\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,1}{4}>\dfrac{0,1}{5}\) 
P dư 
\(n_{P\left(p\text{ư}\right)}=\dfrac{4}{5}n_{O_2}=0,08\left(mol\right)\\ m_{P\left(d\right)}=0,08.31=0,62\left(g\right)\\ n_{P_2O_5}=\dfrac{2}{5}n_{O_2}=0,04\left(mol\right)\\ m_{P_2O_5}=0,04.142=5,68\left(g\right)\\ m_{sp}=0,62+5,68=6,3\left(g\right)\)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)

\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)

4P + 5O₂ \(\underrightarrow{t^o}\) 2P₂O₅

\(\dfrac{0,1}{4}< \dfrac{0,2}{5}\) => O₂ dư, Photpho đủ

\(n_{O_2}=0,2-0,04=0,16\left(mol\right)\)

\(m_{P_2O_5}=\) 0,05 . 142 = 7,1 ( g )

nP = 2,48/31 = 0,08 (mol)

PTHH: 4P + 5O2 -> (t°) 2P2O5

Mol: 0,08 ---> 0,1 ---> 0,04

mP2O5 = 0,04 . 142 = 5,68 (g)

b) nO2 = 4/32 = 0,125 (mol)

So sánh: 0,125 > 0,1 => O2 dư

nO2 (dư) = 0,125 - 0,1 = 0,025 (mol)

mO2 (dư) = 0,025 . 32 = 0,8 (g)

nP = 6.2/31 = 0.2 (mol) 

nO2 = 6.72/22.4 = 0.3 (mol) 

4P + 5O2 -to-> 2P2O5 

0.2___0.25_____0.1

mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g) 

mP2O5 = 0.1*142 = 14.2 (g) 

Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)

\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)

PTHH:

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

ta có:

\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)

=> \(O_2\) dư 

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

4   ----------->2                

0.2---------->0.1=n_P2O5

=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)

nP=\(\dfrac{62}{31}\)=0,2(mol)

nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)

PTHH:4P+5O2to→2P2O5

tpứ:    0,2     0,35     

pứ:     0,2     0,25     0,1

spứ:     0     0,1         0,1

a)chất còn dư là oxi

mO2dư=0,1.32=3,2(g)

b)mP2O5=n.M=0,1.142=14,2(g)

\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)

a) n\(_P\) = \(\dfrac{6,2}{31}\) = 0,2(mol); n\(_{O_2}\) = \(\dfrac{7,84}{22,4}\) = 0,35(mol).

Theo phương trình hóa học:

\(4P+5O_2\) \(\underrightarrow{t^o}\) \(2P_2O_5\)

4        5          2 (mol)

0,2 \(\rightarrow\)0,25 \(\rightarrow\) 0,1(mol)

Tỉ lệ số mol: \(\dfrac{0,2}{4}< \dfrac{0,35}{5}\) \(\Rightarrow\) \(O_2\) phản ứng dư, P phản ứng hết.

\(n_{O_2}\)dư = 0,35 - \(\dfrac{0,2.5}{4}\) = 0,1(mol) \(\Rightarrow\) \(m_{O_2}\)dư = 0,1.32 = 3,2g

b) \(n_{P_2O_5}\) = 0,1.142 = 14,2g

a. \(n_P=\dfrac{12.4}{31}=0,4\left(mol\right)\)

\(n_{O_2}=\dfrac{67.2}{22,4}=3\left(mol\right)\)

Ta thấy : 0,4 < 3 => P đủ , O₂ dư

PTHH : 4P + 5O₂ -----t^o-----> 2P₂O₅

            0,4     0,5                      0,2

b. \(m_{P_2O_5}=0,2.142=28,4\left(g\right)\)