a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)

PTHH: 2CH₃COOH + Mg --> (CH₃COO)₂Mg + H₂

                  0,1<----------------------0,05------->0,05

=> V_H2 = 0,05.22,4 = 1,12 (l)

b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)

Pt: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

\(n_{\left(CH_3COO\right)_2Zn}=\dfrac{14,2}{183}\approx0.077mol\)

Theo pt: nH₂ = n(CH₃COO)₂Zn = 0,077mol

=> VH₂ = 1,7248l

b) Theo pt: nCH₃COOH = 2n(CH₃COO)₂Zn = 0,154 mol

=> CM_CH3COOH = 0,154 : 0,25 = 0,616M

Bài 1

Bài 5

Fe + 2CH₃COOH \(\rightarrow\) (CH₃COO)₂Fe + H₂(1)

nCH₃COOH = \(\dfrac{4,5}{60}=0,075mol\)

a) THeo pt: n(CH₃COO)₂Fe = \(\dfrac{1}{2}.nCH_3COOH=0,0375mol\)

=> m = 6,525g

c) Theo pt (1) nH₂ = 1/2nCH₃COOH = 0,0375 mol

2H₂ + O₂ \(\xrightarrow[]{t^o}\) 2H₂O

Theo pt: nO₂ = 0,5nH₂ = 0,01875mol

=> VO₂ = 0,42 lít

=> Vkk = 0,42.5 = 2,1 lít

\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)

PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

a, \(n_{H_2}=n_{Mg}=0,5\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)

b, \(n_{H_2SO_4}=n_{Mg}=0,5\left(mol\right)\)\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)

a)

2CH₃COOH  +  Mg  →  (CH₃COO)₂Mg  +  H₂

b)

nH₂ = 0,448 : 22,4 = 0,02 mol

=> n(CH₃COO)₂Mg = 0,02 mol 

<=> m(CH₃COO)₂Mg = 0,02.142 = 2,84 gam.

c) nCH₃COOH = 2 nH₂ = 0,04 mol

<=> mCH₃COOH = 0,04 . 60 = 2,4 gam

=> C%_CH3COOH = \(\dfrac{2,4}{40}.100\%\)= 6%

a) \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

_____0,1<-0,2------<0,1<---0,1

=> m_MgCl2 = 0,1.95 = 9,5 (g)

b) \(C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\)

Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

____0,1______0,2_____0,1____0,1 (mol)

a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)

\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)

Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)

\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)

PTHH: Mg + 2CH₃COOH --> (CH₃COO)₂Mg + H₂

                           0,02<-----------0,01-------->0,01

=> V_H2 = 0,01.22,4 = 0,224 (l)

\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)

b) 

PTHH: CH₃COOH + NaOH --> CH₃COONa + H₂O

                  0,02------>0,02

=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)

a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)

\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)

Ta có: m _{dd sau pư} = 5,6 + 120 - 0,1.2 = 125,4 (g)

\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)