\(n_{hhkhí}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\\ m_{tăng}=m_{C_2H_4}=4,2\left(g\right)\\ n_{C_2H_4}=\dfrac{4,2}{28}=0,15\left(mol\right)\\ n_{CH_4}=0,35-0,15=0,2\left(mol\right)\\ \left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,15}{0,35}=42,85\%\\\%V_{CH_4}=100\%-42,85\%=57,15\%\end{matrix}\right.\)

PTHH:

C₂H₄ + 3O₂ --t^o--> 2CO₂ + 2H₂O

0,15 ------------------> 0,3

CH₄ + O₂ --t^o--> CO₂ + 2H₂O

0,2 -----------------> 0,2

Ca(OH)₂ + CO₂ ---> CaCO₃ + H₂O

                   0,5 -------> 0,5

\(m_{CaCO_3}=0,5.100=50\left(g\right)\)

\(a,n_{hhkhí\left(C_2H_4,C_2H_2\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Br_2}=\dfrac{80}{160}=0,5\left(mol\right)\\ Gọi\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ Hệ.pt\left\{{}\begin{matrix}a+b=0,3\\a+2b=0,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\\ \%V_{C_2H_4}=\dfrac{0,1}{0,3}=33,33\%\\ \%V_{C_2H_2}=100\%-33,335=66,67\%\)

\(b,PTHH:\\ C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:0,1\rightarrow0,3\rightarrow0,2\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:0,2\rightarrow0,25\rightarrow0,4\\ n_{CO_2}=0,2+0,4=0,6\left(mol\right)\\ PTHH:Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ Mol:0,6\rightarrow0,6\rightarrow0,6\\ m_{CaCO_3}=0,6.100=60\left(g\right)\)

\(a,Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{C_2H_2}=c\left(mol\right)\end{matrix}\right.\\ n_{hhkhí}=0,4\left(mol\right)\\ n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ Mol:a\rightarrow2a\rightarrow a\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:b\rightarrow3b\rightarrow2b\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:c\rightarrow2,5c\rightarrow2c\\ Hệ.pt\left\{{}\begin{matrix}a+b+c=0,4\\b+2c=0,4\\a+2b+2c=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)

\(\%V_{CH_4}=\%V_{C_2H_2}=\dfrac{0,1}{0,4}=25\%\\ \%V_{C_2H_4}=\dfrac{0,2}{0,4}=50\%\)

\(m_{CH_4}=0,1.16=1,6\left(g\right)\\ m_{C_2H_4}=28.0,2=5,6\left(g\right)\\ m_{C_2H_2}=0,1.26=2,6\left(g\right)\\ \%m_{CH_4}=\dfrac{1,6}{1,6+5,6+2,6}=16,32\%\\ \%m_{C_2H_4}=\dfrac{5,6}{1,6+5,6+2,6}=57,14\%\\ \%m_{C_2H_2}=100\%-16,32\%-57,14\%=26,54\%\)

\(b,PTHH:C_2H_5OH\rightarrow C_2H_4+H_2O\\ Mol:0,2\leftarrow0,2\\ m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)

Dài quá!!!

a) m_tăng = m_C2H4

=> \(n_{C_2H_4}=\dfrac{5,6}{28}=0,2\left(mol\right)\)

=> \(\%V_{C_2H_4}=\dfrac{0,2.22,4}{13,44}.100\%=33,33\%\)

\(\%V_{CH_4}=100\%-33,33\%=66,67\%\)

b) \(n_{CH_4}=\dfrac{13,44.66,67\%}{22,4}=0,4\left(mol\right)\)

PTHH: CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

            0,4--------------->0,4

            C₂H₄ + 3O₂ --t^o--> 2CO₂ + 2H₂O

             0,2----------------->0,4

            Ca(OH)₂ + CO₂ --> CaCO₃ + H₂O

                               0,8----->0,8

=> m_CaCO3 = 0,8.100 = 80 (g)

a.\(m_{tăng}=m_{C_2H_4}=5,6g\)

\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)

\(n_{C_2H_4}=\dfrac{5,6}{28}=0,2mol\)

\(\%V_{C_2H_4}=\dfrac{0,2}{0,6}.100=33,33\%\)

\(\%V_{CH_4}=100\%-33,33\%=66,67\%\)

b.\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)

      0,2                             0,4              ( mol )

\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)

 0,4                          0,4                  ( mol )

\(n_{CO_2}=0,4+0,4=0,8mol\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

                      0,8          0,8                   ( mol )

\(m_{CaCO_3}=0,8.100=80g\)

m_tăng = m_C2H4 = 2,8 (g)

