$a\big)$

$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$

$CH_3COOH+NaOH\to CH_3COONa+H_2O$

Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$

$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$

$b\big)$

$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$

$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$

Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$

$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$

trong dung dịch ban đầu nhé mn

\(Đặt:n_{HCl}=3a\left(mol\right);n_{H_2SO_4}=a\left(mol\right)\\n_{NaOH}=0,05.0,5=0,025\left(mol\right)\\ NaOH+HCl\rightarrow NaCl+H_2O\\ 2NaOH+H_2SO_4 \rightarrow Na_2SO_4+2H_2O\\ \rightarrow n_{NaOH\left(tổng\right)}=3a+2a=5a\left(mol\right)\\ \rightarrow5a=0,025\\ \Leftrightarrow a=0,005\left(mol\right)\\ C_{MddHCl}=\dfrac{0,005.3}{0,1}=0,15\left(M\right)\\ C_{MddH_2SO_4}=\dfrac{0,005}{0,1}=0,05\left(M\right)\)

nNa⁺ = 0,016 mol

Gọi số mol của Cl^- và SO₄^2- lần lượt là a, b

Bảo toàn điện tích: a + 2b = 0,016 (1)

Từ khối lượng muối: 35,5a + 96b = 1,036 - 0,016.23 = 0,668 (2)

Từ (1), (2) suy ra: nCl^- = 0,008 mol ; nSO₄^2- = 0,004 mol

=> Cm_HCl = 0,8 M ; Cm_H2SO4 = 0,4 M

\(n_{NaOH}=0,2.4=0,8\left(mol\right)\)

PT: \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,4\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)

\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{50}.100\%=78,4\%\)

a) \(m_{HCl}=200.10,95\%=21,9\left(g\right)\)

b) \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

x_______2x________x____x(mol)

\(n_{HCl}=\dfrac{200.10,95\%}{36,5}=0,6\left(mol\right)\)

Dung dịch A phải có HCl dư mới có thể trung hòa được NaOH.

\(n_{NaOH}=0,05.2=0,1\left(mol\right)\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

y________y______y(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}2x+y=0,6\\y=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,25\\y=0,1\end{matrix}\right.\)

\(\Rightarrow a=m_{CaCO_3}=100x=100.0,25=25\left(g\right)\\ V=V_{CO_2\left(đktc\right)}=22,4x=22,4.0,25=5,6\left(l\right)\)

c) 

\(m_{ddA}=25+200-0,25.44=214\left(g\right)\\ C\%_{ddCaCl_2}=\dfrac{0,25.111}{214}.100\approx12,967\%\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{214}.100\approx1,706\%\)

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)