2KMnO4-to>K2MnO4+MnO2+O2

1,2-------------------------------------0,6 mol

n O2=13,44\22,4=0,6 mol

H =75%

=>m KMnO4 tt= 1,2.158 .100\75=252,8g

\(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: 2KMnO₄ ---t^o→ K₂MnO₄ + MnO₂ + O₂

Mol:       1,2                                                    0,6

\(m_{KMnO_4\left(lt\right)}=1,2.158=189,6\left(g\right)\Rightarrow m_{KMnO_4\left(tt\right)}=\dfrac{189,6}{75}.100=252,8\left(g\right)\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

\(\Rightarrow n_{KMnO_4}=\dfrac{2n_{O_2}}{75\%}=\dfrac{2.13,44.100}{22,4.75}=1,6\left(mol\right)\)

\(\Rightarrow a=m_{KMnO_4}=1,6.158=252,8\left(g\right)\)

\(Đặt:n_{KMnO_4\left(LT\right)}=a\left(mol\right)\\ 2KMnO_4\underrightarrow{^{to}}K_2MnO_4+MnO_2+O_2\\ Vì:m_{rắn}=29,04\\ \Leftrightarrow\left(31,6-158a\right)+197.0,5a+87.0,5a=29,04\\ \Leftrightarrow a=0,16\\ \Rightarrow H=\dfrac{0,16.158}{31,6}.100=80\%\)

\(Đặt:n_{KMnO_4\left(LT\right)}=a\left(mol\right)\\ 2KMnO_4\underrightarrow{^{to}}K_2MnO_4+MnO_2+O_2\\ n_{KMnO_4\left(bđ\right)}=\dfrac{31,6}{158}=0,2\left(mol\right)\\ n_{KMnO_4\left(LT\right)}=0,2-a\left(mol\right)\\ n_{K_2MnO_4}=n_{MnO_2}=0,5a\left(mol\right)\\ m_{rắn}=29,04\\ \Leftrightarrow m_{KMnO_4\left(LT\right)}+m_{K_2MnO_4}+m_{MnO_2}=29,04\\ \Leftrightarrow\left(31,6-158a\right)+197a.0,5+87a.0,5=29,04\\ \Leftrightarrow a=0,16\)

\(\Rightarrow H=\dfrac{0,16}{0,2}.100=80\%\)

\(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2\left(mol\right)\\ 2KClO_3\underrightarrow{^{to}}2KCl+3O_2\\ n_{O_2\left(LT\right)}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ Vì:H=90\%\Rightarrow n_{O_2\left(TT\right)}=90\%.0,3=0,27\left(mol\right)\\ V_{O_2\left(đktc,thực.tế\right)}=0,27.22,4=6,048\left(l\right)\)

2KClO3-to>2KCl+3O2

0,06-----------------0,09  mol

n O2=2,016\22,4=0,09 mol

=>H =0,06.122,5\12,25 .100=60%

\(n_{O_2\left(TT\right)}=\dfrac{2,016}{22,4}=0,09\left(mol\right)\\ n_{KClO_3}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\\ 2KClO_3\underrightarrow{^{to}}2KCl+3O_2\\ n_{O_2\left(LT\right)}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\\ \Rightarrow H=\dfrac{0,09}{0,15}.100=60\%\)

\(n_{SO2}=\dfrac{6,4}{64}=0,1\left(mol\right)\)

Pt : \(S+O_2\rightarrow\left(t_o\right)SO_2|\)

      1       1                1

     0,1    0,1

\(n_{O2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

\(V_{O2\left(lt\right)}=0,1.22,4=2,24\left(l\right)\)

⇒ \(V_{O2\left(tt\right)}=\dfrac{2,24.100}{80}=2,8\left(l\right)\)

 Chúc bạn học tốt

S+O2-to>SO2

0,2----------0,2 mol

n S=6,4\32=0,2 mol

H=80%

VSO2=0,2.22,4.80\100=3.584l

\(n_S=\dfrac{6,4}{32}=0,2\left(mol\right)\)

PTHH: S + O₂ ---t^o→ SO₂

Mol:    0,2                    0,2

\(V_{SO_2\left(lt\right)}=0,2.22,4=4,48\left(l\right)\)

\(V_{SO_2\left(tt\right)}=4,48.80\%=3,584\left(l\right)\)

\(Đặt:n_{KClO_3\left(LT\right)}=a\left(mol\right)\\ 2KClO_3\underrightarrow{^{to}}2KCl+3O_2\\ n_{KCl}=a\left(mol\right)\\ m_{rắn}=30,99\\ \Leftrightarrow\left(36,75-122,5a\right)+74,5a=30,99\\ \Leftrightarrow a=0,12\\ m_{KClO_3\left(LT\right)}=0,12.122,5=14,7\left(g\right)\\ H=\dfrac{14,7}{36,75}.100=40\%\)

\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{CuO\left(p.ứ\right)}=a\left(mol\right)\\ \Rightarrow n_{Cu}=a\left(mol\right);m_{CuO\left(dư\right)}=24-80a\left(g\right)\\ \Rightarrow m_{rắn}=m_{CuO\left(dư\right)}+m_{Cu}=\left(24-80a\right)+64a=21,6\\ \Leftrightarrow-16a=-2,4\\ \Leftrightarrow a=0,15\\ Vậy:H=\dfrac{0,15.80}{24}.100\%=50\%\\ b,n_{H_2}=n_{Cu}=a=0,15\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\)

Sửa đề: 1,896 → 0,896

Ta có: \(n_{KMnO_4}=\dfrac{15,8}{158}=0,1\left(mol\right)\)

PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

Theo PT: \(n_{O_2\left(LT\right)}=\dfrac{1}{2}n_{KMnO_4}=0,05\left(mol\right)\)

Mà: \(n_{O_2\left(TT\right)}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

\(\Rightarrow H\%=\dfrac{0,04}{0,05}.100\%=80\%\)