CH4+2O2-to>CO2+2H2O

x-----------2x

C2H4+3O2-to>2CO2+2H2O

y------------3y

=>\(\left\{{}\begin{matrix}x+y=0,25\\2x+3y=0,6\end{matrix}\right.\)

=>x=0,15 mol

     y=0,1 mol

=>%CH4=\(\dfrac{0,15.24,79}{6,1975}\).100=60%

=>%C2H4=40%

=>VCO2=(0,15+0,2).24,79=8,6765l

a, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2H_2+O_2\underrightarrow{t^o}2H_2O\)

Ta có: \(n_{CH_4}+n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\left(1\right)\)

Theo PT: \(n_{H_2O}=2n_{CH_4}+n_{H_2}=\dfrac{16,2}{18}=0,9\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,4\left(mol\right)\\n_{H_2}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,4.22,4}{11,2}.100\%=80\%\\\%V_{H_2}=20\%\end{matrix}\right.\)

b, Theo PT: \(n_{CO_2}=n_{CH_4}=0,4\left(mol\right)\Rightarrow V_{CO_2}=0,4.22,4=8,96\left(l\right)\)

Đề có thiếu thể tích hỗn hợp không em ơi !!

\(n_{CO_2}=\dfrac{9,916}{24,79}=0,4\left(mol\right);n_{CH_4}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\\ a,CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ Đặt:n_{CH_4}=a\left(mol\right);n_{C_2H_4}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}a+2b=0,4\\a+b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \Rightarrow\%V_{CH_4}=\%n_{CH_4}=\dfrac{a}{0,3}.100\%=\dfrac{0,2}{0,3}.100\approx66,667\%\\ \Rightarrow\%V_{C_2H_4}\approx33,333\%\\ c,C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\\ \Rightarrow C_{MddBr_2}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)

Chỗ kia chắc 200ml dung dịch Br₂ chứ 200gam thì cần cho thêm KLR á em

a) \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

          0,05-->0,1------->0,05

             2C₂H₂ + 5O₂ --t^o--> 4CO₂ + 2H₂O

            0,125<--0,3125<----0,25

=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,05}{0,05+0,125}.100\%=28,57\%\\\%V_{C_2H_2}=\dfrac{0,125}{0,05+0,125}.100\%=71,43\%\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{0,05.16+0,125.26}.100\%=19,753\%\\\%m_{C_2H_2}=\dfrac{0,125.26}{0,05.16+0,125.26}.100\%=80,247\%\end{matrix}\right.\)

b) \(n_{O_2}=0,1+0,3125=0,4125\left(mol\right)\)

=> \(V_{O_2}=0,4125.22,4=9,24\left(l\right)\)

=> V_kk = 9,24.5 = 46,2 (l)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{0,028}{22,4}=0,00125\left(mol\right)\left(1\right)\)

Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=\dfrac{0,0672}{22,4}=0,003\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,00025\left(mol\right)\\n_{C_2H_2}=0,001\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,00025.22,4}{0,028}.100\%=20\%\\\%V_{C_2H_2}=80\%\end{matrix}\right.\)

b, Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,00225\left(mol\right)\)

\(\Rightarrow V_{CO_2}=0,00225.22,4=0,0504\left(l\right)\)

a, \(CH_4+2O_2\underrightarrow{^{t^o}}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{^{t^o}}2CO_2+2H_2O\)

b, Gọi: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)

Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y=\dfrac{15,68}{22,4}=0,7\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=-0,1\\y=0,3\end{matrix}\right.\)

Đến đây thì ra số mol âm, bạn xem lại đề nhé.

a. \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

     a          2a      a

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

  b          3b       2b

b. \(n_{O_2}=\dfrac{25.88}{22.4}=1.155mol\)

n hỗn hợp khí \(=\dfrac{11.2}{22.4}=0.5mol\)

Ta có: \(\left\{{}\begin{matrix}a+b=0.5\\2a+3b=1.155\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.345\\b=0.155\end{matrix}\right.\)

\(\%V_{CH_4}=\dfrac{0.345\times22.4\times100}{11.2}=69\%\)

\(\%V_{C_2H_4}=100-69=31\%\)

c. \(V_{CO_2}=\left(a+2b\right)\times22.4=\left(0.345+2\times0.155\right)\times22.4=14.672l\)