\(\text{+ nFeCl3= }\frac{19,5}{162,5}=\text{ 0.12 mol}\)

\(\text{+ nAl2(SO4)3= }\frac{27,36}{342}\text{= 0.08 mol}\)

\(\text{+ nH2SO4= }\frac{200}{98}\text{x9.8%= 0.2 mol}\)

\(\text{+ nNaOH=}\frac{77,6}{40}\text{=1.94 mol}\)

+ Cho A + NaOH ta có:

+ Kết tủa B gồm: Fe(OH)3

+ Dd C gồm: NaOH dư ; Na2SO4 ; NaCl ; NaAlO2

\(\text{a) + Chất rắn D là : Fe2O3 0.06 mol}\)

\(\Rightarrow\text{mD= 160x 0.06=9.6 g }\)

b) + mdd C= 400g

\(\text{+ C% NaOH=}\text{5.4%}\)

\(\text{+ C% Na2SO4=}15,62\%\)

\(\text{+ C% NaCl=}5,625\%\)

\(\text{+ C% NaAlO2= }3,28\%\)

nFeCl3 = 0,12

nAl2(SO4)3 = 0,08

nH2SO4 = 0,2

nNaOH = 1,94

Ưu tiên phản ứng trung hòa trước: H2SO4 + 2NaOH —> Na2SO4 + 2H2O

0,2 ——-> 0,4

FeCl3 + 3NaOH —> Fe(OH)3 + 3NaCl

0,12 —-> 0,36

Al2(SO4)3 + 6NaOH —> 2Al(OH)3 + 3Na2SO4

0,08 ———-> 0,48

Sau 3 phản ứng thì còn lại nNaOH = 0,7, sau đó:

Al(OH)3 + NaOH —> NaAlO2 + 2H2O

0,16 ——-> 0,16

Nung kết tủa: 2Fe(OH)3 —> Fe2O3 + 3H2O

0,12 ————>0,06

m = 9,6 gam

Phần dung dịch chứa Na2SO4 (0,44 mol), NaCl (0,36 mol), NaAlO2 (0,16 mol) và NaOH dư (0,54 mol) —> C% ll là 15,62%; 5,625 %; 3,28%; 5,4%.

Ta có :

\(\text{nFeCL3=0.12 nAl2(SO4)3=0.08 nH2SO4=0.2}\)

a. nNaOH=1.94

\(\text{2NaOH+H2SO4-->Na2SO4+2H2O}\)

0.4................0.2..........................................(mol)

\(\text{nNaOH còn=1.54}\)

\(\text{FeCL3+ 3NaOH-->Fe(OH)+3NaCl}\)

0.12...............0.36............0.12..........................(mol)

\(\text{nNaOH còn =1.18}\)

\(\text{ Al2(SO4)3+ 6NaOH-->2Al(OH3)+3Na2SO4}\)

0.08.....................0.48............0.16.................................(mol)

\(\text{-->nNaOH còn=0.7}\)

\(\text{Al(OH)3+ NaOH-->NaAlO2+2H2O}\)

0.16.................0.16............0.16.......................................(mol)

nNaOh còn =0.54

Nung B 2Fe(OH)3-->Fe2O3+3H2O

0.12 0.06

m=9.6

b.mdd H2SO4 ban đầu =1.14*200=228g

-->MddC=19.5+27.36+228-0.12*107=262.02

m nước cần thêm là 400-mddC=137.98

\(\left\{{}\begin{matrix}\text{c%NaOH dư=0.54*40/400=0.054%}\\\text{c%NaAlO2=0.16*82/400=0.0328%}\end{matrix}\right.\)

a)

$Fe_2(SO_4)_3 + 6KOH \to 2Fe(OH)_3 + 3K_2SO_4$

b)

$n_{Fe_2(SO_4)_3} = 0,3.1 = 0,3(mol)$
$n_{KOH} = \dfrac{16,8}{56} =0,3(mol)$

Ta thấy : 

$n_{KOH} : 3 < n_{Fe_2(SO_4)_3} : 1$ nên $Fe_2(SO_4)_3$ dư

$n_{Fe(OH)_3} = \dfrac{1}{3}n_{KOH} = 0,1(mol)$
$n_{Fe_2O_3} = \dfrac{1}{2}n_{Fe(OH)_3} = 0,05(mol)$

$m_{Fe_2O_3} = 0,05.160 = 8(gam)$

\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\) (1)

\(6NaOH+Fe_2\left(SO_4\right)_3\rightarrow2Fe\left(OH\right)_3+3Na_2SO_4\) (2)

\(n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right);n_{Fe_2\left(SO_4\right)_3}=\dfrac{200.4\%}{400}=0,04\left(mol\right)\)

\(TheoPT\left(1\right):n_{NaOH}=n_{Na}=0,4\left(mol\right)\)

Lập tỉ lệ PT (2) : \(\dfrac{0,4}{6}>\dfrac{0,04}{1}\)

=> Sau phản ứng NaOH dư

\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)

Bảo toàn nguyên tố Fe: \(n_{Fe_2O_3}.2=n_{Fe_2\left(SO_4\right)_3}.2\Rightarrow n_{Fe_2O_3}=0,04\left(mol\right)\)

=> \(m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\)

Dung dịch A: \(Na_2SO_4:0,12\left(mol\right);NaOH_{dư}:0,4-0,24=0,16\left(mol\right)\)

\(m_{ddsaupu}=9,2+200-0,08.107=200,64\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{0,12.142}{200,64}=8,5\%\)

\(C\%_{NaOH}=\dfrac{0,16.40}{200,64}.100=3,2\%\)