\(2KOH+H_2SO_4->K_2SO_4+2H_2O\)

\(OH^-+H^+->H_2O\)

\(n_{H_2SO_4}=0,05.0,2=0,01\left(mol\right);n_{KOH}=0,2.0,1=0,02\left(mol\right)\)

PTHH: \(2KOH+H_2SO_4->K_2SO_4+2H_2O\)

_____0,02------->0,01

=> KOH, H2SO4 phản ứng vừa đủ, tạo ra dd K₂SO₄

=> pH = 7

pH~2,5

\(n_{H^+}=0.2\cdot0.01\cdot2=0.004\left(mol\right)\)

\(n_{OH^-}=0.1\cdot0.01=0.001\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(0.001.....0.001\)

\(n_{H^+\left(dư\right)}=0.004-0.001=0.003\left(mol\right)\)

\(pH=-log\left(H^+\right)=-log\left(\dfrac{0.003}{0.2+0.1}\right)=2\)

Có: \(n_{H^+}=2n_{H_2SO_4}=2.0,2.0,01=0,004\left(mol\right)\)

\(n_{OH^-}=0,1.0,01=0,001\left(mol\right)\)

PT ion: \(H^++OH^-\rightarrow H_2O\)

____0,004___0,001 (mol)

\(\Rightarrow n_{H^+\left(dư\right)}=0,003\left(mol\right)\)\\(\Rightarrow\left[H^+\right]=\dfrac{0,003}{0,3}=0,01\)

\(\Rightarrow pH=2\)

Bạn tham khảo nhé!

a) PT phân tử: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)

    PT ion: \(CaCO_3+2H^+\rightarrow Ca^{2+}+H_2O+CO_2\uparrow\)

b) Ta có: \(\left\{{}\begin{matrix}n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\\n_{HCl}=\dfrac{43,8\cdot20\%}{36,5}=0,24\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,24}{2}\) \(\Rightarrow\) HCl dư, tính theo CaCO₃

\(\Rightarrow\left\{{}\begin{matrix}n_{CaCl_2}=0,1\left(mol\right)=n_{CO_2}\\n_{HCl\left(dư\right)}=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCl_2}=0,1\cdot111=11,1\left(g\right)\\m_{CO_2}=0,1\cdot44=4,4\left(g\right)\\m_{HCl\left(dư\right)}=0,04\cdot36,5=1,46\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=49,4\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{CaCl_2}=\dfrac{11,1}{49,4}\cdot100\%\approx22,47\%\\C\%_{HCl\left(dư\right)}=\dfrac{1,46}{49,4}\cdot100\%\approx2,96\%\end{matrix}\right.\)

\(H^++OH^-\rightarrow H_2O\\ n_{H^+}=0,05\left(mol\right);n_{OH^-}=0,07\left(mol\right)\\ Lậptỉlệ:\dfrac{0,05}{1}< \dfrac{0,07}{1}\\ \Rightarrow OH^-dư\\ \left[OH^-_{dư}\right]=\dfrac{0,07-0,05}{0,2}=0,1M\\ \Rightarrow pOH=-log\left(0,1\right)=1\\ \Rightarrow pH=14-1=13\)

Đáp án B

$n_{Ba^{2+}} = 0,1.0,5 = 0,05 < n_{SO_4^{2-}} = 0,1$ nên $SO_4^{2-}$ dư

$n_{BaSO_4} = n_{Ba^{2+}} = 0,05(mol)$
$m_{BaSO_4} = 0,05.233 = 11,65(gam)$

$n_{OH^-} = 0,1.0,5.2 + 0,1.0,5 = 0,15(mol)$
$n_{H^+} = 0,1.2 = 0,2(mol)$

$H^+ + OH^- \to H_2O$

$n_{H^+\ dư} = 0,2 - 0,15 = 0,05(mol)$

$V_{dd} = 0,1 + 0,1 + 0,1 = 0,3(lít)$

$[H^+] = \dfrac{0,05}{0,3} = \dfrac{1}{6}M$
$pH = -log( \dfrac{1}{6} ) = 0,778$

\(n_{Ba^{2+}}=0.1\cdot0.5=0.05\left(mol\right)\)

\(n_{OH^-}=0.1\cdot0.5\cdot2+0.1\cdot0.5=0.15\left(mol\right)\)

\(n_{H^+}=2\cdot0.1\cdot1=0.2\left(mol\right)\)

\(n_{SO_4^{2-}}=0.1\left(mol\right)\)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

\(0.05.........0.05.............0.05\)

\(SO_4^{2-}dư\)

\(m_{\downarrow}=0.05\cdot233=11.65\left(g\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(0.15.......0.15\)

\(n_{H^+\left(dư\right)}=0.2-0.15=0.05\left(mol\right)\)

\(\left[H^+\right]=\dfrac{0.05}{0.1+0.1+0.1}=\dfrac{1}{6}\)

\(pH=-log\left(\dfrac{1}{6}\right)=0.77\)

a, \(NaHCO_3+NaOH\rightarrow Na_2CO_3+H_2O\)

\(HCO_3^-+OH^-\rightarrow CO_3^{2-}+H_2O\)

b, \(\left[Na^+\right]=\dfrac{0,2.1,5+0,12.1,6}{0,2+0,12}=1,5376M\)

\(\left[CO_3^{2-}\right]=\dfrac{0,2.1,5}{0,2+0,12}=0,9375M\)

\(n_{H^+}=0,3\left(mol\right)\)

\(n_{OH^-}=0,192\left(mol\right)\)

\(\Rightarrow n_{H^+dư}=0,108\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,108}{0,2+0,12}=0,3375M\)

\(\Rightarrow pH\approx0,47\)

\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)

\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)

\(0.1.............0.05...............0.05...........0.05\)

\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)

\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)

\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)