Câu 4 : 

Vì bạc không tác dụng với axit sunfuric loãng : 

\(n_{H2}=\dfrac{0,224}{22,4}=0,01\left(mol\right)\)

a) Pt : \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2|\) 

             1           1                1           1

             0,01                       0,01      0,01

b) \(n_{Zn}=\dfrac{0,0.1}{1}=0,01\left(mol\right)\)

\(m_{Zn}=0,01.65=0,65\left(g\right)\)

\(m_{Ag}=1,73-0,65=1,08\left(g\right)\)

⁰/₀Zn = \(\dfrac{0,65.100}{1,73}=37,57\)⁰/₀

⁰/₀Ag = \(\dfrac{1,08.100}{1,73}=62,43\)⁰/₀

c) \(n_{ZnSO4}=\dfrac{0,01.1}{1}=0,01\left(mol\right)\)

⇒ \(m_{ZnSO4}=0,01.161=1,61\left(g\right)\)

 Chúc bạn học tốt

a)

Zn + 2HCl  →  ZnCl₂  +  H₂

Fe + 2HCl  →  FeCl₂  +  H₂

b) Gọi số mol Zn và Fe có trong 17,7 gam hỗn hợp là x và y mol. nH₂ = \(\dfrac{6,72}{22,4}\)=0,3 mol

Theo tỉ lệ phản ứng ta có \(\left\{{}\begin{matrix}x+y=0,3\\65x+56y=17,7\end{matrix}\right.\)=> x = 0,1 và y = 0,2 

=> m_Zn = 0,1.65 = 6,5 gam và m_Fe= 0,2.56 = 11,2 gam

c) nHCl = 2nH₂ = 0,3.2 = 0,6 mol

Áp dụng ĐLBT khối lượng => m muối clorua =  mKl + mHCl - mH₂ 

<=> m muối = 17,7 + 0,6.36,5 - 0,3.2 = 28,05 gam

Gọi a, b lần lượt là mol của Al và Zn

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

a                                        1,5a

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b                                       b

\(\Rightarrow\left\{{}\begin{matrix}27a+65b=9,2\\1,5a+b=\dfrac{5,6}{22,4}\end{matrix}\right.\)                \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,1.27}{9,2}.100\%=29,35\%\)

\(\%m_{Zn}=\dfrac{0,1.65}{9,2}.100\%=70,35\%\)

b. \(n_{H_2}=0,25mol\)           \(\Rightarrow n_{HCl}=0,5mol\)

\(\Rightarrow m_{HCl}=0,5.36,5=18,25g\)

Ta có:  \(10\%=\dfrac{18,25}{m_{dd}}.100\%\)

\(\Leftrightarrow m_{dd}=182,5g\)

a) Cu + 2H₂SO₄ → CuSO₄ + SO₂↑ + 2H₂O

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{SO_2}=n_{Cu}=0,2\left(mol\right)\)

\(\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)

\(\%m_{Cu}=\dfrac{12,8}{20,8}.100=61,54\%\); \(\%m_{CuO}=38,46\%\)

b) \(n_{CuO}=\dfrac{20,8-12,8}{80}=0,1\left(mol\right)\)

\(n_{H_2SO_4}=0,2.2+0,1=0,5\left(mol\right)\)

\(m_{ddH_2SO_4}=\dfrac{0,5.98}{80\%}=61,25\left(g\right)\)

\(n_{CuSO_4}=0,2+0,1=0,3\left(mol\right)\)

\(m_{CuSO_4}=0,3.160=48\left(g\right)\)

Tr oi cuu với ạ

\(\text{Đặt }\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a,PTHH:\left\{{}\begin{matrix}2Al+6HCl\rightarrow2AlCl_3+3H_2\\Fe+2HCl\rightarrow FeCl_2+H_2\end{matrix}\right.\\ b,\text{Theo đề ta có HPT: }\left\{{}\begin{matrix}27x+56y=8,3\\\dfrac{3}{2}x+y=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%_{Al}=\dfrac{0,1\cdot27}{8,3}\approx32,53\%\\\%_{Fe}\approx67,47\%\end{matrix}\right.\)

