a.\(Fe+S\rightarrow\left(t^o\right)FeS\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(FeS+2HCl\rightarrow FeCl_2+H_2S\)

b.\(n_{hhk}=\dfrac{4,48}{22,4}=0,2mol\)

\(Fe+S\rightarrow\left(t^o\right)FeS\)

Ta thu được hh khí --> S hết, Fe dư

Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_S=y\end{matrix}\right.\)

\(\rightarrow n_{FeS}=n_{Fe}=n_S\rightarrow n_{Fe\left(dư\right)}=x-y\) ( mol )

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(x-y\)                            \(x-y\)        ( mol )

\(FeS+2HCl\rightarrow FeCl_2+H_2S\)

  y                                          y       ( mol )

Ta có: \(\left(x-y\right)+y=0,2\)

           \(\Leftrightarrow x=0,2\)

Ta có:\(56x+32y=14,4\)

        \(\Leftrightarrow56.0,2+32y=14,4\)

        \(\Leftrightarrow y=0,1\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2.56}{14,4}.100=77,77\%\\\%m_S=100\%-77,77\%=22,23\%\end{matrix}\right.\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

b, Ta có: \(n_{HCl}=0,5.0,2=0,1\left(mol\right)\)

\(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

Theo PT: \(n_{HCl\left(pư\right)}=2n_{H_2}=0,08\left(mol\right)< 0,1\left(mol\right)\)

→ HCl dư.

Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo PT: \(n_{H_2}=n_{Zn}+n_{Fe}=x+y=0,04\left(1\right)\)

\(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=x\left(mol\right)\\n_{FeCl_2}=n_{Fe}=y\left(mol\right)\end{matrix}\right.\)⇒ 136x + 127y = 5,26 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,02\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,02.65}{0,02.65+0,02.56}.100\%\approx53,72\%\\\%m_{Fe}\approx46,28\%\end{matrix}\right.\)

PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,04\left(mol\right)\Rightarrow m_{Zn}=0,04.65=2,6\left(g\right)\)

⇒ m_Cu = 9 - 2,6 = 6,4 (g)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{2,6}{9}.100\%\approx28,89\%\\\%m_{Cu}\approx71,11\%\end{matrix}\right.\)

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ \Rightarrow n_{Zn}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Ag}=\dfrac{20-0,15.65}{20}.100\%=51,25\%\)

\(n_{H_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(0.05..............................0.05\)

\(m_{Cu}=9.65-0.05\cdot65=6.4\left(g\right)\)

\(\%Cu=\dfrac{6.4}{9.65}\cdot100\%=66.32\%\)

\(\%Zn=100-66.32=33.68\%\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ b,n_{Fe}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Fe}=0,1.56=5,6(g)\\ \Rightarrow \%_{Fe}=\dfrac{5,6}{12}.100\%=46,67\%\\ \Rightarrow \%_{Cu}=100\%-46,67\%=53,33\%\\ c,n_{HCl}=2n_{H_2}=0,2(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,2}=1M\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

\(n_{Zn}=n_{H_2}=\dfrac{0.448}{22.4}=0.02\left(mol\right)\)

\(\Rightarrow m_{Zn}=0.02\cdot65=1.3\left(g\right)\)

\(m_{ZnO}=4.54-1.3=3.24\left(g\right)\)

Lượng khí hidro thoát ra là 0,15 mol.

a) Al₂O₃ + 2NaOH \(\rightarrow\) 2NaAlO₂ + H₂O

2Al + 2NaOH + 2H₂O \(\rightarrow\) 2NaAlO₂ + 3H₂.

b) Lượng Al phản ứng bằng 2/3 số mol khí hidro thoát ra và bằng 0,1 mol.

\(\Rightarrow\) %m_nhôm=\(\dfrac{27.0,1}{12,9}\).100%\(\approx\)20,93%, %m_{nhôm oxit}\(\approx\)100%-20,93%\(\approx\)79,07%.

nH2=0,1mol

Zn + 2HCl -----> ZnCl2 + H2

0,1 mol 0,1 mol

mZn=0,1.65=6,5g

mZnO=14,6-6,5=8,1g

%mZn=\(\frac{6,5}{14,6}\).100=44,5%

%mZnO=55,5%