ai giúp mình với, mình đang ktra huhuhuh

\(m_{H_2SO_4}=\dfrac{19,6\cdot20\%}{100\%}=3,92\left(g\right)\\ \Rightarrow n_{H_2SO_4}=\dfrac{3,92}{98}=0,04\left(mol\right)\\ PTHH:H_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2HCl\\ \Rightarrow n_{H_2SO_4}=n_{BaCl_2}=n_{BaSO_4}=0,04\left(mol\right)\\ \Rightarrow m_{CT_{BaCl_2}}=0,04\cdot208=8,32\left(g\right)\\ \Rightarrow m_{dd_{BaCl_2}}=\dfrac{8,32\cdot100\%}{12\%}\approx69,3\left(g\right)\\ m_{kết.tủa}=m_{BaSO_4}=0,04\cdot233=9,32\left(g\right)\)

Bài 1:

PTHH: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}m_{Ba\left(OH\right)_2}=150\cdot17,1\%=25,65\left(g\right)\\m_{HCl}=300\cdot7,3\%=21,9\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Ba\left(OH\right)_2}=\frac{25,65}{171}=0,15\left(mol\right)\\n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\frac{0,15}{1}< \frac{0,6}{2}\) \(\Rightarrow\) Ba(OH)₂ phản ứng hết, HCl còn dư

\(\Rightarrow\) Dung dịch A làm quỳ tím hóa đỏ

Bài 2:

PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=\frac{150\cdot4\%}{40}=0,15\left(mol\right)\\n_{H_2SO_4}=\frac{300\cdot9,8\%}{98}=0,3\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\frac{0,15}{2}< \frac{0,3}{1}\) \(\Rightarrow\) NaOH phản ứng hết, H₂SO₄ còn dư

\(\Rightarrow\) Dung dịch A làm quỳ tím hóa đỏ

Bài 3:

PTHH: \(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_4\downarrow\) (1)

a) Ta có: \(\left\{{}\begin{matrix}n_{BaCl_2}=\frac{150\cdot5,2\%}{208}=0,0375\left(mol\right)\\n_{H_2SO_4}=\frac{250\cdot19,6\%}{98}=0,5\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\frac{0,0375}{1}< \frac{0,5}{1}\) \(\Rightarrow\) BaCl₂ phản ứng hết, H₂SO₄ còn dư

\(\Rightarrow n_{BaSO_4}=0,0375mol\) \(\Rightarrow m_{BaSO_4}=0,0375\cdot233=8,7375\left(g\right)\)

b) Dung dịch A chứa \(HCl\) và \(H_2SO_{4\left(dư\right)}\)

PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\) (2)

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\) (3)

Theo PTHH (1): \(\left\{{}\begin{matrix}n_{HCl}=2n_{BaCl_2}=0,075mol\\n_{H_2SO_4\left(dư\right)}=0,4625mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{NaOH\left(2\right)}=0,075mol\\n_{NaOH\left(3\right)}=0,925mol\end{matrix}\right.\)

\(\Rightarrow n_{NaOH}=1mol\) \(\Rightarrow V_{NaOH}=\frac{1}{1,5}\approx0,67\left(l\right)=670\left(ml\right)\)

\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

\(n_{BaCl_2}=\dfrac{208.10\%}{208}=0,1\left(mol\right)\\ a,BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ 0,1............0,1..............0,1.............0,2\left(mol\right)\\ b,m_{ddH_2SO_4}=\dfrac{0,1.98.100}{8}=122,5\left(g\right)\\ c,m_{kt}=m_{BaSO_4}=0,1.233=23,3\left(g\right)\\ d,m_{ddsau}=208+122,5-23,3=307,2\left(g\right)\\ C\%_{ddHCl}=\dfrac{0,2.36,5}{307,2}.100\approx2,376\%\)

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?

m_ddH2SO4 = 100 . 1,137 = 113,7

n_H2SO4 = 113,7 . 20%/98 = 0,232 mol

n_BaCl2 = 400 . 5,29%/208 = 0,1 mol

                 H₂SO₄ + BaCl₂ —> BaSO₄ + 2HCI

Bđ:            0,232      0,1

Pứ:            0,1        0, 1         0,1       0,2

Sau pứ:      0,132         0

m_BaSO4 = 0,1.233 = 23,3 gam

Khối lượng dung dịch sau khi lọc bỏ kết tủa:

m_ddB = m_ddH2SO4 + m_ddBaCl2 - m_BaSO4 = 490,4

C%HCI = 0,2.36,5/490,4 = 1,49%

C%_H2SO4 dư = 0,132.98/490,4 = 2,64%

PTHH: \(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_4\downarrow\)

Ta có: \(n_{BaCl_2}=\dfrac{208\cdot10\%}{208}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{BaSO_4}=0,1\left(mol\right)=n_{H_2SO_4}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,1\cdot98}{8\%}=122,5\left(g\right)\\m_{BaSO_4}=0,1\cdot233=23,3\left(g\right)\\m_{HCl}=0,2\cdot36,5=7,3\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{ddBaCl_2}+m_{ddH_2SO_4}-m_{BaSO_4}=307,2\left(g\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{7,3}{307,2}\cdot100\%\approx2,38\%\)

\(a,PTHH:H_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2HCl\\ \left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\)

Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên H₂SO₄ dư

\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\\ b,n_{HCl}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,25\cdot36,5=9,125\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{9,125}{441,75}\cdot100\%\approx2,07\%\)