chịu

Em kiểm tra lại đề nhé. Dữ kiện mất mát 5% hơi mẫu thuẫn. Vì hiệu suất có là 60% nên lượng mất mát đã là 40% rồi

PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(\left\{{}\begin{matrix}n_{Al\left(LT\right)}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\\n_{HCl\left(LT\right)}=2n_{H_2}=0,6\left(mol\right)\end{matrix}\right.\)

Mà: H% = 80%

\(\Rightarrow\left\{{}\begin{matrix}n_{Al\left(TT\right)}=\dfrac{0,2}{80\%}=0,25\left(mol\right)\\n_{HCl\left(TT\right)}=\dfrac{0,6}{80\%}=0,75\left(mol\right)\end{matrix}\right.\)

⇒ m_Al = 0,25.27 = 6,75 (g)

m_HCl = 0,75.36,5 = 27,375 (g)

\(H_2+Cl_2\left(0,18\right)\rightarrow2HCl\left(0,36\right)\)

\(n_{H_2}=\frac{10}{22,4}\approx0,446\left(mol\right)\)

\(n_{Cl_2}=\frac{6,72}{22,4}=0,3\left(mol\right)\)

Vì \(\frac{n_{H_2}}{1}=0,446>\frac{n_{Cl_2}}{1}=0,3\) nên ta tính HCl theo Cl₂

Số mol Cl₂ tham gia phản ứng là: \(0,3.60\%=0,18\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,36.36,5=13,14\left(g\right)\)

\(\Rightarrow m_{HCl\left(conlai\right)}=13,14.\left(100\%-5\%\right)=12,483\left(g\right)\)

\(n_{AgCl}=\dfrac{43.05}{143.5}=0.3\left(mol\right)\) \(\Rightarrow n_{HCl}=0.3\left(mol\right)\)

\(n_{HCl}=\dfrac{6.72}{22.4}=0.3\left(mol\right),n_{Cl_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(H_2+Cl_2\underrightarrow{^{^{t^0}}}2HCl\)

\(0.15....0.15.......0.3\)

\(H\%=\dfrac{0.15}{0.2}\cdot100\%=75\%\)

$n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)$

$n_{H_2\ pư} = 0,3.25\% = 0,075(mol)$
\(N_2 + 3H_2 \buildrel{xt,t^,p}\over\rightleftharpoons 2NH_3\)

Theo PTHH : 

$n_{NH_3} = \dfrac{2}{3}n_{H_2\ pư} = 0,05(mol)$
$m = 0,05.17 = 0,85(gam)$

\(n_{AgCl}=\dfrac{7,175}{143,5}=0,05\left(mol\right)\)

PTHH: HCl + AgNO₃ ---> AgCl↓ + HNO₃

           0,05<---------------0,05
\(\rightarrow m_{HCl}=0,05.36,5=1,825\left(g\right)\\ \rightarrow C\%_{ddA}=\dfrac{1,825}{50}.100\%=3,65\%\)

\(n_{Cl_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Đặt H = x%

PTHH: Cl₂ + H₂ --as--> 2HCl

LTL: 6,72 < 10 => H₂ dư

=> n_HCl = 0,3x (mol)

\(\rightarrow C\%_{HCl}=\dfrac{0,3x.36,5}{0,3x.36,5+385,4}.100\%=3,65\%\\ \Leftrightarrow20,23\%\)

Đáp án D

$N_2 + 3H_2 \buildrel{{t^o,xt,p}}\over\rightleftharpoons 2NH_3$

Ta thấy :  $V_{N_2} : 1 > V_{H_2} : 3$ nên $N_2$ dư

Gọi hiệu suất là a

Suy ra : $V_{H_2\ pư} = 11,2a(lít)$
$V_{N_2\ pư} = \dfrac{11,2a}{3}$
$V_{NH_3} = \dfrac{2.11,2a}{3} $

Ta có : 

$11,2 - 11,2a + 6,72 - \dfrac{11,2a}{3} + \dfrac{2.11,2a}{3} = 13,44$
$\Rightarrow a = 0,6 =6 0\%$

$n_{H_2} = \dfrac{10,08}{22,4} = 0,45(mol)$

$n_{H_2\ pư} = 0,45.37\% = 0,1665(mol)$
$N_2 + 3H_2 \buildrel{xt,t^,p}\over\rightleftharpoons 2NH_3$

$n_{NH_3} = \dfrac{3}{2}n_{H_2}= 0,111(mol)$
$V = 0,111.22,4 = 2,4864(lít)$