Đáp án B

[OH^-]= (0,5.2.0,1+0,1.0,5)/0,2= 0,75M

a, \(\left[Ca^{2+}\right]=\dfrac{0,15.0,5}{0,15+0,05}=0,375M\)

\(\left[Na^+\right]=\dfrac{0,05.2}{0,15+0,05}=0,5M\)

\(\left[Cl^-\right]=\dfrac{0,15.2.0,5+0,05.2}{0,15+0,05}=1,25M\)

b, \(\left[Fe^{3+}\right]=\dfrac{\dfrac{2.1,6}{400}}{1,5}\approx0,005M\)

\(\left[K^+\right]=\dfrac{\dfrac{2.6,96}{174}}{1,5}\approx0,053M\)

\(\left[SO_4^{2-}\right]=\dfrac{\dfrac{3.1,6}{400}+\dfrac{6,96}{174}}{1,5}\approx0,035M\)

[K+]=[Cl-]=0,25M

[KOH dư]=0,25M

b)   2KCl   +    H₂SO₄    ----------->K₂SO₄   + 2HCl

  0,05(mol)---->0,025(mol)

=>v_H2SO4=\(\frac{0,025}{1}\)=0,025(lít)

c)pH=-log(0,25)=0,602

(câu c mình không chắc chắn lắm nha bạn!!!)

câu a) làm sao vậy mn chỉ mik vs

a, \(K_2SO_4\rightarrow2K^++SO_4^{2-}\)

___0,5_______1______0,5_ (mol)

\(\Rightarrow\left\{{}\begin{matrix}\left[K^+\right]=\frac{1}{2}=0,5M\\\left[SO_4^{2-}\right]=\frac{0,5}{2}=0,25M\end{matrix}\right.\)

b, Ta có: \(n_{OH^-}=n_{K^+}=n_{KOH}=0,2.1=0,2\left(mol\right)\)

\(n_{H^+}=n_{Cl^-}=0,1.1=0,1\left(mol\right)\)

PT ion: \(OH^-+H^+\rightarrow H_2O\)

______0,2_____0,1_________ (mol)

⇒ OH^- dư. ⇒ n_{OH^- (dư)} = 0,1 (mol)

Dd X gồm: K⁺; Cl^- và OH^-_(dư).

\(\Rightarrow\left\{{}\begin{matrix}\left[K^+\right]=\frac{0,2}{0,3}=\frac{2}{3}M\\\left[Cl^-\right]=\frac{0,1}{0,3}=\frac{1}{3}M\\\left[OH^-\right]_{\left(dư\right)}=\frac{0,1}{0,3}=\frac{1}{3}M\end{matrix}\right.\)

c, Ta có: \(\left\{{}\begin{matrix}n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,0005.0,5=0,00025\left(mol\right)\\n_{OH^-}=2n_{Ba\left(OH\right)_2}=2.0,0005.0,5=0,0005\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\Sigma n_{H^+}=n_{HNO_3}+n_{HCl}=1.0,1+1.0,05=0,15\left(mol\right)\\n_{NO_3^-}=n_{HNO_3}=1.0,1=0,1\left(mol\right)\\n_{Cl^-}=n_{HCl}=1.0,05=0,05\left(mol\right)\end{matrix}\right.\)

PT ion: \(OH^-+H^+\rightarrow H_2O\)

____0,0005____0,15_________ (mol)

⇒ H⁺ dư. ⇒ n_{H⁺ (dư)} = 0,1495 (mol)

Dd D gồm: Ba²⁺; NO₃^-; Cl^- và H⁺_(dư)

\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\frac{0,00025}{1,0005}\approx2,5.10^{-4}M\\\left[NO_3^-\right]=\frac{0,1}{1,0005}\approx0,09M\\\left[Cl^-\right]=\frac{0,05}{1,0005}\approx0,049M\\\left[H^+\right]_{\left(dư\right)}=\frac{0,1495}{1,0005}\approx0,15M\end{matrix}\right.\)

Bạn tham khảo nhé!

Mà phần c số lẻ quá, không biết đề là 0,5 ml hay 0,5 lít bạn nhỉ?

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)

nNaOH = 0,1.0,2 = 0,02 mol => nOH^- = 0,02 mol

nCa(OH)₂ = 0,1.0,2 = 0,02 mol => nOH^- = 0,02.2 = 0,04 mol

=> Sau khi trộn nOH^- = 0,02 + 0,04 = 0,06 mol

Thể tích dung dịch sau khi trộn = 100 + 200 = 300ml = 0,3 lít

=> [OH^-] = \(\dfrac{0,06}{0,3}\)= 0,2 M

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

0,2.............0,1

Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư

Dung dịch D gồm NaNO3 và NaOH dư

\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)

Ion trong dung dịch D : Na+ , NO3-, OH-

\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)

\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)

\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)

b)Trong dung dịch D chỉ có NaOH dư phản ứng

 \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

0,1................0,05

=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)

Tách ra lần bài đi em !