\(a,PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\\ m_{Al_2O_3}=n.M=0,2.102=20,4\left(g\right)\)

\(b,n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ Lập.tỉ.lệ:\dfrac{n_{Al}}{4}>\dfrac{n_{O_2}}{3}\Rightarrow Al.dư\\ Theo.PTHH:n_{Al\left(pư\right)}=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,2\left(mol\right)\\ n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(pư\right)}=0,4-0,2=0,2\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2O_3}=n.M=0,1=102=10,2\left(g\right)\)

\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)

\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)

\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)

\(PTHH:2Zn+O_2->2ZnO\)

BĐ           0,4      0,3               (mol)

PU           0,4---->0,2--->0,4   (mol) 

CL            0------->0,1---->0,4  (mol)

a)

\(n_{Zn}=\dfrac{m}{M}=\dfrac{26}{65}=0,4\left(mol\right)\\ n_{O_2\left(dktc\right)}=\dfrac{V}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

\(\dfrac{n_{Zn}}{2}< \dfrac{n_{O_2}}{1}\left(\dfrac{0,4}{2}< \dfrac{0,3}{1}\right)\)

=> Zn hết, O2 dư ( tính theo Zn)

b)

\(m_{ZnO}=n\cdot M=0,4\cdot\left(65+16\right)=32,4\left(g\right)\)

\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{5,6}{56}=0,1mol\)

\(n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{4,48}{22,4}=0,2mol\)

\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)

 3          2                 1       ( mol )

0,1  <   0,2                         ( mol )

Chất còn dư là O2, chất hết là Fe

\(n_{Fe}=\dfrac{16,8}{56}=0,3mol\)

\(n_S=\dfrac{6,4}{32}=0,2mol\)

\(Fe+S\rightarrow FeS\)

0,3    0,2     0,2

Sau phản ứng Fe dư và dư 0,1mol.

\(FeS+2HCl\rightarrow FeCl_2+H_2S\uparrow\)

0,2                                     0,2

\(Fe_{dư}+2HCl\rightarrow FeCl_2+H_2\uparrow\)

0,1                                      0,1

\(\Sigma n_{khí}=0,2+0,1=0,3mol\)

\(\Rightarrow V_{khí}=0,3\cdot22,4=6,72l\)

- Cho phản ứng xảy ra hoàn toàn (2 chất trong A có sắt và oxit khác oxit sắt ban đầu)

\(yH_2+Fe_xO_y\rightarrow\left(t^o\right)xFe+yH_2O\left(1\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\\ n_{H_2\left(2\right)}=n_{Fe\left(2\right)}=n_{Fe\left(1\right)}=0,3\left(mol\right)\\ n_{O\left(trong.oxit\right)}=n_{H_2O}=n_{H_2}=0,4\left(mol\right)\\ BTKL:m_{H_2}+m_{oxit}=m_A+m_{H_2O}\\ \Leftrightarrow0,4.2+m=28,4+18.0,4\\ \Leftrightarrow m=34,8\left(g\right)\\ b,x:y=0,3:0,4=3:4\Rightarrow x=3;y=4\\ \Rightarrow CTHH:Fe_3O_4\)

a) Fe₃O₄ + 4H₂ --t^o--> 3Fe + 4H₂O

b)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{4}\) => H₂ hết, Fe₃O₄ dư

PTHH: Fe₃O₄ + 4H₂ --t^o--> 3Fe + 4H₂O

             0,025<--0,1------>0,075

=> \(m_{Fe_3O_4\left(dư\right)}=\left(0,1-0,025\right).232=17,4\left(g\right)\)

c) \(m_{Fe}=0,075.56=4,2\left(g\right)\)

ai giúp mik câu b với ạ

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)

b, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)

PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)

Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,2}{3}\), ta được H₂ dư.

Theo PT: \(n_{H_2\left(pư\right)}=3n_{Fe_2O_3}=0,12\left(mol\right)\Rightarrow n_{H_2\left(dư\right)}=0,2-0,12=0,08\left(mol\right)\)

\(\Rightarrow m_{H_2\left(dư\right)}=0,08.2=0,16\left(g\right)\)

Theo PT: \(n_{Fe}=2n_{Fe_2O_3}=0,08\left(mol\right)\Rightarrow m_{Fe}=0,08.56=4,48\left(g\right)\)