nNO2=0,12mol

Zn + 4HNO3---------> Zn(NO3)2 + 2NO2+ 2H20

0,06mol 0,24mol 0,12mol

mZn=3,9g, mCuO=1,6g

%mZn=\(\dfrac{3,9}{5,5}\) .100%=70,9%

%mCuO=29,1%

b/nCuO=0,02mol

CuO + 2HNO3---------> Cu(NO3)2 +H20

0,02mol 0,04mol

nHNO3=0,24+0,04=0,28mol

CM=\(\dfrac{0,28}{0,028}\) =10M

a)

$n_{NO} = \dfrac{448}{1000.22,4} = 0,02(mol)$

Bảo toàn electron  :$2n_{Cu} = 3n_{NO} \Rightarrow n_{Cu} = 0,03(mol)$

$m_{Cu} = 0,03.64 = 1,92(gam)$
$m_{CuO} = 3,52 - 1,92 = 1,6(gam)$

b)

$n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$

Bảo toàn Cu : $n_{Cu(NO_3)_2} = 0,02 + 0,03 = 0,05(mol)$

Bảo toàn Nito : 

$n_{HNO_3} = 2n_{Cu(NO_3)_2} + n_{NO} = 0,12(mol)$
$m_{dd\ HNO_3} = \dfrac{0,12.63}{10\%} = 75,6(gam)$

a

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

0,15<-0,15<--0,15<----0,15

\(MgO+2HCl\rightarrow MgCl_2+H_2O\)

0,16-->0,32---->0,16

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(m_{Mg}=0,15.24=3,6\left(g\right)\\ m_{MgO}=10-3,6=6,4\left(g\right)\)

b

\(\%m_{Mg}=\dfrac{3,6.100\%}{10}=36\%\\ \%m_{MgO}=\dfrac{6,4.100\%}{10}=64\%\)

c

\(n_{MgO}=\dfrac{6,4}{40}=0,16\left(mol\right)\)

\(CM_{HCl}=\dfrac{0,15+0,32}{0,2}=2,35M\)

d

\(m_{MgCl_2}=\left(0,15+0,16\right).95=29,45\left(g\right)\)

e

\(CM_{MgCl_2}=\dfrac{0,15+0,16}{0,2}=1,55M\)

a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\) (*)

Phương trình hóa học

Mg + 2HCl ---> MgCl₂ + H₂ (**)

MgO + 2HCl ---> MgCl₂ + H₂O (***)

b) Từ (*) và (**) ta có \(n_{Mg}=0,15\Leftrightarrow m_{Mg}=0,15.24=3,6\left(g\right)\)

\(\Rightarrow m_{MgO}=10-3,6=6,4\left(g\right)\)

 \(\%Mg=\dfrac{3,6}{10}.100\%=36\%\)

\(\%MgO=\dfrac{6,4}{10}.100\%=64\%\)

c) Xét phản ứng (**) ta có \(m_{MgO}=6,4\left(g\right)\Leftrightarrow n_{MgO}=n_{MgCl_2}=\dfrac{1}{2}n_{HCl}=0,16\left(mol\right)\) (1) 

\(\Leftrightarrow n_{HCl}=0,32\left(mol\right)\)

Tương tự có số mol HCl trong phản ứng (*) là 0,3 mol

\(C_M=\dfrac{0,32+0,3}{0,2}=3,1\left(M\right)\)

d) Từ (1) ; (*) ; (**) ta có : \(n_{MgCl_2}=0,15+0,16=0,31\left(mol\right)\)

\(m_{MgCl_2}=0,31.95=29,45\left(g\right)\)

e) \(C_M=\dfrac{0,31}{0,2}=1,55\left(M\right)\)

Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)

Ta có:  \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)

\(\%m_{Zn}=100\%-30,11\%=69,89\%\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1     0,2

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,2     0,4

\(n_{HCl}=0,2+0,4=0,6mol\)

\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)

a, \(CuO+H_2\underrightarrow{^{t^o}}Cu+H_2O\)

\(Fe_2O_3+3H_2\underrightarrow{^{t^o}}2Fe+3H_2O\)

Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 160y = 40 (1)

Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=x+3y=\dfrac{13,44}{22,4}=0,6\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,3.80=24\left(g\right)\\m_{Fe_2O_3}=0,1.160=16\left(g\right)\end{matrix}\right.\)

b, \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=40\%\end{matrix}\right.\)

a) Đặt: nMg=x(mol); nZnO=y(mol)

nH2SO4= 0,2(mol)

PTHH: Mg + H2SO4 -> MgSO4 + H2

x___________x____x_______x(mol)

ZnO + H2SO4 -> ZnSO4 + H2O

y____y______y(mol)

Ta có: 

\(\left\{{}\begin{matrix}24x+81y=12,9\\22,4x=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

mMg=0,2.24=4,8(g)

%mMg=(4,8/12,9).100=37,209%

=>%mZnO=62,791%

b) nH2SO4=x+y=0,3(mol)

=> \(C\%ddH2SO4=\dfrac{0,3.98}{120}.100=24,5\%\)