Fe+2HCl->FeCl₂+H₂

x---2x-----------x

Mg+2HCl->MgCl₂+H₂

y------2y-----------y

Ta có :

\(\left\{{}\begin{matrix}56x+24y=24\\x+y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,3 mol, y=0,3 mol

=>%m Fe=\(\dfrac{0,3.56}{24}.100\)=70%

=>%m Mg=100-70=30%

=>VHCl=\(\dfrac{0,3.2+0,3.2}{2}\)=0,6l=600ml

b)

 XCl₂+2AgNO₃->2AgCl+X(NO₃)₂

0,6--------------------1,2mol

=>m AgCl=1,2.143,5=172,2g

\(n_{Cu} = a ; n_{Al} = b ; n_{Fe} = c(mol)\\ \Rightarrow 64a + 27b + 56c = 28,6(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5b + c = \dfrac{13,44}{22,4} = 0,6(2)\\ \text{Mặt khác} : n_{O_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Cu + O_2 \xrightarrow{t^o} 2CuO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 4Fe + 3O_2 \xrightarrow{t^o} 2Fe_2O_3\\ \)

Ta có :

\(\dfrac{n_X}{n_{O_2}}=\dfrac{a+b+c}{0,5a +0,75b + 0,75c} = \dfrac{0,6}{0,4}(3)\\ (1)(2)(3)\Rightarrow a = \dfrac{317}{1460} ; b = \dfrac{121}{365}; c = \dfrac{15}{146}\\ \%m_{Cu} = \dfrac{\dfrac{317}{1460}.64}{28,6}.100\% = 48,59\%\\ \%m_{Al} = \dfrac{\dfrac{121}{365}.27}{28,6}.100\% = 31,3\%\\ \%m_{Fe} = 100\% - 41,59\% - 31,3\% = 27,11\%\)

\(n_{H_2} = \dfrac{4,35-3,95}{2} = 0,2(mol)\\ Mg + 2HCl \to MgCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\)

\(\left\{{}\begin{matrix}Mg:x\left(mol\right)\\Al:y\left(mol\right)\end{matrix}\right.\)→ \(\left\{{}\begin{matrix}24x+27y=4,35\\x+1,5y=0,2\end{matrix}\right.\)→\(\left\{{}\begin{matrix}x=0,125\\y=0,05\end{matrix}\right.\)

Vậy :

\(\%m_{Mg} = \dfrac{0,125.24}{4,35}.100\% = 68,97\%\\ \%m_{Al} = 100\% - 68,97\% = 31,03\%\)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)  (1)

             \(MgO+2HCl\rightarrow MgCl_2+H_2O\)  (2)

a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)

\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)

b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)

\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)

c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)

\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)

Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)

\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)

Gọi x, y tương ứng là số mol Mg và MgO: 24x + 40y = 8,8.

x + y = nMgCl2 = 28,5/95 = 0,3

Giải hệ thu được: x = 0,2; y = 0,1.

a) %Mg = 24.0,2/8,8 = 54,54%; %MgO = 100 - 54,54 = 45,46%

b) nHCl = 2(x+y) = 0,6 mol; mdd =36,5.0,6.100/14,6 = 150 gam.

c) mdd sau p.ư = 8,8 + 150 - mH2 = 158,8 - 2.0,2 = 158,4 gam.

%MgCl2 = 28,5/158,4 = 17,99%

a) 2Al + 6HCl -> 2AlCl3 + 3H2

Al2O3 + 6HCl -> 2AlCl3 + 3H2O

nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol

=>%mAl=20,93% =>%mAl2O3 = 79,07%

b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g

mddY=12,9+100-0,15.2=112,6g

mAlCl3=22,5g=>C%=19,98%