1)

a)

$CaO + 2HCl \to CaCl_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$

$n_{CaCO_3} = n_{CO_2} = 0,2(mol)$
$n_{CaCl_2} = 0,3(mol)$

Suy ra: 

$n_{CaO} = 0,3 - 0,2 = 0,1(mol)$
$\%m_{CaO} = \dfrac{0,1.56}{0,1.56 + 0,2.100}.100\% = 21,875\%$

$\%m_{CaCO_3} = 78,125\%$

b) 

$m_{dd} = 0,1.56 + 0,2.100 + 50 - 0,2.44 = 66,8(gam)$
$C\%_{CaCl_2} = \dfrac{33,3}{66,8}.100\% = 49,85\%$

Câu 4 : 

a)

Gọi $n_{Fe} = a(mol) ; n_{MgO} = b(mol)$

Suy ra: $56a + 40b = 19,2(1)$

$Fe + 2HCl \to FeCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2O$
Theo PTHH : $n_{HCl} = 2a + 2b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,2

$\%m_{Fe} = \dfrac{0,2.56}{19,2}.100\% = 58,33\%$
$\%m_{MgO} = 100\% -58,33\% = 41,67\%$

b)

$n_{FeCl_2} = a = 0,2(mol)$
$n_{MgCl_2} = b = 0,2(mol)$

$m_{muối} = 0,2.127 + 0,2.95 = 44,4(gam)$

Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)

PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)

                    0,2_____0,4_____0,2____0,2_____0,2  (mol)

            \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                 0,1_____0,2_____0,1____0,1    (mol)

Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)

Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)

\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)

\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)

nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol

nCaCl₂=\(\dfrac{33,3}{111}=0,3\)

CaCO₂ + 2HCl → CaCl₂ + CO₂ + H₂O

  0,2           ←         0,2    ← 0,2

CaO + 2HCl  → CaCl₂ + H₂O     

 0,1              ←    0,1

a)  % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)    

   % CaCO₃ =100% - 21,875%= 78,125%

b) a = mCaO+mCaCO₃ =0,1.56+0,2.100=25,6g

mdd sau pư= a + mddHCl - mCO2

                  = 25,6 + 50 - 0,2.44=66,8g

C%CaCl₂=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)

\(PTHH:CaO+2HCl\rightarrow CaCl2+H2O\)

________0,1____________0,1____________

\(CaCO3+2HCl\rightarrow CaCl2+CO2+H2O\)

0,2_____________0,2_________0,2_________

Ta có :

\(n_{CO2}=\frac{4,48}{22,4}=0,2\left(mol\right)\)

\(n_{CaCl2}=\frac{33,3}{111}=0,3\left(mol\right)\)

\(\rightarrow n_{CaCO3}=0,2\left(mol\right),n_{CaO}=0,1\left(mol\right)\)

\(a=m_{CaCO3}+m_{CaO}=0,2.100+0,1.56=25,6\left(g\right)\)

nCaCl2 = 0.3 mol

nCO2 = 0.2 mol

CaCO3 + 2HCl => CaCl2 + CO2 + H2O

0.2_______0.4______0.2____0.2

CaO + 2HCl => CaCl2 + H2O

0.1_____0.2_____0.1

mA = mCaCO3 + mCaO = 0.2*100 + 0.1*56 = 25.6 g

CM HCl = 0.6/0.3 = 2M

a)

Gọi $n_{CaCO_3} = a ; n_{MgCO_3} = b$
$\Rightarrow 100a + 84b = 4,68(1)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$MgCO_3 + 2HCl \to MgCl_2 +C O_2 + H_2O$

$n_{CO_2} = a + b = 0,05(2)$

Từ (1)(2) suy ra a = 0,03 ; b = 0,02

$\%m_{CaCO_3} = \dfrac{0,03.100}{4,68}.100\% = 64,1\%$
$\%m_{MgCO_3} = 35,9\%$

$m_{CaCl_2} = 0,03.111 = 3,33(gam)$
$m_{MgCl_2} = 0,02.95 = 1,9(gam)$
b)

$n_{HCl} = 2n_{CO_2} = 0,1(mol)$
$C_{M_{HCl}} = \dfrac{0,1}{0,25} = 0,4M$

a) Ta có: \(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)

Gọi a và b lần lượt là số mol của Al và Zn

Bảo toàn mol e: \(3a+2b=1,4\)

                   Mà \(27a+65b=31,4\)

\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{31,4}\cdot100\%\approx17,2\%\\\%m_{Zn}=82,8\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=1,4mol\)

\(\Rightarrow V_{HCl}=\dfrac{1,4}{2}=0,7\left(l\right)=700\left(ml\right)\)

Đặt : 

nAl = a mol 

nZn = b mol 

mB = 27a + 65b = 31.4 (g) (1) 

2Al + 6HCl => 2AlCl3 + 3H2 

a___________________1.5a

Zn + 2HCl => ZnCl2 + H2 

b__________________b

nH2 = 1.5a + b = 15.68/22.4 = 0.7 (mol) (2) 

(1) , (2) : 

a = 0.2

b = 0.4 

%Al = 5.4/31.4 * 100% = 17.19%

%Zn = 100 - 17.19 = 82.81%

nHCl = 2nH2 = 0.7*2 = 1.4 (mol) 

Vdd HCl = 1.4 / 2 = 0.7 (l) 

nHCl = 0.4 * 2.75 = 1.1 (mol) 

=> nH2 = nHCl/2 = 0.55 (mol) 

VH2 = 12.32 (l) 

BTKL : 

mA + mHCl = mX + mH2 

25.3 + 1.1*36.5 = mX + 1.1 

=> mX = 64.35 (g) 

a)

$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CO_2} = \dfrac{672}{1000.22,4} = 0,03(mol)$
$n_{HCl} = 2n_{CO_2} = 0,06(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,06}{0,2} = 0,3M$

b)

$\%m_{CaCO_3} = \dfrac{0,03.100}{5}.100\% = 60\%$
$\%m_{CaSO_4}=  100\% -60\% = 40\%$