\(C_{M\left(H_2SO_4\right)}=a;C_{M\left(NaOH\right)}=b\\ H_2SO_4+2NaOH->Na_2SO_4+2H_2O\\ 0,015a\cdot2-0,036b=0\\ Ba\left(OH\right)_2+H_2SO_4->BaSO_4+2H_2O\\ 0,04a=\dfrac{0,056b}{2}+\dfrac{0,466}{233}=0,028b+0,002\\ a=0,12M;b=0,1M\)

Em ko có tiền nên mong a , cj tham khảo(đây là 500 g dung dịch nên mong a, cj sửa 1 chút ạ)

Theo bài ra ta có:

+)mBa(OH)2 = \(\dfrac{C\%.mdd}{100\%}\) = \(\dfrac{10\%.855}{100\%}\)= 85,5 g

=> nBa(OH)2 = \(\dfrac{\text{mBa(OH)2 }}{\text{MBa(OH)2 }}\)= \(\dfrac{85,5}{171}\)= 0,5 mol

PTHH. Ba(OH)2 + H2SO4 -> 2H2O + BaSO4↓ (1)

0,5-----------0,5

Theo bài ra ta lại có:

+) mddNaOH = 125. 1,28 = 160g

=> mNaOH = \(\dfrac{C\%.mdd}{100\%}\) = \(\dfrac{25\%.160}{100\%}\) = 40g

=> nNaOH = \(\dfrac{\text{mNaOH }}{\text{MNaOH }}\)= \(\dfrac{40}{40}\) = 1 mol

PTHH. H2SO4 + 2NaOH --->Na2SO4 + 2H2O (2)

0,5-------1

Từ trên => nH2SO4 = nH2SO4(pt1) + nH2SO4(pt2)

= 0,5 + 0,5 = 1 mol

Đổi 200ml = 200g

=> mH2SO4 = nH2SO4 . MH2SO4 = 1. 98 = 98 g

=> C%ddH2SO4 = \(\dfrac{m_{ct}.100\%}{m_{dd}}\) = \(\dfrac{98.100\%}{200}\) = 49%

Vậy....

Gọi \(\left\{{}\begin{matrix}C_{M\left(A\right)}=aM\\C_{M\left(B\right)}=bM\end{matrix}\right.\)

Giả sử trộn 50ml dd A với 50ml dd B để thu được 100ml dd C

=> \(\left\{{}\begin{matrix}n_{NaOH}=0,05a\left(mol\right)\\n_{Ba\left(OH\right)_2}=0,05b\left(mol\right)\end{matrix}\right.\)

\(n_{BaSO_4}=\dfrac{9,32}{233}=0,04\left(mol\right)\)

n_H2SO4 = 0,035.2 = 0,07 (mol)

PTHH: Ba(OH)₂ + H₂SO₄ --> BaSO₄ + 2H₂O

              0,04<----0,04<-------0,04

            2NaOH + H₂SO₄ --> Na₂SO₄ + 2H₂O

              0,06<----0,03

=> \(\left\{{}\begin{matrix}0,05a=0,06\\0,05b=0,04\end{matrix}\right.\)

=> a = 1,2; b = 0,8 

20 ml dd A chứa n_NaOH = 0,02.1,2 = 0,024 (mol)

\(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)

PTHH: 2NaOH + Al₂O₃ --> 2NaAlO₂ + H₂O

             0,024-->0,012

            Ba(OH)₂ + Al₂O₃ --> Ba(AlO₂)₂ + H₂O

             0,188<---0,188

=> \(V_{dd.B}=\dfrac{0,188}{0,8}=0,235\left(l\right)=235\left(ml\right)\)

\(n_{CuSO_4}=\dfrac{160.10\%}{160}=0,1\left(mol\right)\)

\(n_{NaOH}=\dfrac{150.8\%}{40}=0,3\left(mol\right)\)

PTHH: CuSO₄ + 2NaOH --> Cu(OH)₂ + Na₂SO₄

Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,3}{2}\) => CuSO₄ hết, NaOH dư

PTHH: CuSO₄ + 2NaOH --> Cu(OH)₂ + Na₂SO₄

                0,1------>0,2------->0,1------->0,1

=> m = 0,1.98 = 9,8 (g)

\(\left\{{}\begin{matrix}m_{NaOH_{dư}}=\left(0,3-0,2\right).40=4\left(g\right)\\m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\end{matrix}\right.\)

m_{dd sau pư} = 160 + 150 - 9,8 = 300,2 (g)

\(\left\{{}\begin{matrix}C\%_{NaOH_{dư}}=\dfrac{4}{300,2}.100\%=1,33\%\\C\%_{Na_2SO_4}=\dfrac{14,2}{300,2}.100\%=4,73\%\end{matrix}\right.\)

\(m_{CuSO_4}=\dfrac{160.10}{100}=16\left(g\right)\\ n_{NaOH}=\dfrac{8.150}{100}=12\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\end{matrix}\right.\)

PTHH: 2NaOH + CuSO₄ ---> Cu(OH)₂ + Na₂SO₄

LTL: \(0,1< \dfrac{0,3}{2}\rightarrow\) NaOH dư

Theo pt: \(\left\{{}\begin{matrix}n_{NaOH\left(pư\right)}=\dfrac{1}{2}n_{CuSO_4}=2.0,1=0,2\left(mol\right)\\n_{Na_2SO_4}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\rightarrow m=0,1.98=9,8\left(g\right)\\ m_{dd}=160+150-9,8=300,2\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{NaOH\left(dư\right)}=\dfrac{\left(0,3-0,2\right).40}{300,2}=1,33\%\\C\%_{Na_2SO_4}=\dfrac{0,1.142}{300,2}=4,73\%\end{matrix}\right.\)

Khối lượng BaCl2 : 104*10/100=10,4g =>nBaCl2 = 10,4/208= 0,05mol 
Khối lượng dd NaOH : 1,28*250= 80g => nNaOH = (80*25/100)/40 = 2mol 
PT : BaCl2 + H2SO4 ----> BaSO4 + 2HCl 
0,05mol --> 0,05mol 
H2SO4 + 2NaOH -------> Na2SO4 + 2H2O 
1mol <--- 2mol 
hoep t trên ta có tổng số mol của  H2SO4 : 0,05+1 = 1,05mol => mH2SO4 = 98*1,05 =102,9g 
Vậy c%H2SO4 : 102,9/200*100= 51,45%

Chọn đáp án C

a, \(n_{HCl}=0,2.0,1=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)

\(n_{H_2SO_4}=0,2.0,15=0,03\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,06\left(mol\right)\)

\(\Rightarrow\Sigma n_{H^+}=0,02+0,06=0,08\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)=n_{Ba^{2+}}\) 

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

0,03___0,03 (mol) ⇒ n_H⁺ dư = 0,05 (mol)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

0,015___0,015______0,015 (mol) ⇒ n_SO4^2- dư = 0,015 (mol)

⇒ m = m_BaSO4 = 0,015.233 = 3,495 (g)

\(\left[Cl^-\right]=\dfrac{0,02}{0,2+0,3}=0,04\left(M\right)\)

\(\left[H^+\right]=\dfrac{0,05}{0,2+0,3}=0,1\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0,015}{0,2+0,3}=0,03\left(M\right)\)

b, pH = -log[H⁺] = 1