- Thấy Cu không phản ứng với HCl .

\(\Rightarrow m_{cr}=m_{Cu}=6,4\left(g\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

.x.......................................1,5x.........

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

.y....................................y.............

Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}27x+56y+6,4=17,4\\1,5x+y=0,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\) ( mol )

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=5,4\\m_{Fe}=5,6\end{matrix}\right.\) ( g )

b, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

.......0,1.........0,2...............................

\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)

...0,2.......0,6..........................

\(\Rightarrow n_{NaOH}=0,2+0,6=0,8< 1\)

=> Trong B còn có HCl dư .

\(NaOH+HCl\rightarrow NaCl+H_2O\)

...0,2..........0,2....................

=> Dư 0,2 mol HCl .

\(\Rightarrow n_{HCl}=2n_{H_2}+0,2=1\left(mol\right)\)

\(\Rightarrow m_{ddB}=17,4+250-6,4-0,8=260,2\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{260,2}.100\%\approx2,8\%\\C\%_{FeCl_2}\approx4,88\%\\C\%_{AlCl_3}\approx10,26\%\end{matrix}\right.\)

Vậy ....

Gọi số mol Al, Fe là a, b

\(m_{Cu}=m_B=6,4\left(g\right)\)

=> \(m_{Al}+m_{Fe}=17,4-6,4=11\left(g\right)\)

=> 27a + 56b = 11

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂ 

            b----------------------->b

            2Al + 6HCl --> 2AlCl₃ + 3H₂

             a------------------------>1,5a

=> 1,5a + b = 0,4

=> a = 0,2; b = 0,1

=> \(\left\{{}\begin{matrix}m_{Fe}=0,1.56=5,6\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)

a) Fe +2 HCl -> FeCl2 + H2

x____2x______x____x(mol)

2 Al + 6 HCl -> 2 AlCl3 + 3 H2

y____3y______y________1,5y(mol)

b) nH2= 0,05(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}56x+27y=1,66\\x+1,5y=0,05\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,02\end{matrix}\right.\)

=> mFe=0,02.56= 1,12(g)

mAl=0,02.27=0,54(g)

\(a) m_{Cu} = 9,6(gam)\\ n_{Al} = a(mol) ; n_{Fe} = b(mol)\\ \Rightarrow 27a + 56b = 16,55 -9,6 =6,95(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5a + b = \dfrac{3,92}{22,4} = 0,175(2)\\ (1)(2) \Rightarrow a = 0,05 ; b = 0,1\\ m_{Al} = 0,05.27 = 1,35(gam); n_{Fe} = 0,1.56 = 5,6(gam)\)

\(b) n_{HCl} = 2n_{H_2} = 0,175.2 = 0,35(mol) \Rightarrow m_{HCl} = 0,35.36,5 = 12,775(gam)\)

\(a.2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ A:Al_2\left(SO_4\right)_3\\ B:Cu\\ D:H_2\\ b.n_{H_2}=n_{H_2SO_4}=\dfrac{200.18,375\%}{100\%.98}=0,375mol\\ V_{H_2}=0,375.22,4=8,4l\\ c.n_{Al}=\dfrac{0,375.2}{3}=0,25mol\\ m_{Al}=0,25.27=6,75g\\ m_{Cu}=19,55-6,75=12,8g\\ d.n_{Al_2\left(SO_4\right)_3}=\dfrac{0,375}{3}=0,125mol\\ m_{dd}=6,75+200-0,375.2=206g\\ m_{Al_2\left(SO_4\right)_3}=0,125.342=42,75g\\ C_{\%_{Al_2\left(SO_4\right)_2}}=\dfrac{42,75}{206}\cdot100\%=20,75\%\)

\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(0.1.......0.2......................0.1\)

Chất rắn X : Cu 

\(m_{Zn}=0.1\cdot65=6.5\left(g\right)\Rightarrow m_{Cu}=19.3-6.5=12.8\left(g\right)\)

\(n_{Cu}=\dfrac{12.8}{64}=0.2\left(mol\right)\)

\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)

\(2Cu+O_2\underrightarrow{^{^{t^o}}}2CuO\)

\(0.2........0.1\)

\(m_{tăng}=m_{O_2}=0.1\cdot32=3.2\left(g\right)\)

2Al + 6HCl → 2 A l C l 3 + 3 H 2

a……….3/2.a (mol)

Mg + 2HCl → M g C l 2 +  H 2

b....................b (mol)

4 gam rắn không tan là Cu, gọi số mol của Al và Mg lần lượt là a và b (mol). Ta có:

⇒ % m C u = 4 13 .100 = 30,77 % ⇒ % m A l = 0,2.27 13 .100 = 41,54 % ⇒ % m M g = 100 % − 30,77 % − 41,54 % = 27,69 %

⇒ Chọn C.

\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ b.Chấtrắnkhôngtan:Cu\\ \%m_{Cu}=54,24\%\\ Đặt:\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}2x+2y=\dfrac{91,25.20\%}{36,5}\\56x+24y=23,6-12,8\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=35,59\%\\\%m_{Mg}=10,17\%\end{matrix}\right.\)