Trộn 100 ml dung dikch HCL 0.1M với 300ml dung dịch HCl 0.04M 

\(n_{HCl}=0,1.0,1=0,01\left(mol\right);n_{HCl}=0,3.0,04=0,012\left(mol\right)\)

Dung dịch gồm H+ và Cl-

\(n_{H^+}=0,01+0,012=0,022\left(mol\right)\)

=> \(\left[H^+\right]=\dfrac{0,022}{0,4}=0,055M\)

\(n_{Cl^-}=0,01+0,012=0,022\left(mol\right)\)

=>\(\left[Cl^-\right]=\dfrac{0,022}{0,4}=0,055M\)

Trộn 100ml dung dịch HNO3 0.1M với 400ml dung dịch H2SO4 0.03M

\(n_{HNO_3}=0,1.0,1=0,01\left(mol\right);n_{H_2SO_4}=0,04.0,3=0,012\left(mol\right)\)

Dung dịch sau khi trộn gồm :

\(n_{H^+}=0,01+0,012.2=0,034\left(mol\right)\)

=> \(\left[H^+\right]=\dfrac{0,034}{0,5}=0,068M\)

\(n_{NO_3^-}=0,01\left(mol\right)\)

=>\(\left[NO_3^-\right]=\dfrac{0,01}{0,5}=0,02M\)

\(n_{SO_4^{2-}}=0,012\left(mol\right)\)

=> \(\left[SO_4^{2-}\right]=\dfrac{0,012}{0,5}=0,024M\)

\(pH=2\Rightarrow\left[H^+_{dư}\right]=10^{-2}\Rightarrow n_{H^+}=10^{-2}\left(V+0,4\right)\)

\(n_{H^+}=2.0,0375.0,4+0,0125.0,4=0,035\left(mol\right)\)

\(n_{OH^-}=0,3V\left(mol\right)\)

\(\Rightarrow0,035+0,3V=10^{-2}\left(V+0,4\right)\)

\(\Rightarrow V=33,1\left(l\right)\)

\(\Leftrightarrow V=\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02........0.02\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)

\(a.\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02.......0.02\)

\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)

a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

b) Ta có: \(pH=14+log\left[OH^-\right]=13\)

c) PT ion: \(OH^-+H^+\rightarrow H_2O\)

Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)

 

a, \(\left[Na^+\right]=0,1\)

\(\left[K^+\right]=0,1\)

\(\left[OH^-\right]=0,2\)

\(\left[SO_4^{2-}\right]=0,2\)

\(\left[H^+\right]=0,4\)

b, \(n_{H^+}=0,1.0,4=0,04\left(mol\right)\)

\(n_{OH^-}=0,1.0,2=0,02\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(\Rightarrow n_{H^+dư}=0,02\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,02}{200}=10^{-4}\)

\(\Rightarrow pH=4\)

$n_{NaOH} = n_{KOH} = 0,1.0,1 = 0,01(mol)$
$n_{H_2SO_4} = 0,02(mol)$

              OH^- + H⁺ → H₂O

       Bđ : 0,01...0,04..................(mol)

      Pư : 0,01...0,01...................(mol)

Sau pư :   0......0,03...................(mol)

$V_{dd} = 0,1 + 0,1 = 0,2(lít)$

Vậy : 

 $[K^+] = [Na^+] = \dfrac{0,01}{0,2} = 0,05M$
$[H^+] = \dfrac{0,03}{0,2} = 0,15M$
$[SO_4^{2-}] = \dfrac{0,02}{0,2} = 0,1M$

b)

$pH = -log(0,15) = 0,824$

nH2SO4=0,01 mol=> nH+ =2nH2SO4=0,02 mol

nNaOH=nOH-=0,03mol>nH+ => H+ hết

H+ + OH- -> H2O

0,02->0,02

=>nOH- dư=0,03-0,02=0,01 mol

Vdd=100+150=250ml=0,25l

=>[OH-]=0,01/0,25=0,04M

=>[H+]=10^-14/0,04=2,5.10^-13M

=>pH=-log2,5.10^-13=12,6

Có:nH2SO4 =0,02(mol) ; nHCl=0,04(mol)

=>nH(+)=0,08(mol)

Có: nBa(OH)2 =0,045 (mol); nNaOH=0,03(mol)

=>nOH(-)=0,12(mol)

H(+) +OH(-) ------>H2O

0,008-----0,008

=>nOH(-) dư=0,04(mol)

[OH(-) dư]=0,04/0,5=0,08(M)

=>pH= -log(0,08) =1,1

	Lương Tuấn Dũng | +1đ điểm giá trị
Thứ 4, ngày 20/09/2017 22:07:04
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Đây ạ:
+nNaOH=0.1*0.3=0.03(mol)=nOH{-}
+nBa(OH)2=0.025*0.3=0.0075(mol)
=>nOH{-}=0.0075*2=0.015(mol)
=>nOH{-}(tổng)=0.03+0.015=0.045(mol)

+nH2SO4=0.2x(mol)
=>nH{+}=0.2x*2=0.4x(mol)

_Sau phản ứng thu được dd có pH=2=>môi trường có tính axit.
+[H+] dư=10^-2M
_Vdd(sau)=300+200=500(ml)=0.5(lit)
=>nH{+} dư=10^-2*0.5=0.005(mol)
H{+}+OH{-}=>H2O
0.4x->0.045...........(mol)
0.045->0.045........(mol)
0.4x-0.045->0........(mol)
=>nH{+} dư=0.4x-0.045(mol)
<=>0.4x-0.045=0.005
<=>0.4x=0.05
<=>x=0.125M
Vậy [H2SO4]=0.125M
_Sau phản ứng thu được kết tủa BaSO4:
+nBa{2+}=nBa(OH)2=0.0075(mol)
+nSO4{2-}=0.2*0.125=0.025(mol)
Ba{2+}+SO4{2-}=>BaSO4
0.0075<0.025---->0.0075(mol)
=>mBaSO4=0.0075*233=1.7475(g) Tham khảo nha

+nNaOH=0.1*0.3=0.03(mol)=nOH{-}
+nBa(OH)2=0.025*0.3=0.0075(mol)
=>nOH{-}=0.0075*2=0.015(mol)
=>nOH{-}(tổng)=0.03+0.015=0.045(mol)

+nH2SO4=0.2x(mol)
=>nH{+}=0.2x*2=0.4x(mol)

_Sau phản ứng thu được dd có pH=2=>môi trường có tính axit.
+[H+] dư=10^-2M
_Vdd(sau)=300+200=500(ml)=0.5(lit)
=>nH{+} dư=10^-2*0.5=0.005(mol)
H{+}+OH{-}=>H2O
0.4x->0.045...........(mol)
0.045->0.045........(mol)
0.4x-0.045->0........(mol)
=>nH{+} dư=0.4x-0.045(mol)
<=>0.4x-0.045=0.005
<=>0.4x=0.05
<=>x=0.125M
Vậy [H2SO4]=0.125M
_Sau phản ứng thu được kết tủa BaSO4:
+nBa{2+}=nBa(OH)2=0.0075(mol)
+nSO4{2-}=0.2*0.125=0.025(mol)
Ba{2+}+SO4{2-}=>BaSO4
0.0075<0.025---->0.0075(mol)
=>mBaSO4=0.0075*233=1.7475(g)

ai xóa câu trả lời của mk v