\(Fe_2O_3 + 6HCl \rightarrow 2FeCl_3 + 3H_2O\)

\(CuO + 2HCl \rightarrow CuCl_2 + H_2O\)

\(NaOH + HCl \rightarrow NaCl + H_2O\)

\(n_{NaOH} = 0,2 . 1 = 0,2 mol\)

\(n_{HCl dư} = n_{NaOH}= 0,2 mol\)

\(\Rightarrow n_{HCl pư}= n_{HCl ban đầu} - n_{HCl dư}= 1,4- 0,2 = 1,2 mol\)

Gọi n_{\(Fe_2O_3\)} và n_\(CuO\) là x, y

\(\begin{cases} 160x + 80y=40\\ 6x + 2y= 1,2 \end{cases} \)

\(\begin{cases} x=0,1\\ y=0,3 \end{cases} \)

\(\Rightarrow m_{Fe_2O_3}= 0,1 . 160= 16g\)

\(m_{CuO} = 0,3 . 80=24g\)

a. PTHH: Cu + HCl ---x--->

Zn + 2HCl ---> ZnCl₂ + H₂ (1)

b. Đổi 100ml = 0,1 lít

Ta có: \(C_{M_{HCl}}=\dfrac{n_{HCl}}{0,1}=3M\)

=> n_HCl = 0,3(mol)

Theo PT₍₁₎: \(n_{Zn}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,3=0,15\left(mol\right)\)

=> m_Zn = 65 . 0,15 = 9,75(g)

=> m_Cu = 12,1 - 9,75 = 2,35(g)

=> \(\%_{m_{Zn}}=\dfrac{9,75}{12,1}.100\%=80,6\%\)

\(\%_{m_{Cu}}=100\%-80,6\%=19,4\%\)

c. PTHH: Cu + H₂SO₄ ---x--->

Zn + H₂SO₄ ---> ZnSO₄ + H₂ (2)

Theo PT₍₂₎: \(n_{Zn}=n_{H_2SO_4}=0,15\left(mol\right)\)

=> \(m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)

Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{14,7}{m_{dd_{H_2SO_4}}}.100\%=20\%\)

=> \(m_{dd_{H_2SO_4}}=73,5\left(g\right)\)

a) Đặt nAl=a(mol) ; nFe=b(mol) (a,b>0)

nHCl= (365.12%)/36,5=1,2(mol)

PTHH: 2Al + 6 HCl -> 2AlCl3 +3 H2

a________3a_________2a____1,5a(mol)

Fe + 2 HCl -> FeCl2 + H2

b_____2b____b____b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}27a+56b=22,2\\3a+2b=1,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)

b) => %mAl= [(0,2.27)/22,2].100=24,324%

=>%mFe= 75,676%

c) mFeCl2=127. 0,3=38,1(g)

mAlCl3= 133,5. 0,2= 26,7(g)

mddsau= 22,2+365 - 1,2.2=384,8(g)

=>C%ddFeCl2= (38,1/384,8).100=9,901%

C%ddAlCl3= (26,7/384,8).100=6,939%

\(a)n_{HCl}=0,2.1,5=0,3mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}2n_{CaO}+2n_{CuO}=0,3\\56n_{CaO}+80n_{CuO}=10,8\end{matrix}\right.\\ \Rightarrow n_{CaO}=n_{CaCl_2}=0,05mol;n_{CuO}=n_{CuCl_2}=0,1mol\\ \%m_{CaO}=\dfrac{0,05.56}{10,8}\cdot100=25,93\%\\ \%m_{CuO}=100-25,93=74,07\%\\ b)C_{M_{CaCl_2}}=\dfrac{0,05}{0,2}=0,25M\\ C_{M_{CuCl_2}}=\dfrac{0,1}{0,2}=0,5M\)

\(CaO+2HCl\rightarrow CaCl_2+H_2O\)

x            2x            x           x 

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

y             2y            y          y 

\(\left\{{}\begin{matrix}56x+80y=10,8\\2x+2y=0,2.1,5=0,3\end{matrix}\right.\)

\(\Rightarrow x=0,05;y=0,1\)

\(a,\%m_{CaO}=0,05.56:10,8.100\%=25,93\left(\%\right)\)

\(\%m_{CuO}=100\%-25,93\%=74,07\%\)

\(b,C_{M\left(CaCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)

\(n_{HCl}=3.0,2=0,6(mol)\\ PTHH:Fe_2O_3+6HCl\to 2FeCl_3+3H_2O\\ \Rightarrow n_{Fe_2O_3}=\dfrac{1}{6}n_{HCl}=0,1(mol)\\ \Rightarrow m_{Fe_2O_3}=0,1.160=16(g)\\ \Rightarrow \%_{Fe_2O_3}=\dfrac{16}{20}.100\%=80\%\\ \Rightarrow \%_{Cu}=100\%-80\%=20\%\)

a) 

n_NaOH = 0,04.1 = 0,04 (mol)

PTHH: NaOH + HCl --> NaCl + H₂O

           0,04--->0,04

=> n_{HCl(pư với X)} = 0,2.1 - 0,04 = 0,16 (mol)

Gọi số mol CuO, Fe₂O₃ là a, b (mol)

=> 80a + 160b = 4,8 (1)

PTHH: CuO + 2HCl --> CuCl₂ + H₂O

              a----->2a

            Fe₂O₃ + 6HCl --> 2FeCl₃ + 3H₂O

               b----->6b

=> 2a + 6b = 0,16 (2)

(1)(2) => a = 0,02; b = 0,02

=> \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,02.80}{4,8}.100\%=33,33\%\\\%m_{Fe_2O_3}=\dfrac{0,02.160}{4,8}.100\%=66,67\%\end{matrix}\right.\)

b) Chất rắn thu được gồm CuO, Fe₂O₃

Bảo toàn Cu: n_CuO = 0,02 (mol)

Bảo toàn Fe: n_Fe2O3 = 0,02 (mol)

=> m = 0,02.80 + 0,02.160 = 4,8 (g)