Fe+2HCl->FeCl₂+H₂

0,02-0,04--------------0,02

Fe₂O₃+6HCl->2Fecl₃+3H₂O

0,03-----0,18 mol

n H2=\(\dfrac{0,448}{22,4}\)=0,02 mol

=>m Fe=0,02.56=1,12g

=>m _Fe2O3=4,8g=>n F_e2O3=\(\dfrac{4,8}{160}\)=0,03 mol

=>x=CM_HCl=\(\dfrac{0,22}{0,5}\)=0,44M

b)

2Fe+3Cl₂-to>2FeCl₃

0,02---0,03

=>m _Cl2=0,03.71=2,13g

Giúp mình vớiii

\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

a) \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

  \(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)

b) \(n_{Fe}=n_{H2}=n_{H2SO4}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)

\(\Rightarrow m_{Al2O3}=15,8-5,6=10,2\left(g\right)\)

c) Ta có : \(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\Rightarrow n_{H2SO4}=3n_{Al2O3}=0,3\left(mol\right)\)

\(C_{MddH2SO4}=\dfrac{0,1+0,3}{0,2}=2M\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\left(2\right)\)

\(n_{H_2}=\dfrac{3.785}{24.79}=0.15\left(mol\right)\Rightarrow n_{Al}=\dfrac{2}{3}\cdot0.15=0.1\left(mol\right),n_{HCl\left(1\right)}=0.15\cdot2=0.3\left(mol\right)\)

\(m_{Al}=0.1\cdot27=2.7\left(g\right)\Rightarrow m_{Al_2O_3}=40-2.7=37.3\left(g\right)\Rightarrow n_{Al_2O_3}=\dfrac{37.3}{102}=0.36\left(mol\right)\)

\(\Rightarrow n_{HCl\left(2\right)}=0.36\cdot6=2.16\left(mol\right)\)

\(n_{HCl}=0.3+2.16=2.46\left(mol\right)\)

\(V_{dd_{HCl}}=\dfrac{2.46}{2}=1.23\left(l\right)\)

Ta có : C1=2C2

=> Gọi n_H2SO4 =x 

=> n _HCl = 2x

Bảo toàn nguyên tố H :\(n_{HCl}.1+n_{H_2SO_4}.2=n_{H_2}.2\)

\(\Rightarrow2a+2a=\dfrac{13,44}{22,4}=0,6.2\)

=>a = 0,3(mol)

=> CM_HCl = \(\dfrac{0,6}{0,3}=2M\); CM_H2SO4 = \(\dfrac{0,3}{0,3}=1M\)

Dung dịch B gồm : Mg ²⁺ , Al³⁺ , Cl^- , SO4 ^2-

\(n_{Cl^-}=n_{HCl}=0,6\left(mol\right);n_{SO_4^{2-}}=n_{H_2SO_4}=0,3\left(mol\right)\)

Bảo toàn điện tích cho dung dịch B:

\(n_{Mg}.2+n_{Al}.3=0,6+0,3.2\) (1)

Theo đề bài : \(24.n_{Mg}+27.n_{Al}=12,6\) (2)

Từ (1), (2)=> \(\left\{{}\begin{matrix}n_{Mg}=0,3\\n_{Al}=0,2\end{matrix}\right.\)

=> \(\%m_{Mg}=\dfrac{0,3.24}{12,6}.100=57,14\%\)

=> % m _Al = 100 -57.14 = 42,86%

Sửa đề: 3,785 (l) → 3,7185 (l)

a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)

c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)

Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)

\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)

d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)

\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)

e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)

Cu không phản ứng với dung dịch HCl

\(Zn + 2HCl \to ZnCl_2 + H_2\\ n_{Zn} = n_{H_2} =\dfrac{2,24}{22,4} = 0,1(mol)\\ m_{Zn} = 0,1.65 = 6,5(gam)\\ m_{Cu} = 9,6 - 6,5 = 3,1(gam)\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

            \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

a) Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)=n_{Zn}\)

\(\Rightarrow\%m_{Zn}=\dfrac{0,4\cdot65}{36,2}\cdot100\%\approx71,23\%\) \(\Rightarrow\%m_{Al_2O_3}=28,77\%\)

c) Ta có: \(n_{Al_2O_3}=\dfrac{36,2-0,4\cdot65}{102}=0,1\left(mol\right)\)

Theo PTHH: \(n_{HCl}=2n_{Zn}+6n_{Al_2O_3}=1,4\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{1,4\cdot36,5}{10\%}=511\left(g\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{511}{1,1}\approx464,5\left(ml\right)=0,4645\left(l\right)\)

c) Theo PTHH: \(\left\{{}\begin{matrix}n_{ZnCl_2}=0,4\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,4}{0,4645}\approx0,86\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4645}\approx0,43\left(M\right)\end{matrix}\right.\)