Coi $n_A = 1(mol) \Rightarrow m_A = 1.2.13,5 = 27(gam)$
$m_{NH_3} + m_{O_2} + m_{N_2} = 27$

$\Rightarrow \dfrac{7}{8}m_{O_2} + m_{O_2} + \dfrac{3}{6} (m_{O_2} + m_{NH_3} ) = 27$

$\Rightarrow \dfrac{7}{8}m_{O_2} + m_{O_2} + \dfrac{3}{6} (m_{O_2} + \dfrac{7}{8}m_{O_2} ) = 27$
$\Rightarrow \dfrac{45}{16}m_{O_2} = 27 \Rightarrow m_{O_2} = 9,6(gam)$

Suy ra: 

$m_{NH_3} = 8,4 ; m_{N_2} = 9$

Suy ra : $n_{O_2} = 0,3(mol) ; n_{NH_3} = \dfrac{42}{85}(mol)$

$\%V_{O_2} = \dfrac{0,3}{1}.100\% = 30\%$
$\%V_{NH_3} = 49,41\%$
$\%V_{N_2} = 20,59\%$

a)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(n_{H_2O}=\dfrac{1,8}{18}=0,1\left(mol\right)\)

PTHH: 2H₂ + O₂ --t^o--> 2H₂O

            0,1<-0,05<-------0,1

            2CO + O₂ --t^o--> 2CO₂

            0,2<--0,1-------->0,2

=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\V_{CO}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)

b) \(m_{CO_2}=0,2.44=8,8\left(g\right)\)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(n_{H_2O}=\dfrac{1,8}{18}=0,1mol\)

\(2CO+O_2\rightarrow2CO_2\)

  a         0,5a     a

\(2H_2+O_2\rightarrow2H_2O\)

 0,1   0,05 \(\leftarrow\)    0,1

\(\Sigma n_{O_2}=0,5a+0,05=0,15\)

\(\Rightarrow a=n_{O_2\left(CO\right)}=0,2mol\)

\(V_{CO}=2\cdot0,2\cdot22,4=8,96l\)

\(V_{H_2}=0,1\cdot22,4=2,24l\)

\(m_{CO_2}=0,2\cdot44=8,8g\)

\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)

\(\overline{M_x}=24.2=48\)

\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\)       48    = \(\dfrac{16}{16}=1\)

\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)

1. \(m_{hh}=0,3.64+0,3.32=28,8g\)

2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)

\(\Rightarrow\%V_{O_2}=50\%\)

3. \(m_{SO_2}=0,3.64=19,2g\)

\(m_{O_2}=0,3.32=9,6g\)

a/ \(2CO\left(0,2\right)+O_2\left(0,1\right)\rightarrow2CO_2\left(0,2\right)\)

\(2H_2\left(0,1\right)+O_2\left(0,05\right)\rightarrow2H_2O\left(0,1\right)\)

\(n_{H_2O}=\frac{1,8}{18}=0,1\)

\(n_{O_2}=\frac{3,36}{22,4}=0,15\)

Số mol O₂ phản ứng ở phản ứng đầu là: \(0,15-0,05=0,1\)

\(\Rightarrow m_{CO_2}=0,2.44=8,8\)

b/ \(m_{CO}=0,2.28=5,6\)

\(m_{H_2}=0,1.2=0,2\)

c/ \(\%CO=\frac{0,2}{0,3}.100\%=66,67\%\)

\(\Rightarrow\%H_2=100\%-66,67\%=33,33\%\)

a) \(n_{N_2}+n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)

Có: \(28.n_{N_2}+44.n_{CO_2}=24,4\)

=> \(\left\{{}\begin{matrix}n_{N_2}=0,4\left(mol\right)\\n_{CO_2}=0,3\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%V_{N_2}=\dfrac{0,4}{0,7}.100\%=57,143\%\\\%V_{CO_2}=\dfrac{0,3}{0,7}.100\%=42,857\%\end{matrix}\right.\)

b) \(\left\{{}\begin{matrix}m_{N_2}=0,4.28=11,2\left(g\right)\\m_{CO_2}=0,3.44=13,2\left(g\right)\end{matrix}\right.\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a          2a          a            a

\(FeS+2HCl\rightarrow FeCl_2+H_2S\uparrow\)

b            2b            b            b

\(n_{HCl}=\dfrac{400\times7.3}{100\times36.5}=0.8mol\)

\(n_X=\dfrac{4.48}{22.4}=0.2mol\)

\(M_X=2\times9=18\Leftrightarrow\dfrac{2a+34b}{a+b}=18\)

Ta có: \(\left\{{}\begin{matrix}a+b=0.2\\\dfrac{2a+34b}{a+b}=18\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a+b=0.2\\2a+34b=3.6\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.1\\b=0.1\end{matrix}\right.\)

a. \(\%V_{H_2}=\dfrac{0.1\times22.4\times100}{4.48}=50\%\)

\(\%V_{H_2S}=100-50=50\%\)

b. \(a=0.1\times56+0.1\times88=14.4g\)

\(\%m_{Fe}=\dfrac{0.1\times56}{14.4}\times100=38.8\%\)

\(\%m_{FeS}=100-38.8=61.2\%\)

c. m dung dịch sau phản ứng\(=14.4+400-0.1\times2-0.1\times34=410.8g\)

nHCl phản ứng\(=2\times0.1+2\times0.1=0.4mol\)

nHCl dư = 0.8 - 0.4 = 0.4 mol

\(C\%_{HCldu}=\dfrac{0.4\times36.5\times100}{410.8}=3.55\%\)

\(C\%_{FeCl_2}=\dfrac{0.2\times127\times100}{410.8}=6.18\%\)

1)

Coi \(n_X = 1(mol)\)

Gọi : \(n_{CO_2} = a(mol) ; n_{N_2} = b(mol)\)

Ta có :

\(n_X = a + b = 1(mol)\\ m_X = 44a + 28b = 1.1,225.32(gam)\\ \Rightarrow a = 0,7 ; b = 0,3\)

Vậy :

\(\%V_{CO_2} = \dfrac{0,7}{1}.100\% = 70\%\\ \%V_{N_2} = 100\% - 70\% = 30\%\)

2)

\(n_X = \dfrac{1}{22,4}(mol)\\ \Rightarrow m_X = n.M = \dfrac{1}{22,4}.1,225.32 = 1,75(gam)\)