Bài 1 :

PTHH : Zn + H₂SO₄ ------> ZnSO₄ + H₂

\(n_{Zn}=\frac{m}{M}=\frac{26}{65}=0,4\left(mol\right)\)

Theo PTHH : n_H2 = n_Zn = 0,4 mol

=> Khối lượng H₂ được tạo ra ở đktc là :

\(V=n\times22,4\)

\(\Rightarrow V_{H_2}=0,4\times22,4\)

\(\Rightarrow V_{H_2}=8,96\left(l\right)\)

Theo PTHH : n_ZnSO4 = n_Zn = 0,4 mol

=> Khối lượng muối được tạo thành là :

\(m=n\times M\)

\(\Rightarrow m_{ZnSO_4}=0,4\times161\)

\(\Rightarrow m_{ZnSO_4}=64,4\left(g\right)\)

b) Theo PT : \(n_{H_2SO_4}=n_{Zn}=0,4\left(mol\right)\)

=> Khối lượng \(H_2SO_4\)cần dùng cho phản ứng là :

\(m=n\times M\)

\(\Rightarrow m_{H_2SO_4}=0,4\times98\)

\(\Rightarrow m_{H_2SO_4}=39,2\left(g\right)\)

c) Nồng độ phần trăm thu được sau phản ứng là :

\(C\%=\frac{m_{ct}}{m_{dd}}\times100\%\)

\(\Rightarrow C\%=\frac{39,2}{64,4}\times100\%\approx60,9\%\)

Vậy :.........................

a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{H_2SO_4}=0,2.98=19,6\left(g\right)\)

c, \(C\%_{H_2SO_4}=\dfrac{19,6}{50}.100\%=39,2\%\)

d, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)

\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

a. PTHH: Zn + H₂SO₄ ---> ZnSO₄ + H₂↑

b. Ta có: \(C_{M_{H_2SO_4}}=\dfrac{n_{H_2SO_4}}{200:1000}=1,5M\)

=> \(n_{H_2SO_4}=0,3\left(mol\right)\)

Ta lại có: \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

Ta thấy: \(\dfrac{0,3}{1}>\dfrac{0,25}{1}\)

Vậy H₂SO₄ dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)

=> \(V_{H_2}=0,25.22,4=5,6\left(lít\right)\)

c. Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,25\left(mol\right)\)

=> \(m_{ZnSO_4}=0,25.161=40,25\left(g\right)\)

d. Ta có: \(V_{dd_{ZnSO_4}}=0,2\left(lít\right)\)

=> \(C_{M_{ZnSO_4}}=\dfrac{0,25}{0,2}=1,25M\)

Zn + 2HCl --> ZnCl2 + H2

0,5      1              0,5       0,5

nZn=\(\dfrac{32,5}{65}\)=0,5(mol)

mZnCl2=0,5.136=68(g)

VH2=0,5.22,4=11,2(l)

c) CM HCl=\(\dfrac{1}{0,25}=4M\)

a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)

\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)

Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)

b, Ta có: 126n_Na2SO3 + 158n_K2SO3 = 44,2 (1)

Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)

Có: m _{dd sau pư} = 44,2 + 147 - 0,3.64 = 172 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)

c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)

\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO₃.

PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)

\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)

a)

$n_{Al} = 0,3(mol)$

$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$

Theo PTHH : 

$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$

b)

$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$

c)

$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$

Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)

a. PTHH: Mg + H₂SO₄ ---> MgSO₄ + H₂↑

Theo PT: \(n_{H_2}=n_{Mg}=0,4\left(mol\right)\)

=> \(V_{H_2}=0,4.22,4=8,96\left(lít\right)\)

b. Theo PT: \(n_{H_2SO_4}=n_{Mg}=0,4\left(mol\right)\)

=> \(m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)

Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{39,2}{m_{dd_{H_2SO_4}}}.100\%=10\%\)

=> \(m_{dd_{H_2SO_4}}=392\left(g\right)\)

c. Ta có: \(m_{H_2}=0,4.2=0,8\left(g\right)\)

=> \(m_{dd_{MgSO_4}}=9,6+392-0,8=400,8\left(g\right)\)

Theo PT: \(n_{MgSO_4}=n_{Mg}=0,4\left(mol\right)\)

=> \(m_{MgSO_4}=0,4.120=48\left(g\right)\)

=> \(C_{\%_{MgSO_4}}=\dfrac{48}{400,8}.100\%=11,98\%\)

\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)