Đổi 500ml=0,5l

\(n_{Ca}=\dfrac{12}{40}=0,3\left(g\right)\)

\(Ca+H_2SO_4\rightarrow CaSO_4+H_2\)

1...........1.............1............1....(mol)

0,3........0,3.......0,3............0,3..(mol)

\(C_{MH_2SO_4}=\dfrac{n}{Vdd}=\dfrac{0,3}{0,5}==0,6\left(M\right)\)

a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)

c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)

d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)

e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)

d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H₂SO₄ dư.

Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)

Đáp án C

0,1M

n_Al = 5.4/27 = 0.2  (mol) 

2Al + 3H2SO4 => Al2(SO4)3 + 3H2 

0.2____0.3_________________0.3 

VH2 = 0.3*22.4 = 6.72(l) 

CM H2SO4 = 0.3/0.1 = 3 M

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) 

\(\Rightarrow n_{H_2}=0,3mol=n_{H_2SO_4}\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{H_2SO_4}}=\dfrac{0,3}{0,1}=3\left(M\right)\end{matrix}\right.\)

nK2SO3=15.8\158=0.1(mol)

K2SO3+H2SO4→K2SO4+SO2+H2O

0.1...........................0.1..........0.1

VSO2=0.1⋅22.4=2.24(l)

CMK2SO4=0.1\0.2=0.5(M)

a)\(n_{K_2O}=\dfrac{23,5}{94}=0,25mol\)

\(K_2O+H_2O\rightarrow2KOH\)

0,25      0,25       0,5

\(C_M=\dfrac{0,5}{0,5}=1M\)

b)Để trung hòa: \(n_{H^+}=n_{OH^-}=0,5\)

   \(\Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{H^+}=0,25mol\)

   \(m_{H_2SO_4}=0,25\cdot98=24,5g\)

   \(\Rightarrow m_{ddHCl}=\dfrac{24,5\cdot100\%}{60\%}=\dfrac{245}{6}g\)

   Thể tích dung dịch:

   \(V=\dfrac{m}{D}=\dfrac{\dfrac{245}{6}}{1,5}\approx27,22ml\)

\(n_{K_2O}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ K_2O+H_2O\rightarrow2KOH\\ n_{KOH}=2.0,25=0,5\left(mol\right)\\ a,C_{M\text{dd}A}=C_{M\text{dd}KOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\\ n_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{\text{dd}H_2SO_4}=\dfrac{24,5.100}{60}=\dfrac{245}{6}\left(g\right)\\ V_{\text{dd}H_2SO_4}=\dfrac{\dfrac{245}{6}}{1,5}=\dfrac{245}{9}\left(ml\right)\approx27,222\left(ml\right)\)

Bài 1:

\(a.n_{NaOH\left(tổng\right)}=0,05.1+0,2.0,2=0,09\left(mol\right)\\ V_{ddNaOH\left(tổng\right)}=50+200=250\left(ml\right)=0,25\left(l\right)\\ C_{MddNaOH\left(cuối\right)}=\dfrac{0,09}{0,25}=0,36\left(M\right)\\ b.n_{HCl}=0,5.0,02=0,01\left(mol\right)\\ n_{H_2SO_4}=0,08.0,2=0,016\left(mol\right)\\ V_{ddsau}=20+80=100\left(ml\right)=0,1\left(l\right)\\ C_{MddH_2SO_4}=\dfrac{0,016}{0,1}=0,16\left(M\right)\\ C_{MddHCl}=\dfrac{0,01}{0,1}=0,1\left(M\right)\)

Bài 2:

\(a.m_{H_2SO_4}=29,4.10\%=2,94\left(g\right)\\ b.n_{H_2SO_4}=\dfrac{2,94}{98}=0,03\left(mol\right)\\ n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,01}{1}< \dfrac{0,03}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(dư\right)}=0,03-0,01=0,02\left(mol\right)\\ m_{H_2SO_4\left(dư\right)}=0,02.98=1,96\left(g\right)\\ n_{H_2}=n_{Fe}=0,01\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\)

\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

0,2     0,2                0,2       0,2

a)\(V_{H_2}=0,2\cdot22,4=4,48l\)

b)\(C_{M_{H_2SO_4}}=\dfrac{0,2}{0,5}=0,4M\)

c)\(C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4M\)

\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\) 
pthh : \(Fe+H_2SO_4->FeSO_4+H_2\) 
          0,2                                      0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(L\right)\) 
\(m_{H_2SO_4}=\dfrac{0,5}{22,4}.98\approx2,188\left(g\right)\) 
=> mdd=11,2+2,188=13,388(g) 
C%=\(\dfrac{2,188}{13,388}.100\%=16,3\%\)