\(CH_3COOH+NaCl\rightarrow CH_3COONa+HCl\)

\(2CH_3COOH+CaCO_3\rightarrow\left(CH_3COO\right)_2Ca+H_2O+CO_2\)

   2                         1                     1                      1         1    (mol)

 0,08                    0,04                0,04              0,04         0,04 (mol)

\(nCO_2=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

\(mCaCO_3=0,04.100=4\left(g\right)\)

=> \(mNaCl=12,5-4=8,5\left(g\right)\)

( không thấy hh B ) 

c ) .

\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)

 1             2               1                  1     (mol)

0,04       0,08           0,04        0,04 (mol)

\(mNa_2CO_3=0,04.106=4,24\left(g\right)\)

\(mNa_2CO_{3\left(thựctế\right)}=\)\(\dfrac{4,24.85\%}{100\%}=3,604\left(g\right)\)

a) 

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            0,2-->0,4----->0,2--->0,2

=> V_H2 = 0,2.22,4 = 4,48 (l)

b) m_HCl = 0,4.36,5 = 14,6 (g)

=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)

c)

m_{dd sau pư} = 13 + 200 - 0,2.2 = 212,6 (g)

m_ZnCl2 = 0,2.136 = 27,2 (g)

=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)

Fe+H2SO4->FeSO4+H2

0,1----0,1-------0,1-----0,1 

n Fe=5,6\56=0,1 mol

=>VH2=0,1.22,4=2,24l

=>m H2SO4=0,1.98=9,8g

=>C%=9,8\100 .100=9,8%

\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)

\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)

\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)

a) 2Al + 6HCl --> 2AlCl₃ + 3H₂

Fe + 2HCl --> FeCl₂ + H₂

b) Gọi số mol Al, Fe lần lượt là a,b 

=> 27a + 56b = 13,9

\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)

2Al + 6HCl --> 2AlCl₃ + 3H₂

a----->3a--------->a------->1,5a______(mol)

Fe + 2HCl --> FeCl₂ + H₂

b------>2b-------->b----->b__________(mol)

=> 1,5a + b = 0,35

=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)

c) n_HCl = 3a + 2b = 0,7 (mol)

=> m_HCl = 0,7.36,5 = 25,55(g)

=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)

\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)

\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)

\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\) 
           0,4       0,8        0,4           0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)

\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(0.1......................0.1..........0.1\)

\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)

\(m_{dd_{H_2SO_4}}=150\cdot1.08=162\left(g\right)\)

\(m_{dd}=6.5+162-0.1\cdot2=168.3\left(g\right)\)

\(C\%_{ZnSO_4}=\dfrac{0.1\cdot161}{168.3}\cdot100\%=9.56\%\)

PTHH: \(Mg+H_2SO_4\rightarrow MgsO_4+H_2\uparrow\)

Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)=n_{MgSO_4}=n_{H_2SO_4}\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgSO_4}=0,2\cdot120=24\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\C\%_{H_2SO_4}=\dfrac{0,2\cdot98}{294}\cdot100\%\approx6,67\%\end{matrix}\right.\)