\(c,\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\end{matrix}\right.\\ \Rightarrow\sum m_{muối}=13,35+12,7=26,05\left(g\right)\)

Câu 1: 

\(n_{H_2}=\dfrac{2.91362}{22.4}=0.13mol\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

 a           a                a           a

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

 2b          3b               b                 3b

Ta có: \(\left\{{}\begin{matrix}24a+54b=2.58\\a+3b=0.13\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.04\\b=0.03\end{matrix}\right.\)

\(m_{Mg}=0.04\times24=0.96g\)

\(m_{Al}=0.03\times2\times27=1.62g\)

\(V_{H_2SO_4}=\dfrac{0.04+3\times0.03}{0.5}=0.26l\)

Câu 2:

\(n_{H_2}=\dfrac{3.136}{22.4}=0.14mol\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

a            a              a             a

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b           b                 b         b

Ta có: \(\left\{{}\begin{matrix}24a+56b=4.96\\a+b=0.14\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.09\\b=0.05\end{matrix}\right.\)

\(m_{Mg}=0.09\times24=2.16g\)

\(m_{Fe}=0.05\times56=2.8g\)

\(C\%_{H_2SO_4}=\dfrac{0.14\times98\times100}{200}=6.86\%\)

Câu 3: 

\(n_{H_2}=\dfrac{1.568}{22.4}=0.07mol\)

\(Ba+H_2SO_4\rightarrow BaSO_4+H_2\)

a           a              a             a

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

b          b                 b             b

Ta có: \(\left\{{}\begin{matrix}137a+24b=3.94\\a+b=0.07\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.02\\b=0.05\end{matrix}\right.\)

\(m_{Ba}=0.02\times137=2.74g\)

\(m_{Mg}=0.05\times24=1.2g\)

\(CM_{H_2SO_4}=\dfrac{0.07}{0.1}=0.7M\)

Gọi số mol Mg, Fe, Al là a, b, c

=> 24a + 56b + 27c = 23,8

PTHH: Mg + 2HCl --> MgCl₂ + H₂ 

            a------------------------->a

            Fe + 2HCl --> FeCl₂ + H₂

            b------------------------->b

            2Al + 6HCl --> 2AlCl₃ + 3H₂ 

            c------------------------->1,5c

=> a + b + 1,5c = \(\dfrac{17,92}{22,4}=0,8\left(mol\right)\)

PTHH: Mg + Cl₂ --t^o--> MgCl₂

             a-->a

            2Fe + 3Cl₂ --t^o--> 2FeCl₃

             b--->1,5b

             2Al + 3Cl₂ --t^o--> 2AlCl₃

             c--->1,5c

=> \(a+1,5b+1,5c=\dfrac{20,16}{22,4}=0,9\left(mol\right)\)

=> a = 0,3; b = 0,2; c = 0,2

=> \(\left\{{}\begin{matrix}m_{Mg}=0,3.24=7,2\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)

a) 

\(n_{H_2}=\dfrac{9,916}{24,79}=0,4\left(mol\right)\)

PTHH: Zn + H₂SO₄ --> ZnSO₄ + H₂

_____0,4<---0,4<--------0,4<----0,4

=> m_Zn = 0,4.65 = 26 (g)

=> \(\left\{{}\begin{matrix}\%Zn=\dfrac{26}{51,6}.100\%=50,388\%\\\%Cu=\dfrac{51,6-26}{51,6}.100\%=49,612\text{%}\end{matrix}\right.\)

b) 

m_ZnSO4 = 0,4.161 = 64,4 (g)

c) 

\(V_{ddH_2SO_4}=\dfrac{0,4}{2}=0,2\left(l\right)\)