\(m_{CH_3COOH}=24\%.150=36\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)

PTHH: 2CH₃COOH + Na₂CO₃ ---> 2CH₃COONa + CO₂ + H₂O

                0,6                  0,3                  0,6                  0,3 

=> V_CO2 = 0,3.22,4 = 6,72 (l)

\(m_{Na_2CO_3}=0,3.31,8\left(g\right)\)

=> \(m_{ddNa_2CO_3}=\dfrac{31,8}{21,2\%}=150\left(g\right)\)

m_CO2 = 0,3.44 = 13,2 (g)

\(m_{dd}=150+150-13,2=286,8\left(g\right)\)

\(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{24,6}{286,8}=8,58\%\)

Ta có: \(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)

a. PTHH: Fe₃O₄ + 4H₂SO₄ ---> FeSO₄ + Fe₂(SO₄)₃ + 4H₂O

Theo PT: \(n_{H_2SO_4}=4.n_{Fe_3O_4}=4.0,01=0,04\left(mol\right)\)

=> \(m_{H_2SO_4}=0,04.98=3,92\left(g\right)\)

Theo đề, ta có: \(C_{\%_{H_2SO_4}}=\dfrac{3,92}{m_{dd_{H_2SO_4}}}.100\%=20\%\)

=> \(m_{dd_{H_2SO_4}}=19,6\left(g\right)\)

b. Ta có: \(m_{dd_{SauPỨ}}=2,32+19,6=21,92\left(g\right)\)

Theo PT: \(n_{FeSO_4}=n_{Fe_2\left(SO_4\right)_3}=n_{Fe_3O_4}=0,01\left(mol\right)\)

=> \(m_{FeSO_4}=0,01.152=1,52\left(g\right)\)

\(m_{Fe_2\left(SO_4\right)_3}=0,01.400=4\left(g\right)\)

=> \(m_{SauPỨ}=1,52+4=5,52\left(g\right)\)

=> \(C_{\%_{SauPỨ}}=\dfrac{5,52}{21,92}.100\%=25,18\%\)

\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ 0,05.........0,1..........0,05..........0,05\left(mol\right)\\ a.C\%_{ddHCl}=\dfrac{0,1.36,5}{200}.100=1,825\%\\ b.m_{Zn}=0,05.65=3,25\left(g\right)\\ c.C\%_{ddZnCl_2}=\dfrac{136.0,05}{3,25+200-0,05.2}.100\approx3,347\%\)

\(m_{CH_3COOH}=12\%.100=12\left(g\right)\\ n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)

PTHH: CH₃COOH + NaOH ---> CH₃COONa + H₂O

               0,2--------->0,2------------>0,2

\(m_{NaOH}=0,2.40=8\left(g\right)\\ m_{ddNaOH}=\dfrac{8}{8,4\%}=\dfrac{2000}{21}\left(g\right)\\ m_{ddCH_3COONa}=\dfrac{2000}{21}+100=\dfrac{4100}{21}\left(g\right)\\ m_{CH_3COONa}=0,2.82=16,4\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{16,4}{\dfrac{4100}{21}}.100\%=8,4\%\)

`=>` Gợi ý:

`CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O`

`m<sub>CH3COOH</sub> = 100x12/100 = 12` (g)

`==> n<sub>CH3COOH</sub> = m/M = 12/60 = 0.2` (mol)

Theo pt: `=> n<sub>NaHCO3</sub> = 0.2` (mol)

`==> m<sub>NaHCO3</sub> = n.M = 0.2x84 =16.8` (g)

`==> m<sub>dd NaHCO3</sub> = 16.8x100/8.4 = 200` (g)

Ta có: `n<sub>CH3COONa</sub> = 0.2` (mol)

\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)

PTHH: Fe₂O₃ + 3H₂SO₄ --> Fe₂(SO₄)₃ + 3H₂O

______0,05------>0,15--------->0,05

=> m_H2SO4 = 0,15.98 = 14,7(g)

=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)

\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)

PTHH: Fe₂(SO₄)₃ + 6NaOH --> 2Fe(OH)₃\(\downarrow\) + 3Na₂SO₄

________0,05----------------------->0,1

=> mFe(OH)₃ = 0,1.107=10,7(g)

a) Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

              0,0125<-----0,025------------>0,025------>0,0125

=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)

c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)

\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)

m CH3COOH=1,5g=>n=0,025 mol

2CH3COOH+Na2CO3->2CH3COONa+H2O+CO2

0,025--------------0,0125----------0,025

=>m Na2CO3=0,0125.106=1,325g

=>mdd=25g

c) 

C% =\(\dfrac{0,025.82}{25+25}100=4,1\%\)

\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\\ a,n_{CH_3COOH}=2.n_{H_2}=2.0,3=0,6\left(mol\right)\\ m_{ddCH_3COOH}=\dfrac{0,6.60.100}{20}=180\left(g\right)\\ b,n_{\left(CH_3COO\right)_2Zn}=n_{Zn}=n_{H_2}=0,3\left(mol\right)\\ C\%_{dd\left(CH_3COO\right)_2Zn}=\dfrac{0,3.183}{180+0,3.65-0,3.2}.100\approx27,602\%\)

n Zn= 19,5/65=0,3 (mol).

PTPƯ: Zn(0.3) +   HCl(0.6) ---->  ZnCl2(0.3) + H2(0,3)

mHCl=0,6.36.5=21.9(g)

a) C%HCl= 21.9/300.100%=7,3%

b) VH2=0,3.22,4=6,72(lít)

c) mH2=0,3.2=0,6(g)

mZnCl2=0,3.136=40,8(g)

mddZnCl2 =(19,5+300)-0,6=318,9(g)

C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%