Câu 1:

Gọi : nMg=a(mol); nMgO=b(mol) (a,b>0)

a) PTHH: Mg + 2 HCl -> MgCl2 + H2

a________2a_______a______a(mol)

MgO +2 HCl -> MgCl2 + H2O

b_____2b_______b___b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+40b=8,8\\22,4a=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)

=> mMg=0,2.24=4,8(g)

=>%mMg= (4,8/8,8).100=54,545%

=> %mMgO= 45,455%

b) m(muối)=mMg2+ + mCl- = 0,3. 24 + 0,6.35,5=28,5(g)

c) V=VddHCl=(2a+2b)/2=0,3(l)=300(ml)

Câu 2:

Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{HCl}=0,4\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

PTHH: \(Ca+2HCl\rightarrow CaCl_2+H_2\uparrow\)

               0,2____0,4_____0,2____0,2   (mol)

           \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                0,2____0,4______0,2____0,2  (mol)

Ta có: \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{0,2\cdot40}{0,2\cdot40+0,2\cdot56}\cdot100\%\approx41,67\%\\\%m_{CaO}=58,33\%\\m_{CaCl_2}=\left(0,2+0,2\right)\cdot111=44,4\left(g\right)\end{matrix}\right.\)

\(n_{Cu} = a ; n_{Al} = b ; n_{Fe} = c(mol)\\ \Rightarrow 64a + 27b + 56c = 28,6(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5b + c = \dfrac{13,44}{22,4} = 0,6(2)\\ \text{Mặt khác} : n_{O_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Cu + O_2 \xrightarrow{t^o} 2CuO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 4Fe + 3O_2 \xrightarrow{t^o} 2Fe_2O_3\\ \)

Ta có :

\(\dfrac{n_X}{n_{O_2}}=\dfrac{a+b+c}{0,5a +0,75b + 0,75c} = \dfrac{0,6}{0,4}(3)\\ (1)(2)(3)\Rightarrow a = \dfrac{317}{1460} ; b = \dfrac{121}{365}; c = \dfrac{15}{146}\\ \%m_{Cu} = \dfrac{\dfrac{317}{1460}.64}{28,6}.100\% = 48,59\%\\ \%m_{Al} = \dfrac{\dfrac{121}{365}.27}{28,6}.100\% = 31,3\%\\ \%m_{Fe} = 100\% - 41,59\% - 31,3\% = 27,11\%\)

\(n_{HCl}=0,65.2=1,3\left(mol\right)\)

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\) (1)

0,1<----0,3<------0,1<-----0,15

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\) (2)

 x--------->6x-------->2x

\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (3)

y--------->2y-------->y

Gọi \(\left\{{}\begin{matrix}n_{Al_2O_3}=x\left(mol\right)\\n_{MgO}=y\left(mol\right)\end{matrix}\right.\)

Theo PTHH (1), (2), (3) có:

 \(n_{HCl\left(2\right)}+n_{HCl\left(3\right)}=n_{HCl.ban.đầu}-n_{HCl\left(1\right)}\\ \Leftrightarrow6x+2y=1,3-0,3=1\left(mol\right)\left(I\right)\)

Theo PTHH (1) có: \(m_{Al}=0,1.27=2,7\left(g\right)\\ \Rightarrow m_{Al_2O_3}+m_{MgO}=102x+40y=20,9-2,7=18,2\left(g\right)\left(II\right)\) 

Từ (I),(II) có hệ phương trình:

 \(\left\{{}\begin{matrix}6x+2y=1\\102x+40y=18,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

Trong hỗn hợp ban đầu:

\(\left\{{}\begin{matrix}m_{Al}=2,7\left(g\right)\\m_{Al_2O_3}=102x=102.0,1=10,2\left(g\right)\\m_{MgO}=40y=40.0,2=8\left(g\right)\end{matrix}\right.\)

b

\(CM_{AlCl_3}=\dfrac{0,1+2x}{0,65}=\dfrac{0,1+2.0,1}{0,65}=\dfrac{6}{13}\approx0,46M\)

