a) \(n_{CH_3COOH}=0,1.0,3=0,03\left(mol\right)\)

PTHH: CH₃COOH + NaOH --> CH₃COONa + H₂O

                  0,03---->0,03--------->0,03

=> \(V_{dd.NaOH}=\dfrac{0,03}{1,5}=0,02\left(l\right)\)

b) m_CH3COONa = 0,03.82 = 2,46 (g)

c) \(C_{M\left(CH_3COONa\right)}=\dfrac{0,03}{0,1+0,02}=0,25M\)

\(a)n_{H_2SO_4}=0,15.1=0,15mol\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

0,3                 0,15            0,15              0,15

\(C_{M\left(NaOH\right)}=\dfrac{0,3}{0,1}=3M\\ b)C_{M\left(Na_2SO_4\right)}=\dfrac{0,15}{0,1+0,15}=0,6M\)

\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)

Pt : \(K_2O+H_2O\rightarrow2KOH|\)

         1           1              2

        0,1                        0,2

a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)

200ml = 0,2l

\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)

b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)

              1            1           1            1

            0,1          0,1

\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)

\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)

c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)

        1          2               1              1

      0,05      0,1

\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)

\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)

 Chúc bạn học tốt

\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

\(a,H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=1.0,4=0,4\left(mol\right)\\ n_{NaOH}=0,4.2=0,8\left(mol\right)\\ b,V_{ddNaOH}=\dfrac{0,8}{0,5}=1,6\left(l\right)\\ c,n_{Na_2SO_4}=n_{H_2SO_4}=0,4\left(mol\right)\\ V_{ddNa_2SO_4}=0,4+1,6=2\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,4}{2}=0,2\left(M\right)\)

\(n_{NaOH}=0.4\cdot1.5=0.6\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_{2O}\)

\(0.6...........0.3......................0.3\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.3}{1.5}=0.2\left(l\right)\)

\(C_{M_{Na_2SO_4}}=\dfrac{0.3}{0.4+0.2}=0.5\left(M\right)\)

\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

0,2------->0,1--------->0,1

Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư

Trong dung dịch D có:

\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)

b

\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)

0,35<---------0,35

\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\end{matrix}\right.\)