Đổi 2,016 dm3 = 2,016 l

nH2 = 2,016/22,4 = 0,09 (mol)

Gọi nFe2O3 = a (mol); nCuO = b (mol)

160a + 80b = 5,6 (g) (1)

PTHH:

Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O

Mol: a ---> 3a ---> 2a ---> 3a

CuO + H2 -> (t°) Cu + H2O

Mol: b ---> b ---> b ---> b

3a + b = 0,09 (mol) (2)

Từ (1) và (2) => a = 0,02 (mol); b = 0,03 (mol)

mFe2O3 = 0,02 . 160 = 3,2 (g)

mCuO = 0,03 . 80 = 2,4 (g)

mH2O = (0,02 . 3 + 0,03) . 18 = 1,62 (g)

mFe = 2 . 0,02 . 56 = 2,24 (g)

mCu = 0,03 . 64 = 1,92 (g)

Fe3O4+4H2-to>3Fe+4H2O

                x---------\(\dfrac{3}{4}x\)

CuO+H2-to>Cu+H2O

           y--------y mol

Ta có :

\(\left\{{}\begin{matrix}x+y=0,5\\\dfrac{3}{4}x.56+64y=23,2\end{matrix}\right.\)

=>x=0,4 mol, y=0,1 mol

=>% m Fe3O4=\(\dfrac{0,4.232}{0,4.232+0,1.80}.100\)=92,1%

=>%m CuO=100-92,1=7,9%

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)

\(Fe_3O_4+4H_2\rightarrow3Fe+4H_2O\)

x             4x          3x

\(CuO+H_2\rightarrow Cu+H_2O\)

y           y          y

\(\Rightarrow\left\{{}\begin{matrix}4x+y=0,5\\3\cdot56x+64y=23,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)

\(\%m_{Fe_2O_3}=\dfrac{0,1\cdot232}{0,1\cdot232+0,1\cdot80}\cdot100\%=74,36\%\)

\(\%m_{CuO}=100\%-74,36\%=25,64\%\)

a)

\(m_{CuO}=\dfrac{32.40}{100}=12,8\left(g\right)\) => \(n_{CuO}=\dfrac{12,8}{80}=0,16\left(mol\right)\)

\(n_{Fe_2O_3}=\dfrac{32-12,8}{160}=0,12\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

           0,16->0,16---->0,16

             Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

              0,12-->0,36----->0,24

=> \(V_{H_2}=\left(0,16+0,36\right).22,4=11,648\left(l\right)\)

b)

m_Cu = 0,16.64 =10,24 (g)

m_Fe = 0,24.56 = 13,44 (g)

c) 

\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

 Xét tỉ lệ: \(\dfrac{0,24}{1}< \dfrac{0,5}{2}\) => HCl dư, Fe hết

PTHH: Fe + 2HCl --> FeCl₂ + H₂

          0,24------------------->0,24

=> \(V_{H_2}=0,24.22,4=5,376\left(l\right)\)

\(a.Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ b.n_{H_2SO_4}=0,22.1,25=0,275mol\\ n_{Fe_2O_3}=a;n_{CuO}=b\\ \Rightarrow\left\{{}\begin{matrix}3a+b=0,275\\160a+80b=16\end{matrix}\right.\\ \Rightarrow a=0,075;b=0,05\\ \%m_{Fe_2O_3}=\dfrac{0,075.160}{16}\cdot100=75\%\\ \%m_{CuO}=100-75=25\%\)

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