Trong \(20,4g\) hỗn hợp có: \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow65a+56b+27c=20,4\left(1\right)\)

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)

\(BTe:2n_{Zn}+2n_{Fe}+3n_{Al}=2n_{H_2}\)

\(\Rightarrow2a+2b+3c=2\cdot0,45\left(2\right)\)

Trong \(0,2mol\) hhX có \(\left\{{}\begin{matrix}Zn:ka\left(mol\right)\\Fe:kb\left(mol\right)\\Al:kc\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow ka+kb+kc=0,2\)

\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275mol\)

\(BTe:2n_{Zn}+3n_{Fe}+3n_{Al}=2n_{Cl_2}\)

\(\Rightarrow2ka+3kb+3kc=2\cdot0,275\)

Xét thương:

 \(\dfrac{ka+kb+kc}{2ka+3kb+3kc}=\dfrac{0,2}{2\cdot0,275}\Rightarrow\dfrac{a+b+c}{2a+3b+3c}=\dfrac{4}{11}\)

\(\Rightarrow3a-b-c=0\left(3\right)\)

Từ (1), (2), (3)\(\Rightarrow\left\{{}\begin{matrix}a=0,1mol\\b=0,2mol\\c=0,1mol\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Zn}=6,5g\\m_{Fe}=11,2g\\m_{Al}=2,7g\end{matrix}\right.\)

\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)

\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)

\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)

0,02                                                   0,06

\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)

0,05                          0,05

\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)

Chọn A

a) Sửa đề: dd H₂SO₄ 9,8%

Ta có: \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\) \(\Rightarrow m_{H_2}=0,35\cdot2=0,7\left(g\right)\)

Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{H_2}=0,35\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,35\cdot98}{9,8\%}=350\left(g\right)\)

\(\Rightarrow m_{dd}=m_{KL}+m_{H_2SO_4}-m_{H_2}=361,6\left(g\right)\)

b) Tương tự câu a

$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{Fe} = n_{H_2} = \dfrac{3360}{1000.22,4} = 0,15(mol)$
$n_{SO_2} = \dfrac{4480}{22,4.1000} = 0,2(mol)$
Bảo toàn electron : 

$3n_{Fe} + 2n_{Cu} = 2n_{SO_2}$

Suy ra: $0,15.3 + 2n_{Cu} = 0,2.2 \Rightarrow n_{Cu} = -0,025<0$

(Sai đề)

Fe+H2SO4->FeSO4+H2

0,15-----------------------0,15 mol

n H2=0,15 mol

=>m Fe=0,15.56=8,4g

=>m Cu=11,8-8,4=3,4g

\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)

PTHH: Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

             0,1---->0,3

          Zn + H₂SO₄ --> ZnSO₄ + H₂

           0,3<--------------------0,3

=> m = 0,3.65 = 19,5 (g)