\(a,\) Đặt \(\begin{cases} n_{Fe}=x(mol)\\ n_{Al}=y(mol) \end{cases}\Rightarrow 56x+27y=22(1)\)

\(n_{H_2}=\dfrac{17,92}{22,4}=0,8(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow x+1,5y=0,8(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,2(mol)\\ y=0,4(mol) \end{cases} \Rightarrow \begin{cases} \%_{Fe}=\dfrac{0,2.56}{22}.100\%=50,91\%\\ \%_{Al}=100\%-50,91\%=49,09\% \end{cases} \)

\(b,\Sigma n_{HCl}=2n_{Fe}+3n_{Al}=0,4+1,2=1,6(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{1,6.36,5}{3,7\%}=1578,38\%\)

\(a.BTNT\left(H\right):n_{HCl}=2n_{H_2}=0,65\left(mol\right)\\ \Rightarrow CM_{HCl}=\dfrac{0,65}{0,5}=1,3M\\ b.2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Đặt:\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\dfrac{3}{2}x+y=0,325\\27x+56y=9,65\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=4,05\left(g\right)\\m_{Fe}=5,6\left(g\right)\end{matrix}\right.\)

Đáp án A

Đặt n_Fe = a và n_Al = b.

+ Phương trình theo khối lượng hỗn hợp: 56a + 27b = 9,65 (1)

+ Phương trình bảo toàn e là: 2a + 3b = 2n_H2 = 0,65 (2)

+ Giải hệ (1) và (2) ⇒ n_Al = b = 0,15 mol

⇒ %m_Al = 0,15×27/9,65 × 100 ≈ 41,97% 

\(a,n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: Ba + 2H₂O ---> Ba(OH)₂ + H₂

            0,3<-------------0,3<---------0,3

=> m_Ba = 0,3.137 = 41,1 (g)

=> m_K2O = 59,9 - 41,1 = 18,8 (g)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{41,1}{59,9}.100\%=68,61\%\\\%m_{K_2O}=100\%-68,61\%=31,39\%\end{matrix}\right.\)

\(b,n_{K_2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\)

PTHH: K₂O + H₂O ---> 2KOH

          0,2----------------->0,4

Các chất tan trong dd sau phản ứng: KOH, Ba(OH)₂

\(\rightarrow\left\{{}\begin{matrix}m_{KOH}=0,4.56=22,4\left(g\right)\\m_{Ba\left(OH\right)_2}=0,3.171=51,3\left(g\right)\end{matrix}\right.\)

\(a) m_{Cu} = 9,6(gam)\\ n_{Al} = a(mol) ; n_{Fe} = b(mol)\\ \Rightarrow 27a + 56b = 16,55 -9,6 =6,95(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5a + b = \dfrac{3,92}{22,4} = 0,175(2)\\ (1)(2) \Rightarrow a = 0,05 ; b = 0,1\\ m_{Al} = 0,05.27 = 1,35(gam); n_{Fe} = 0,1.56 = 5,6(gam)\)

\(b) n_{HCl} = 2n_{H_2} = 0,175.2 = 0,35(mol) \Rightarrow m_{HCl} = 0,35.36,5 = 12,775(gam)\)

a) Fe +2 HCl -> FeCl2 + H2

x____2x______x____x(mol)

2 Al + 6 HCl -> 2 AlCl3 + 3 H2

y____3y______y________1,5y(mol)

b) nH2= 0,05(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}56x+27y=1,66\\x+1,5y=0,05\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,02\end{matrix}\right.\)

=> mFe=0,02.56= 1,12(g)

mAl=0,02.27=0,54(g)