\(CM_{MgCl_2}=\dfrac{y}{0,65}=\dfrac{0,2}{0,65}=\dfrac{4}{13}\approx0,31M\)

a.\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{8,96}{22,4}=0,4mol\)

Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_{Zn}=y\end{matrix}\right.\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

 x                                      x ( mol )

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

 y                                        y   ( mol )

Ta có:

\(\left\{{}\begin{matrix}56x+65y=25,55\\x+y=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,35\end{matrix}\right.\)

\(\Rightarrow m_{Fe}=0,05.56=2,8g\)

\(\Rightarrow m_{Zn}=0,35.65=22,75g\)

\(\%m_{Fe}=\dfrac{2,8}{25,55}.100=10,95\%\)

\(\%m_{Zn}=100\%-10,95\%=89,05\%\)

b.\(n_{HCl}=2.0,05+2.0,35=0,8mol\)

\(C_M=\dfrac{n}{V}\Rightarrow V=\dfrac{n}{C_M}=\dfrac{0,8}{2}=0,4l\)

Bài 1:

\(n_{HCl}=2.0,16=0,32\left(mol\right);n_{H_2}=\dfrac{3,584}{22,4}=0,16\left(mol\right)\)

PTHH: Mg + 2HCl → MgCl₂ + H₂

PTHH: Fe + 2HCl → FeCl₂ + H₂

\(m_{H_2}=0,16.2=0,32\left(g\right)\)

\(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Theo ĐLBTKL ta có: \(m_{MgCl_2+FeCl_2}=1,4+11,68-0,32=12,76\left(g\right)\)

Bài 12:

Theo ĐLBTKL, ta có:

\(m_{hhkl}+m_{O_2}=m_{hh.oxit}\\ \Leftrightarrow11,9+m_{O_2}=18,3\\ \Leftrightarrow m_{O_2}=18,3-11,9=6,4\left(g\right)\\ n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\)

\(Fe + 2HCl \to FeCl_2 + H_2\\ n_{Fe} = n_{FeCl_2} = n_{H_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ m_{Fe} = 0,4.56 = 22,4(gam)\\ m_{FeCl_2} = 0,4.127 = 50,8(gam)\)

\(n_{H_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(n_{Fe}=n_{FeCl_2}=n_{H_2}=0.4\left(mol\right)\)

\(m_{Fe}=0.4\cdot56=22.4\left(g\right)\)

\(m_{FeCl_2}=0.4\cdot127=50.8\left(g\right)\)

a) PTHH : Fe + 2HCl → FeCl₂ + H₂

b) V_H2(đktc)=8,96(l) → n_H2= \(\dfrac{8,96}{22,4}\)=0,4(mol)

→ n_Fe= 0,4(mol)

m_Fe= 0,4 . 56=22,4(g)

c) Ta có :  n_H2= \(\dfrac{8,96}{22,4}\)=0,4(mol) → n_FeCl2= 0,4(mol)

m_FeCl2= 0,4 . 127=50,8(g)

Fe+2HCl->FeCl₂+H₂

x---2x-----------x

Mg+2HCl->MgCl₂+H₂

y------2y-----------y

Ta có :

\(\left\{{}\begin{matrix}56x+24y=24\\x+y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,3 mol, y=0,3 mol

=>%m Fe=\(\dfrac{0,3.56}{24}.100\)=70%

=>%m Mg=100-70=30%

=>VHCl=\(\dfrac{0,3.2+0,3.2}{2}\)=0,6l=600ml

b)

 XCl₂+2AgNO₃->2AgCl+X(NO₃)₂

0,6--------------------1,2mol

=>m AgCl=1,2.143,5=172,2g

a)

$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$

b)

Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$

$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$

$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$

c) $Fe + CuSO_4 \to FeSO_4 + Cu$

$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$

$= 3,6 + 0,15.64 = 13,2(gam)$