=> \(n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

=> V_C2H4 = 0,1.22,4 = 2,24 (l)

=> V_CH4 = 4,48 - 2,24 = 2,24 (l)

C2H4+Br2-to>C2H4Br2

0,01---0,01 mol

n C2H4=\(\dfrac{2,8}{28}\)=0,1 mol

=>VC2H4=0,01.22,4=2,24l

=>VCH4=2,24

Ta có: m _{dd Br2 tăng} = m_C2H4 = 2,8 (g)

\(\Rightarrow n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)

Có: \(n_{CH_4}=\dfrac{3,36}{22,4}-0,1=0,05\left(mol\right)\)

⇒ m _hh = m_CH4 + m_C2H4 = 0,05.16 + 0,1.28 = 3,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{3,6}.100\%\approx22,22\%\\\%m_{C_2H_4}\approx77,78\%\end{matrix}\right.\)

a.\(m_{tăng}=m_{C_2H_4}=2,8g\)

\(V_{khí.thoát.ra}=V_{CH_4}+V_{CO_2}\)

\(n_{C_2H_4}=\dfrac{2,8}{28}=0,1mol\)

\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)

 0,1                                          0,2        ( mol )

\(m_{H_2O\left(thu.được\right)}=0,2.18=3,6g\)

\(\Rightarrow m_{H_2O\left(pứCH_4\right)}=7,2-3,6=3,6g\)

\(n_{H_2O}=\dfrac{3,6}{18}=0,2mol\)

\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)

0,1                                       0,2         ( mol )

\(\Rightarrow V_{CH_4}=0,1.22,4=2,24l\)

\(\Rightarrow V_{CO_2}=3,36-2,24=1,12l\)

\(\Rightarrow V_{C_2H_4}=0,1.22,4=2,24l\)

\(\rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{2,24}{2,24+1,12+2,24}.100=40\%\\\%V_{CO_2}=\dfrac{1,12}{2,24+1,12+2,24}.100=20\%\\\%V_{C_2H_4}=100\%-40\%-20\%=40\%\end{matrix}\right.\)

b.\(\rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6g\\m_{CO_2}=0,05.44=2,2g\\m_{C_2H_4}=0,1.28=2,8g\end{matrix}\right.\)

\(\Rightarrow m_{hh}=1,6+2,2+2,8=6,6g\)

c.\(m_{PE}=28.n_{C_2H_4}.H\%=28.0,1.80\%=2,24g\)

a) Khối lượng bình tăng bằng khối lượng khí etilen tham gia phản ứng với Br₂, số mol khí etilen là 2,8/28=0,1 (mol).

Đốt hỗn hợp, khí metan và etilen tạo ra 7,2/18=0,4 (mol) H₂O, suy ra số mol khí metan là (0,4.2-0,1.4):4=0,1 (mol) (BT H).

3,36 lít khí thoát ra gồm khí metan và khí cacbonic, số mol khí cacbonic là 3,36/22,4-0,1=0,05 (mol).

%V_metan=0,1/(0,1+0,1+0,05).100%=40%=%V_etilen, suy ra %V_cacbonic=100%-(40%+40%)=20%.

b) m=0,1.16+0,1.28+0,05.44=6,6 (g).

c) Số mol polietilen thực tế là 0,1.0,8/n=0,08/n (mol).

Khối lượng cần tìm là 0,08/n.28n=2,24 (g).

a. Phương trình phản ứng :

C_2­H₂ + 2Br₂  → C₂H₂Br₄         (1)

C_2­H₄ + Br₂ → C₂H₄Br₂            (2)

b. Hỗn hợp khí B gồm có H₂, C₂H₆. Gọi x, y ( mol ) lần lượt là  số mol của H₂ và C₂H₆ có trong 6,72 lít hỗn hợp B.

n_B = x + y = 6,72 : 22,4 = 0,3  mol                               (I)

% V(C₂H₆) = 100% – 66,67% = 33,33%

c.  n_A = 11,2 : 22,4 = 0,5 mol , M A  = 0,4 . 44 = 17,6 g/ mol

m_A =  0,5 . 17,6 = 8,8 gam

m_B = 0,2 . 2 + 0,1 . 30 = 3,4 gam

Vậy khối lượng bình Br₂ tăng:  m = m_A – m_B  = 8,8 – 3,4 = 5,4 gam.

nhh khí = 2,24/22,4 = 0,1 (mol)

nC2H4 = 1,4/28 = 0,05 (mol)

%VC2H4 = 0,05/0,1 = 50%

%VC2H6 = 100% - 50% = 50%

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