nBaO=30,6/153=0,2(mol)

a) PTHH: BaO + 2 HNO3 -> Ba(NO3)2 + H2O

b) nHNO3=0,2.2=0,4(mol) => mHNO3= 63.0,4=25,2(g)

=>C%ddHNO3=(25,2/150).100=16,8%

a)m_H2SO4=\(\dfrac{200.7,3\text{%}}{100\%}\)=14,6g

n_HCl=\(\dfrac{14,6}{36,5}\)=0,4(mol)

PTHH:

NaOH+ HCl→ NaCl+ H₂O

1            1            1         1

0,4        0,4         0,4     (mol)

⇒m_NaOH=0,4.40=16(g)

Nồng độ % của dd NaOH cần dùng là:

C_%NaOH=\(\dfrac{16}{200}\)   .100%=8%

b)Ta có:m_{dd spứ}=m_{dd trc pứ}=400g

m_NaCl=0,4.58,5=23,4g

Nồng độ % dd muối tạo thành sau pứ là:

C_%dd NaCl=\(\dfrac{23,4}{400}\)   .100%=5,85%        

a, \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)

Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,2.84}{64,8}.100\%\approx25,93\%\\\%m_{MgSO_4}\approx74,07\%\end{matrix}\right.\)

b, - Dung dịch C gồm: MgCl₂, MgSO₄ và HCl dư.

Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{CO_2}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{CO_2}=0,4\left(mol\right)\end{matrix}\right.\)

Ta có: \(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,5-0,4=0,1\left(mol\right)\)

\(m_{MgSO_4}=64,8-0,2.84=48\left(g\right)\Rightarrow n_{MgSO_4}=\dfrac{48}{120}=0,4\left(mol\right)\)

Có: m _{dd sau pư} = 64,8 + 100 - 0,2.44 = 156 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,2.95}{156}.100\%\approx12,18\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{156}.100\%\approx2,34\%\\C\%_{MgSO_4}=\dfrac{48}{156}.100\%\approx30,77\%\end{matrix}\right.\)

c, PT: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)

\(HCl+NaOH\rightarrow NaCl+H_2O\)

\(MgSO_4+2NaOH\rightarrow Na_2SO_4+Mg\left(OH\right)_{2\downarrow}\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}+n_{MgSO_4}=0,6\left(mol\right)\)

\(\Rightarrow m_{cr}=m_{MgO}=0,6.40=24\left(g\right)\)

\(n_{Na}=\dfrac{m}{M}=\dfrac{4,6}{23}=0,2\left(mol\right)\)

\(n_{ddH_2SO_4}=\dfrac{m}{M}=\dfrac{200}{98}=2\)

PTHH:\(2Na+H_2SO_4\rightarrow Na_2SO_4+H_2\)

tpư:     0,2          2        

pư:      0,2          0,1           0,1           0,1

spư:      0           1,9            0,1         0,1

a)\(V_{H_2}=n.22,4\)=0,1.22,4=2,24

b)\(m_{Na_2SO_4}=n.M\)=0,1.142=14,2

\(m_{H_2SO_4dư}=n.M\)=1,9.98=186,2

c)\(C\%H_2SO_4=\dfrac{m_{ct}}{m_{dd}}.100=\dfrac{0,1.98}{200}.100\)=0,099%

\(n_{CuSO4}=\dfrac{16\%.50}{100\%.160}=0,05\left(mol\right)\)

Pt : \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

       0,05-------->0,1---------->0,05--------->0,05

a) \(C\%_{ddNaOH}=\dfrac{0,1.40}{250}.100\%=1,6\%\)

b) \(m_{ddspu}=50+250-0,05.98=295,1\left(g\right)\)

\(C\%_{Na2SO4}=\dfrac{0,05.142}{295,1}.100\%=2,41\%\)

\(n_{CuSO_4}=\dfrac{m_{dd}\cdot C\%}{100\cdot M}=\dfrac{50\cdot16\%}{100\cdot\left(64+32+16\cdot4\right)}=0,05\left(mol\right)\)

\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

                     1                  2                    1                    1

                   0,05              0,1                 0,05               0,05 (mol)

\(a)C\%_{NaOH}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{01\cdot100\cdot\left(23+16+1\right)}{250}=1,6\%\)

\(b)m_{dd-sau-pư}=m_{dd_đ}+m_{ct_đ}-m\downarrow-m\uparrow\)

\(=50+250-\left(0,05\cdot23+32+16\cdot4\right)=294,05\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{0,05\cdot100\cdot\left(23\cdot2+32+16\cdot4\right)}{294,05}\approx2,41\%.\)

nCuSO4​=100%.16016%.50​=0,05(mol)

Pt : ����4+2����→��(��)2+��2��4CuSO4​+2NaOH→Cu(OH)2​+Na2​SO4​

       0,05-------->0,1---------->0,05--------->0,05

a) �%������=0,1.40250.100%=1,6%C%ddNaOH​=2500,1.40​.100%=1,6%

b) ������=50+250−0,05.98=295,1(�)mddspu​=50+250−0,05.98=295,1(g)

�%��2��4=0,05.142295,1.100%=2,41%C%Na2SO4​=295,10,05.142​.100%=2,41%

 a)           CO₂+        2NaOH→        Na₂CO₃+      H₂O

(mol)       0,05           0,1                  0,05             0,05

b) \(n_{CO_2}=\dfrac{V}{22,4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)                             

\(m_{Na_2CO_3}=n.M=0,05.106=5,3\)(g)

c)đổi: 200ml=0,2 lít

\(C_{M_{NaOH}}=\dfrac{n}{V}=\dfrac{0,1}{0,2}=0,5M\)

a) $CaSO_3 + 2HCl \to CaCl_2 + SO_2 + H_2O$
b)

$n_{SO_2} = n_{CaSO_3} = \dfrac{12}{120} = 0,1(mol)$
$m_{SO_2} = 0,1.64 = 6,4(gam)$

c)

$n_{HCl} = 2n_{SO_2} = 0,2(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$

d)

$m_{dd\ sau\ pư} = m_{CaSO_3} + m_{dd\ HCl} - m_{SO_2} = 12 + 50 - 6,4 = 55,6(gam)$

$C\%_{CaCl_2} = \dfrac{0,1.111}{55,6}.100\% = 19,96\%$

Ta có: \(n_{CaSO_3}=\dfrac{12}{120}=0,1\left(mol\right)\)

a. PTHH: CaSO₃ + 2HCl ---> CaCl₂ + H₂O + SO₂

b. Theo PT: \(n_{SO_2}=n_{CaSO_3}=0,1\left(mol\right)\)

=> \(m_{SO_2}=0,1.64=6,4\left(g\right)\)

c. Theo PT: \(n_{HCl}=2.n_{CaSO_3}=2.0,1=0,2\left(mol\right)\)

=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{7,3}{m_{dd_{HCl}}}.100\%=14,6\%\)
=> \(m_{dd_{HCl}}=50\left(g\right)\)

d. Ta có: \(m_{dd_{CaCl_2}}=12+50-0,1.64=55,6\left(g\right)\)

Theo PT: \(n_{CaCl_2}=n_{SO_2}=0,1\left(mol\right)\)

=> \(m_{CaCl_2}=0,1.111=11,1\left(g\right)\)

=> \(C_{\%_{CaCl_2}}=\dfrac{11,1}{55,6}.100\%=19,96\%\)