Bài 1:

Ta có: \(\Sigma n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,05.0,01+0,05.0,005.2=0,001\left(mol\right)\)

\(n_{H^+}=n_{HCl}=0,05.0,015=0,00075\left(mol\right)\)

PT ion: \(OH^-+H^+\rightarrow H_2O\)

______0,001__0,00075 (mol)

⇒ OH^- dư. n_{OH^- (dư)} = 2,5.10^-4 (mol)

\(\Rightarrow\left[OH^-\right]=\frac{2,5.10^{-4}}{0,1}=2,5.10^{-3}M\Rightarrow\left[H^+\right]=4.10^{-12}M\)

\(\Rightarrow pH\approx11,4\)

Bài 2: Đáp án D

Giải:

Ta có: \(\Sigma n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,1.0,002+0,2.2.x=2.10^{-4}+0,4x\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\frac{2.10^{-4}+0,4x}{0,3}M\)

\(\Rightarrow pH=-log\left(\frac{2.10^{-4}+0,4x}{0,3}\right)=2,7\)

\(\Rightarrow x\approx9,964.10^{-4}\approx10^{-3}\)

Bạn tham khảo nhé!

a) 

Ta có : n_H⁺ = 0,025 mol      ;     n_OH^- = 4.10^-3 mol

         H^{+       +}         OH ^-  ----->   H₂O

Bđ: 0,025 mol     4.10^-3 mol

P/u: 4.10^-3 mol     4.10^-3

Sau:0,021mol        0

---> CMH⁺ = 0,021 / _0,5 =0,042 M

=> pH = -log [H^+] = 1,38

( mk k chắc là đúng k nữa vì số hơi lẻ , mong ktra lại , nếu mk có sai sót thì bạn cứ chỉnh sửa để mk biết nhé ! Cảm ơn...)

a) $Ba(OH)_2 + H_2SO_4 \to BaSO_4 + 2H_2O$

b)

$n_{H_2SO_4} = n_{BaSO_4} = n_{Ba(OH)_2} = 0,2.1 = 0,2(mol)$
$\Rightarrow a = \dfrac{0,2}{0,1} = 2M$

$m = 0,2.233 = 46,6(gam)$

Ta có: \(\left\{{}\begin{matrix}n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,1.0,01=0,001\left(mol\right)\\n_{OH^-}=2n_{Ba\left(OH\right)_2}=2.0,1.0,01=0,002\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\Sigma n_{H^+}=0,2.0,01+2.0,2.0,02=0,01\left(mol\right)\\n_{SO_4^{2-}}=n_{H_2SO_4}=0,2.0,02=0,004\left(mol\right)\end{matrix}\right.\)

PT ion: \(H^++OH^-\rightarrow H_2O\)

_____ 0,01___0,002_________ (mol)

⇒ H⁺ dư. \(\Rightarrow n_{H^+\left(dư\right)}=0,008\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\frac{0,008}{0,3}=\frac{2}{75}M\Rightarrow pH\approx1,57\)

PT ion: \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_{4\downarrow}\)

______ 0,001__0,004__ → 0,001 (mol)

\(\Rightarrow m_{\downarrow}=m_{BaSO_4}=0,001.233=0,233\left(g\right)\)

Bạn tham khảo nhé!

Đáp án D

pH =1 => [H+] = 0,1 => n H +  = 01.01 = 0,01 mol.

n O H -  = 0,1a

pH =12 => [H+] = 10^-12 => [OH-] =10^-2 => n O H -  dư = 0,01.(0,1+0,1) = 0,002 mol

=> 0,1a - 0,01 = 0,002 => a = 0,12.

\(n_{H_2SO_4}=0,005.0,1=0,0005\left(mol\right)\\ \Rightarrow n_{H^+}=2.0,0005=0,001\left(mol\right)\\ n_{NaOH}=0,1.0,002=0,0002\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,003.0,1=0,0003\left(mol\right)\\ \Rightarrow n_{OH^-}=0,0002+0,0003.2=0,0008\left(mol\right)\\ H^++OH^-\rightarrow H_2O\\ Vì:\dfrac{0,0008}{1}< \dfrac{0,001}{1}\Rightarrow H^+dư\\ \left[H^+\left(dư\right)\right]=\dfrac{0,001-0,0008}{0,1+0,1}=0,001\left(M\right)\\ \Rightarrow pH=-log\left[H^+\right]=-log\left[0,001\right]=3\)

\(m=m_{Na^+}+m_{Ba^{2+}}+m_{SO_4^{2-}}=0,0002.23+0,0003.137+0,0005.96=0,0937\left(g\right)\)

\(n_{NaOH}=0,1.0,01=0,001(mol)\\ \Rightarrow n_{OH^{-}}=0,001(mol)\\ n_{HCl}=0,03.0,2=0,006(mol)\\ \Rightarrow n_{H^{+}}=0,006(mol)\\ H^{+}+OH^{-}\to H_2O\\ 0,001<0,006\\ OH^{-} hêt; H^{+} dư\\ n_{H^{+}}=0,006-0,001=0,005(mol)\\ [H^{+}]=\frac{0,005}{0,1+0,2}=\frac{1}{60}M\\ \to pH=-log(\frac{1}{60})=1,77 \)