K_2MnO_4}=\dfrac{29,55}{42,6}\cdot100\%=69,37\%\)

\(\%m_{MnO_2}=100\%-69,37\%=30,63\%\)

- Gọi số mol KClO3 và KMnO4 bị nhiệt phân là x, y mol ( x,y > 0 )

\(2KClO_3\rightarrow2KCl+3O_2\)

...x.............................1,5x.............

\(2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)

.....y.................................................0,5y.....

Ta có : \(m_{hh}=m_{KClO3}+m_{KMnO4}=122,5x+158y=546,8\)

Theo PTHH : \(n_{O2}=1,5x+0,5y=\dfrac{V}{22,4}=4,4\)

\(\Rightarrow\left\{{}\begin{matrix}x=2,4\\y=1,6\end{matrix}\right.\) mol

\(\Rightarrow m_{KClO3}=n.M=294g\left(53,8\%\right)\)

=> %KMnO4 = 46,2%

\(a.Al,Ag+H_2SO_4\rightarrow ChỉcóAlphảnứng,chấtrắnsauphảnứnglàAg\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ TheoPT:n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\\ \Rightarrow m_{Al}=0,1.27=2,7\left(g\right)\\ \Rightarrow m_{rắnsaupu}=m_{Ag}=15,4-2,7=12,7\left(g\right)\\ b.\%m_{Al}=\dfrac{2,7}{15,4}.100=17,53\%,\%m_{Ag}=100-17,53=82,47\%\)

a) $n_{O_2} = 0,15(mol)$

\(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)

0,3                         0,15           0,15       0,15                    (mol)

$H = \dfrac{0,15.158}{63,2}.100\% = 37,5\%$

b)

$m_B = 63,2 - 0,15.32 = 58,4(gam)$
$\%m_{K_2MnO_4} = \dfrac{0,15.197}{58,4}.100\% = 50,59\%$

$\%m_{MnO_2} = \dfrac{0,15.87}{58,4}.100\% = 22,35\%$
$\%m_{KMnO_4\ dư} = 100\% -50,59\% -22,35\% = 27,06\%$

2KClO3-to>2KCl+3O₂

0,1224----------------0,1836 mol

n _KClO3=\(\dfrac{15}{122,5}\)=0,1224 mol

=>H =\(\dfrac{4,032}{0,1836.22,4}.100\).100=98%